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Modification of magnesium and calcium hydroxides with salts: An efficient way to advanced materials for storage of middle-temperature heat

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  • Shkatulov, Alexandr
  • Aristov, Yuri

Abstract

Thermochemical heat storage can greatly contribute to higher efficiency of numerous industrial processes and units, especially based on renewable energy sources and/or polygeneration systems. Pure magnesium and calcium hydroxides are convenient materials for storage of middle temperature heat (250–500 °C), however, both suffer from kinetic impediments. In this work, we studied the doping effect of various salts in order to affect the dehydration dynamics of these hydroxides. The screening among the selected classes of salts, namely, chlorides, nitrates, sulphates and acetates of alkaline metals, showed a valuable possibility to a) improve the dehydration dynamics, and b) manage the dehydration temperature. Variation of the dehydration temperature was shown to depend on the salt nature and content. A strong effect of nitrates and acetates on the dehydration rate of both hydroxides was revealed. LiNO3 and XOOCCH3 (X = Li, Na, K) diminished the dehydration temperature of Mg(OH)2 by 50–80 K. Alike, though weaker, effect was found for Ca(OH)2 doped with KNO3 (c.a. 40K). The modification with salts is proven to be a promising way to get new advanced hydroxide-based materials for middle temperature heat storage with enhanced and controllable dehydration reactivity.

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  • Shkatulov, Alexandr & Aristov, Yuri, 2015. "Modification of magnesium and calcium hydroxides with salts: An efficient way to advanced materials for storage of middle-temperature heat," Energy, Elsevier, vol. 85(C), pages 667-676.
    • Handle: RePEc:eee:energy:v:85:y:2015:i:c:p:667-676
    DOI: 10.1016/j.energy.2015.04.004
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    1. Schmidt, Matthias & Gutierrez, Andrea & Linder, Marc, 2017. "Thermochemical energy storage with CaO/Ca(OH)2 – Experimental investigation of the thermal capability at low vapor pressures in a lab scale reactor," Applied Energy, Elsevier, vol. 188(C), pages 672-681.
    2. Mamani, V. & Gutiérrez, A. & Fernández, A.I. & Ushak, S., 2020. "Industrial carnallite-waste for thermochemical energy storage application," Applied Energy, Elsevier, vol. 265(C).
    3. Xia, B.Q. & Zhao, C.Y. & Yan, J. & Khosa, A.A., 2020. "Development of granular thermochemical heat storage composite based on calcium oxide," Renewable Energy, Elsevier, vol. 147(P1), pages 969-978.
    4. André, Laurie & Abanades, Stéphane & Flamant, Gilles, 2016. "Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 703-715.
    5. Li, T.X. & Xu, J.X. & Yan, T. & Wang, R.Z., 2016. "Development of sorption thermal battery for low-grade waste heat recovery and combined cold and heat energy storage," Energy, Elsevier, vol. 107(C), pages 347-359.
    6. Chen, Xiaoyi & Jin, Xiaogang & Liu, Zhimin & Ling, Xiang & Wang, Yan, 2018. "Experimental investigation on the CaO/CaCO3 thermochemical energy storage with SiO2 doping," Energy, Elsevier, vol. 155(C), pages 128-138.
    7. Seon Tae Kim & Haruka Miura & Hiroki Takasu & Yukitaka Kato & Alexandr Shkatulov & Yuri Aristov, 2019. "Adapting the MgO-CO 2 Working Pair for Thermochemical Energy Storage by Doping with Salts: Effect of the (LiK)NO 3 Content," Energies, MDPI, vol. 12(12), pages 1-13, June.
    8. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    9. Yupeng Feng & Xuhan Li & Haowen Wu & Chaoran Li & Man Zhang & Hairui Yang, 2023. "Critical Review of Ca(OH) 2 /CaO Thermochemical Energy Storage Materials," Energies, MDPI, vol. 16(7), pages 1-23, March.
    10. Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    11. Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Lanza, M. & Milone, C., 2016. "Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 181(C), pages 232-243.

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