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Experimental investigation on thermochemical heat storage using manganese chloride/ammonia

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  • Yan, T.
  • Wang, R.Z.
  • Li, T.X.

Abstract

Thermal energy storage plays a key role in the application of renewable energy and low-grade thermal energy. A laboratory test unit of thermochemical heat storage with manganese chloride (MnCl2) as the reactive salt and ammonia (NH3) as the working gas was constructed, in which expanded graphite was used to improve the heat and mass transfer performance of composite materials. The experimental campaigns show some promising conclusions on the heat storage performances of such a storage unit. With 3.78 kg of composite materials, the highest thermochemical heat storage density is about 1391 kJ/kg when the charging and discharging temperature is 174 °C and 50 °C, respectively. The corresponding volume density of thermochemical heat storage is 179 kWh/m3. The maximum of thermochemical heat storage efficiency obtained is 48%. The maximum of instantaneous thermochemical heat output power is more than 50 kW. The maximum for the average thermochemical heat output power reaches to 9.9 kW under the experimental conditions. The application prospects of such a thermochemical heat storage system are presented. The promising results have been gained, but some problems must be envisaged. The improvement measures to overcome these problems are also brought forward in order to make the thermochemical heat storage technology realize a successful application in practical systems.

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  • Yan, T. & Wang, R.Z. & Li, T.X., 2018. "Experimental investigation on thermochemical heat storage using manganese chloride/ammonia," Energy, Elsevier, vol. 143(C), pages 562-574.
    • Handle: RePEc:eee:energy:v:143:y:2018:i:c:p:562-574
    DOI: 10.1016/j.energy.2017.11.030
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    9. Wu, S. & Li, T.X. & Yan, T. & Wang, R.Z., 2019. "Advanced thermochemical resorption heat transformer for high-efficiency energy storage and heat transformation," Energy, Elsevier, vol. 175(C), pages 1222-1233.
    10. Jiang, L. & Liu, W. & Lin, Y.C. & Wang, R.Q. & Zhang, X.J. & Hu, M.K., 2022. "Hybrid thermochemical sorption seasonal storage for ultra-low temperature solar energy utilization," Energy, Elsevier, vol. 239(PB).
    11. Yan, Ting & Zhang, Hong & Yu, Nan & Li, Dong & Pan, Q.W., 2022. "Performance of thermochemical adsorption heat storage system based on MnCl2-NH3 working pair," Energy, Elsevier, vol. 239(PD).
    12. Palomba, V. & Lombardo, W. & Groβe, A. & Herrmann, R. & Nitsch, B. & Strehlow, A. & Bastian, R. & Sapienza, A. & Frazzica, A., 2020. "Evaluation of in-situ coated porous structures for hybrid heat pumps," Energy, Elsevier, vol. 209(C).
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    14. Zhang, Hong & Yan, Ting & Yu, Nan & Li, Z.H. & Pan, Q.W., 2022. "Sorption based long-term thermal energy storage with strontium chloride/ammonia," Energy, Elsevier, vol. 239(PD).

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