IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v150y2020icp990-1000.html
   My bibliography  Save this article

Stabilization of K2CO3 in vermiculite for thermochemical energy storage

Author

Listed:
  • Shkatulov, A.I.
  • Houben, J.
  • Fischer, H.
  • Huinink, H.P.

Abstract

Thermochemical energy storage (TCES) is an emerging technology promising for domestic applications. Recently, K2CO3 was identified and studied as a TCES material. In this work, the composite “K2CO3 in expanded vermiculite” (69 wt. % of the salt) was prepared and studied for thermochemical energy storage bearing in mind its application for space heating. The hydration rate was found to be higher for the confined K2CO3 in comparison with K2CO3 granules of the same size. While morphology and texture of the composite alter after 74 hydration/dehydration cycles, its chemical composition and average grain size do not change. The energy storage density of the composite bed can reach 0.9 GJ/m3 (250 kWh/m3) for cycles with deliquescence which makes the composite an inexpensive thermochemical material for space heating. Stable conversion for deliquescence conditions was shown for at least 47 cycles.

Suggested Citation

  • Shkatulov, A.I. & Houben, J. & Fischer, H. & Huinink, H.P., 2020. "Stabilization of K2CO3 in vermiculite for thermochemical energy storage," Renewable Energy, Elsevier, vol. 150(C), pages 990-1000.
  • Handle: RePEc:eee:renene:v:150:y:2020:i:c:p:990-1000
    DOI: 10.1016/j.renene.2019.11.119
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119318130
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.renene.2019.11.119?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Deutsch, Markus & Müller, Danny & Aumeyr, Christian & Jordan, Christian & Gierl-Mayer, Christian & Weinberger, Peter & Winter, Franz & Werner, Andreas, 2016. "Systematic search algorithm for potential thermochemical energy storage systems," Applied Energy, Elsevier, vol. 183(C), pages 113-120.
    2. Lv, Peizhao & Liu, Chenzhen & Rao, Zhonghao, 2017. "Review on clay mineral-based form-stable phase change materials: Preparation, characterization and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 707-726.
    3. Shkatulov, Alexandr & Ryu, Junichi & Kato, Yukitaka & Aristov, Yury, 2012. "Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat," Energy, Elsevier, vol. 44(1), pages 1028-1034.
    4. Sögütoglu, L.C. & Donkers, P.A.J. & Fischer, H.R. & Huinink, H.P. & Adan, O.C.G., 2018. "In-depth investigation of thermochemical performance in a heat battery: Cyclic analysis of K2CO3, MgCl2 and Na2S," Applied Energy, Elsevier, vol. 215(C), pages 159-173.
    5. Gaeini, M. & Rouws, A.L. & Salari, J.W.O. & Zondag, H.A. & Rindt, C.C.M., 2018. "Characterization of microencapsulated and impregnated porous host materials based on calcium chloride for thermochemical energy storage," Applied Energy, Elsevier, vol. 212(C), pages 1165-1177.
    6. Donkers, P.A.J. & Sögütoglu, L.C. & Huinink, H.P. & Fischer, H.R. & Adan, O.C.G., 2017. "A review of salt hydrates for seasonal heat storage in domestic applications," Applied Energy, Elsevier, vol. 199(C), pages 45-68.
    7. N’Tsoukpoe, Kokouvi Edem & Schmidt, Thomas & Rammelberg, Holger Urs & Watts, Beatriz Amanda & Ruck, Wolfgang K.L., 2014. "A systematic multi-step screening of numerous salt hydrates for low temperature thermochemical energy storage," Applied Energy, Elsevier, vol. 124(C), pages 1-16.
    8. Jiang, Long & Gao, Jiao & Wang, Liwei & Wang, Ruzhu & Lu, Yiji & Roskilly, Anthony Paul, 2017. "Investigation on performance of multi-salt composite sorbents for multilevel sorption thermal energy storage," Applied Energy, Elsevier, vol. 190(C), pages 1029-1038.
    9. L. G. Gordeeva & Yu. I. Aristov, 2012. "Composites ‘salt inside porous matrix’ for adsorption heat transformation: a current state-of-the-art and new trends," International Journal of Low-Carbon Technologies, Oxford University Press, vol. 7(4), pages 288-302, April.
    10. Xu, J.X. & Li, T.X. & Chao, J.W. & Yan, T.S. & Wang, R.Z., 2019. "High energy-density multi-form thermochemical energy storage based on multi-step sorption processes," Energy, Elsevier, vol. 185(C), pages 1131-1142.
    11. Yannan Zhang & Ruzhu Wang & Tingxian Li & Yanjie Zhao, 2016. "Thermochemical Characterizations of Novel Vermiculite-LiCl Composite Sorbents for Low-Temperature Heat Storage," Energies, MDPI, vol. 9(10), pages 1-15, October.
    12. Prieto, Cristina & Cooper, Patrick & Fernández, A. Inés & Cabeza, Luisa F., 2016. "Review of technology: Thermochemical energy storage for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 909-929.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yihan Wang & Zicheng Zhang & Shuli Liu & Zhihao Wang & Yongliang Shen, 2023. "Development and Characteristics Analysis of Novel Hydrated Salt Composite Adsorbents for Thermochemical Energy Storage," Energies, MDPI, vol. 16(18), pages 1-21, September.
    2. Gbenou, Tadagbe Roger Sylvanus & Fopah-Lele, Armand & Wang, Kejian, 2022. "Macroscopic and microscopic investigations of low-temperature thermochemical heat storage reactors: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    3. Liu, Yang & Ayub, Iqra & Khan, Muhammad Raheel & Yang, Fusheng & Wu, Zhen & Zhang, Zaoxiao, 2022. "Numerical investigation of metal hydride heat storage reactor with two types multiple heat transfer tubes structures," Energy, Elsevier, vol. 253(C).
    4. Aristov, Yu. I., 2022. "Adsorption heat conversion and storage in closed systems: What have we learned over the past decade of this century?," Energy, Elsevier, vol. 239(PB).
    5. Zhang, Yong & Hu, Mingke & Chen, Ziwei & Su, Yuehong & Riffat, Saffa, 2023. "Modelling analysis of a solar-driven thermochemical energy storage unit combined with heat recovery," Renewable Energy, Elsevier, vol. 206(C), pages 722-737.
    6. Mohamed Zbair & Simona Bennici, 2021. "Survey Summary on Salts Hydrates and Composites Used in Thermochemical Sorption Heat Storage: A Review," Energies, MDPI, vol. 14(11), pages 1-33, May.
    7. Chen, Ziwei & Zhang, Yanan & Zhang, Yong & Su, Yuehong & Riffat, Saffa, 2023. "A study on vermiculite-based salt mixture composite materials for low-grade thermochemical adsorption heat storage," Energy, Elsevier, vol. 278(PB).
    8. Salviati, Sergio & Carosio, Federico & Cantamessa, Francesco & Medina, Lilian & Berglund, Lars A. & Saracco, Guido & Fina, Alberto, 2020. "Ice-templated nanocellulose porous structure enhances thermochemical storage kinetics in hydrated salt/graphite composites," Renewable Energy, Elsevier, vol. 160(C), pages 698-706.
    9. Strelova, Svetlana V. & Gordeeva, Larisa G. & Grekova, Alexandra D. & Salanov, Aleksei N. & Aristov, Yuri I., 2023. "Composites “lithium chloride/vermiculite” for adsorption thermal batteries: Giant acceleration of sorption dynamics," Energy, Elsevier, vol. 263(PB).
    10. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2021. "Numerical analysis on the improved thermo-chemical behaviour of hierarchical energy materials as a cascaded thermal accumulator," Energy, Elsevier, vol. 232(C).
    11. Isye Hayatina & Amar Auckaili & Mohammed Farid, 2023. "Review on Salt Hydrate Thermochemical Heat Transformer," Energies, MDPI, vol. 16(12), pages 1-23, June.
    12. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Salt hydrate–based gas-solid thermochemical energy storage: Current progress, challenges, and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    13. Li, Wei & Markides, Christos N. & Zeng, Min & Peng, Jian, 2024. "4E evaluations of salt hydrate-based solar thermochemical heat transformer system used for domestic hot water production," Energy, Elsevier, vol. 286(C).
    14. Li, Wei & Zhang, Lianjie & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Thermochemical energy conversion behaviour in the corrugated heat storage unit with porous metal support," Energy, Elsevier, vol. 259(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mohamed Zbair & Simona Bennici, 2021. "Survey Summary on Salts Hydrates and Composites Used in Thermochemical Sorption Heat Storage: A Review," Energies, MDPI, vol. 14(11), pages 1-33, May.
    2. Mazur, Natalia & Blijlevens, Melian A.R. & Ruliaman, Rick & Fischer, Hartmut & Donkers, Pim & Meekes, Hugo & Vlieg, Elias & Adan, Olaf & Huinink, Henk, 2023. "Revisiting salt hydrate selection for domestic heat storage applications," Renewable Energy, Elsevier, vol. 218(C).
    3. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2022. "Salt hydrate–based gas-solid thermochemical energy storage: Current progress, challenges, and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    4. Hui Yang & Chengcheng Wang & Lige Tong & Shaowu Yin & Li Wang & Yulong Ding, 2023. "Salt Hydrate Adsorption Material-Based Thermochemical Energy Storage for Space Heating Application: A Review," Energies, MDPI, vol. 16(6), pages 1-54, March.
    5. Li, Wei & Klemeš, Jiří Jaromír & Wang, Qiuwang & Zeng, Min, 2020. "Development and characteristics analysis of salt-hydrate based composite sorbent for low-grade thermochemical energy storage," Renewable Energy, Elsevier, vol. 157(C), pages 920-940.
    6. Flegkas, S. & Birkelbach, F. & Winter, F. & Freiberger, N. & Werner, A., 2018. "Fluidized bed reactors for solid-gas thermochemical energy storage concepts - Modelling and process limitations," Energy, Elsevier, vol. 143(C), pages 615-623.
    7. Yi Yuan & Yingjie Li & Jianli Zhao, 2018. "Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review," Sustainability, MDPI, vol. 10(8), pages 1-24, July.
    8. Isye Hayatina & Amar Auckaili & Mohammed Farid, 2023. "Review on Salt Hydrate Thermochemical Heat Transformer," Energies, MDPI, vol. 16(12), pages 1-23, June.
    9. Schmidt, Matthias & Linder, Marc, 2017. "Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design," Applied Energy, Elsevier, vol. 203(C), pages 594-607.
    10. Bryan Li & Louise Buisson & Ruby-Jean Clark & Svetlana Ushak & Mohammed Farid, 2024. "A Eutectic Mixture of Calcium Chloride Hexahydrate and Bischofite with Promising Performance for Thermochemical Energy Storage," Energies, MDPI, vol. 17(3), pages 1-18, January.
    11. N’Tsoukpoe, Kokouvi Edem & Kuznik, Frédéric, 2021. "A reality check on long-term thermochemical heat storage for household applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    12. Bennici, Simona & Dutournié, Patrick & Cathalan, Jérémy & Zbair, Mohamed & Nguyen, Minh Hoang & Scuiller, Elliot & Vaulot, Cyril, 2022. "Heat storage: Hydration investigation of MgSO4/active carbon composites, from material development to domestic applications scenarios," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    13. Emanuela Mastronardo & Emanuele La Mazza & Davide Palamara & Elpida Piperopoulos & Daniela Iannazzo & Edoardo Proverbio & Candida Milone, 2022. "Organic Salt Hydrate as a Novel Paradigm for Thermal Energy Storage," Energies, MDPI, vol. 15(12), pages 1-13, June.
    14. Li, Wei & Markides, Christos N. & Zeng, Min & Peng, Jian, 2024. "4E evaluations of salt hydrate-based solar thermochemical heat transformer system used for domestic hot water production," Energy, Elsevier, vol. 286(C).
    15. Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    16. Gordeeva, L.G. & Aristov, Yu.I., 2019. "Adsorptive heat storage and amplification: New cycles and adsorbents," Energy, Elsevier, vol. 167(C), pages 440-453.
    17. Stylianos Flegkas & Felix Birkelbach & Franz Winter & Hans Groenewold & Andreas Werner, 2019. "Profitability Analysis and Capital Cost Estimation of a Thermochemical Energy Storage System Utilizing Fluidized Bed Reactors and the Reaction System MgO/Mg(OH) 2," Energies, MDPI, vol. 12(24), pages 1-16, December.
    18. Gao, J.T. & Xu, Z.Y. & Wang, R.Z., 2020. "Experimental study on a double-stage absorption solar thermal storage system with enhanced energy storage density," Applied Energy, Elsevier, vol. 262(C).
    19. N'Tsoukpoe, Kokouvi Edem & Restuccia, Giovanni & Schmidt, Thomas & Py, Xavier, 2014. "The size of sorbents in low pressure sorption or thermochemical energy storage processes," Energy, Elsevier, vol. 77(C), pages 983-998.
    20. Cabeza, Luisa F. & Solé, Aran & Barreneche, Camila, 2017. "Review on sorption materials and technologies for heat pumps and thermal energy storage," Renewable Energy, Elsevier, vol. 110(C), pages 3-39.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:150:y:2020:i:c:p:990-1000. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.