IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v181y2016icp232-243.html
   My bibliography  Save this article

Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps

Author

Listed:
  • Mastronardo, E.
  • Bonaccorsi, L.
  • Kato, Y.
  • Piperopoulos, E.
  • Lanza, M.
  • Milone, C.

Abstract

Newly developed hybrid materials made of magnesium hydroxide and carbon nanotubes were proposed as heat storage medium for MgO/H2O/Mg(OH)2 chemical heat pumps. Samples were synthesized by deposition-precipitation method varying the Mg(OH)2 load (32–52wt.%) and the type of carbon nanotubes, pristine or functionalized. The performances of the synthesized materials were evaluated by thermogravimetric analysis, which simulates the chemical heat pump cycle. The presence of the carbonaceous material positively affected the reaction performances, so that the hybrid materials showed improved heat storage/output capacity and faster heat output rate compared to pure Mg(OH)2. The functionalization treatment and a proper Mg(OH)2 load were fundamental to better the dispersibility of Mg(OH)2 into the carbon nanotubes bundles which in turn enhanced the thermochemical performance of the active material, fully exploiting for the first time its maximum potential heat storage capacity, that is ∼1300kJ/kgMg(OH)2, thus bringing the development of this technology to a level closer to its industrial application.

Suggested Citation

  • Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Lanza, M. & Milone, C., 2016. "Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 181(C), pages 232-243.
    • Handle: RePEc:eee:appene:v:181:y:2016:i:c:p:232-243
    DOI: 10.1016/j.apenergy.2016.08.041
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191631128X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.08.041?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Oluleye, Gbemi & Jobson, Megan & Smith, Robin & Perry, Simon J., 2016. "Evaluating the potential of process sites for waste heat recovery," Applied Energy, Elsevier, vol. 161(C), pages 627-646.
    2. Nagel, Thomas & Beckert, Steffen & Lehmann, Christoph & Gläser, Roger & Kolditz, Olaf, 2016. "Multi-physical continuum models of thermochemical heat storage and transformation in porous media and powder beds—A review," Applied Energy, Elsevier, vol. 178(C), pages 323-345.
    3. Zhang, P. & Ma, F. & Xiao, X., 2016. "Thermal energy storage and retrieval characteristics of a molten-salt latent heat thermal energy storage system," Applied Energy, Elsevier, vol. 173(C), pages 255-271.
    4. Shkatulov, Alexandr & Ryu, Junichi & Kato, Yukitaka & Aristov, Yury, 2012. "Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat," Energy, Elsevier, vol. 44(1), pages 1028-1034.
    5. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    6. Forman, Clemens & Muritala, Ibrahim Kolawole & Pardemann, Robert & Meyer, Bernd, 2016. "Estimating the global waste heat potential," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1568-1579.
    7. Paskevicius, M. & Sheppard, D.A. & Williamson, K. & Buckley, C.E., 2015. "Metal hydride thermal heat storage prototype for concentrating solar thermal power," Energy, Elsevier, vol. 88(C), pages 469-477.
    8. Yan, J. & Zhao, C.Y., 2016. "Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage," Applied Energy, Elsevier, vol. 175(C), pages 277-284.
    9. Bauer, Thomas & Pfleger, Nicole & Breidenbach, Nils & Eck, Markus & Laing, Doerte & Kaesche, Stefanie, 2013. "Material aspects of Solar Salt for sensible heat storage," Applied Energy, Elsevier, vol. 111(C), pages 1114-1119.
    10. Shkatulov, Alexandr & Aristov, Yuri, 2015. "Modification of magnesium and calcium hydroxides with salts: An efficient way to advanced materials for storage of middle-temperature heat," Energy, Elsevier, vol. 85(C), pages 667-676.
    11. Ma, Q. & Luo, L. & Wang, R.Z. & Sauce, G., 2009. "A review on transportation of heat energy over long distance: Exploratory development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1532-1540, August.
    12. Abedin, Ali Haji & Rosen, Marc A., 2012. "Assessment of a closed thermochemical energy storage using energy and exergy methods," Applied Energy, Elsevier, vol. 93(C), pages 18-23.
    13. Brückner, Sarah & Liu, Selina & Miró, Laia & Radspieler, Michael & Cabeza, Luisa F. & Lävemann, Eberhard, 2015. "Industrial waste heat recovery technologies: An economic analysis of heat transformation technologies," Applied Energy, Elsevier, vol. 151(C), pages 157-167.
    14. Prieto, Cristina & Cooper, Patrick & Fernández, A. Inés & Cabeza, Luisa F., 2016. "Review of technology: Thermochemical energy storage for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 909-929.
    15. Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Milone, C., 2016. "Efficiency improvement of heat storage materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 162(C), pages 31-39.
    16. Fais, Birgit & Sabio, Nagore & Strachan, Neil, 2016. "The critical role of the industrial sector in reaching long-term emission reduction, energy efficiency and renewable targets," Applied Energy, Elsevier, vol. 162(C), pages 699-712.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Takasu, Hiroki & Ryu, Junichi & Kato, Yukitaka, 2017. "Application of lithium orthosilicate for high-temperature thermochemical energy storage," Applied Energy, Elsevier, vol. 193(C), pages 74-83.
    2. Lutz, Michael & Bhouri, Maha & Linder, Marc & Bürger, Inga, 2019. "Adiabatic magnesium hydride system for hydrogen storage based on thermochemical heat storage: Numerical analysis of the dehydrogenation," Applied Energy, Elsevier, vol. 236(C), pages 1034-1048.
    3. Yan, J. & Pan, Z.H. & Zhao, C.Y., 2020. "Experimental study of MgO/Mg(OH)2 thermochemical heat storage with direct heat transfer mode," Applied Energy, Elsevier, vol. 275(C).
    4. Jae Yong Lee & Taesu Yim & Hyouck Ju Kim & Sungkook Hong & Doo Won Seo & Hong Soo Kim, 2019. "Investigation on Long Term Operation of Thermochemical Heat Storage with MgO-Based Composite Honeycombs," Energies, MDPI, vol. 12(7), pages 1-18, April.
    5. Taesu Yim & Hong Soo Kim & Jae Yong Lee, 2018. "Cyclic Assessment of Magnesium Oxide with Additives as a Thermochemical Material to Improve the Mechanical Strength and Chemical Reaction," Energies, MDPI, vol. 11(9), pages 1-15, September.
    6. Emanuela Mastronardo & Yukitaka Kato & Lucio Bonaccorsi & Elpida Piperopoulos & Candida Milone, 2017. "Thermochemical Storage of Middle Temperature Wasted Heat by Functionalized C/Mg(OH) 2 Hybrid Materials," Energies, MDPI, vol. 10(1), pages 1-16, January.
    7. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
    8. Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    2. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    3. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    4. Stylianos Flegkas & Felix Birkelbach & Franz Winter & Hans Groenewold & Andreas Werner, 2019. "Profitability Analysis and Capital Cost Estimation of a Thermochemical Energy Storage System Utilizing Fluidized Bed Reactors and the Reaction System MgO/Mg(OH) 2," Energies, MDPI, vol. 12(24), pages 1-16, December.
    5. Flegkas, S. & Birkelbach, F. & Winter, F. & Freiberger, N. & Werner, A., 2018. "Fluidized bed reactors for solid-gas thermochemical energy storage concepts - Modelling and process limitations," Energy, Elsevier, vol. 143(C), pages 615-623.
    6. Schmidt, Matthias & Linder, Marc, 2017. "Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design," Applied Energy, Elsevier, vol. 203(C), pages 594-607.
    7. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Rood, Mark, 2017. "Thermal energy storage systems for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 82-100.
    8. Dizaji, Hossein Beidaghy & Hosseini, Hannaneh, 2018. "A review of material screening in pure and mixed-metal oxide thermochemical energy storage (TCES) systems for concentrated solar power (CSP) applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 9-26.
    9. Pan, Z.H. & Zhao, C.Y., 2017. "Gas–solid thermochemical heat storage reactors for high-temperature applications," Energy, Elsevier, vol. 130(C), pages 155-173.
    10. Schmidt, Matthias & Gutierrez, Andrea & Linder, Marc, 2017. "Thermochemical energy storage with CaO/Ca(OH)2 – Experimental investigation of the thermal capability at low vapor pressures in a lab scale reactor," Applied Energy, Elsevier, vol. 188(C), pages 672-681.
    11. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
    12. Arias, I. & Cardemil, J. & Zarza, E. & Valenzuela, L. & Escobar, R., 2022. "Latest developments, assessments and research trends for next generation of concentrated solar power plants using liquid heat transfer fluids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    13. Gravogl, Georg & Knoll, Christian & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Harasek, Michael & Hradil, Klaudia & Werner, Andreas & Weinberger, Peter & Müller, D, 2019. "Pressure effects on the carbonation of MeO (Me = Co, Mn, Pb, Zn) for thermochemical energy storage," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    14. Yi Yuan & Yingjie Li & Jianli Zhao, 2018. "Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review," Sustainability, MDPI, vol. 10(8), pages 1-24, July.
    15. Gabriel Zsembinszki & Aran Solé & Camila Barreneche & Cristina Prieto & A. Inés Fernández & Luisa F. Cabeza, 2018. "Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants," Energies, MDPI, vol. 11(9), pages 1-23, September.
    16. Tescari, S. & Singh, A. & Agrafiotis, C. & de Oliveira, L. & Breuer, S. & Schlögl-Knothe, B. & Roeb, M. & Sattler, C., 2017. "Experimental evaluation of a pilot-scale thermochemical storage system for a concentrated solar power plant," Applied Energy, Elsevier, vol. 189(C), pages 66-75.
    17. Ye, H. & Tao, Y.B. & Wu, Z.H., 2022. "Performance improvement of packed bed thermochemical heat storage by enhancing heat transfer and vapor transmission," Applied Energy, Elsevier, vol. 326(C).
    18. Daniele Dadi & Vito Introna & Miriam Benedetti, 2022. "Decarbonization of Heat through Low-Temperature Waste Heat Recovery: Proposal of a Tool for the Preliminary Evaluation of Technologies in the Industrial Sector," Sustainability, MDPI, vol. 14(19), pages 1-28, October.
    19. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Castelain, Cathy, 2019. "Integration of a thermochemical energy storage system in a Rankine cycle driven by concentrating solar power: Energy and exergy analyses," Energy, Elsevier, vol. 167(C), pages 498-510.
    20. Zhao, Y. & Zhao, C.Y. & Markides, C.N. & Wang, H. & Li, W., 2020. "Medium- and high-temperature latent and thermochemical heat storage using metals and metallic compounds as heat storage media: A technical review," Applied Energy, Elsevier, vol. 280(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:181:y:2016:i:c:p:232-243. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.