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Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities

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  • Müller, Danny
  • Knoll, Christian
  • Gravogl, Georg
  • Artner, Werner
  • Welch, Jan M.
  • Eitenberger, Elisabeth
  • Friedbacher, Gernot
  • Schreiner, Manfred
  • Harasek, Michael
  • Hradil, Klaudia
  • Werner, Andreas
  • Miletich, Ronald
  • Weinberger, Peter

Abstract

Systematic variation of the dehydration temperature and time enables the preparation of highly reactive magnesium oxide for thermochemical energy storage purposes. The reactivity of the MgO, resulting from varying dehydration conditions has been studied by a comparative approach, including reactive surface area, particle morphology and reactivity towards rehydration. For the rehydration an in-situ powder X-Ray diffraction setup is used, allowing for continuous monitoring of Mg(OH)2 formation. The outcome of this investigation was subsequently applied to MgO from natural magnesites to assess the impact of impurities in the material on rehydration reactivity.

Suggested Citation

  • Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:253:y:2019:i:c:11
    DOI: 10.1016/j.apenergy.2019.113562
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    Cited by:

    1. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    2. Mamani, V. & Gutiérrez, A. & Fernández, A.I. & Ushak, S., 2020. "Industrial carnallite-waste for thermochemical energy storage application," Applied Energy, Elsevier, vol. 265(C).
    3. Yan, J. & Pan, Z.H. & Zhao, C.Y., 2020. "Experimental study of MgO/Mg(OH)2 thermochemical heat storage with direct heat transfer mode," Applied Energy, Elsevier, vol. 275(C).
    4. Saman Setoodeh Jahromy & Mudassar Azam & Christian Jordan & Michael Harasek & Franz Winter, 2021. "The Potential Use of Fly Ash from the Pulp and Paper Industry as Thermochemical Energy and CO 2 Storage Material," Energies, MDPI, vol. 14(11), pages 1-21, June.
    5. Georgios E. Arnaoutakis & Dimitris Al. Katsaprakakis, 2021. "Concentrating Solar Power Advances in Geometric Optics, Materials and System Integration," Energies, MDPI, vol. 14(19), pages 1-25, September.

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