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Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities

Author

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  • Müller, Danny
  • Knoll, Christian
  • Gravogl, Georg
  • Artner, Werner
  • Welch, Jan M.
  • Eitenberger, Elisabeth
  • Friedbacher, Gernot
  • Schreiner, Manfred
  • Harasek, Michael
  • Hradil, Klaudia
  • Werner, Andreas
  • Miletich, Ronald
  • Weinberger, Peter

Abstract

Systematic variation of the dehydration temperature and time enables the preparation of highly reactive magnesium oxide for thermochemical energy storage purposes. The reactivity of the MgO, resulting from varying dehydration conditions has been studied by a comparative approach, including reactive surface area, particle morphology and reactivity towards rehydration. For the rehydration an in-situ powder X-Ray diffraction setup is used, allowing for continuous monitoring of Mg(OH)2 formation. The outcome of this investigation was subsequently applied to MgO from natural magnesites to assess the impact of impurities in the material on rehydration reactivity.

Suggested Citation

  • Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:253:y:2019:i:c:11
    DOI: 10.1016/j.apenergy.2019.113562
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    1. Deutsch, Markus & Müller, Danny & Aumeyr, Christian & Jordan, Christian & Gierl-Mayer, Christian & Weinberger, Peter & Winter, Franz & Werner, Andreas, 2016. "Systematic search algorithm for potential thermochemical energy storage systems," Applied Energy, Elsevier, vol. 183(C), pages 113-120.
    2. Cabeza, L.F. & Castell, A. & Barreneche, C. & de Gracia, A. & Fernández, A.I., 2011. "Materials used as PCM in thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1675-1695, April.
    3. Bauer, Thomas & Pfleger, Nicole & Breidenbach, Nils & Eck, Markus & Laing, Doerte & Kaesche, Stefanie, 2013. "Material aspects of Solar Salt for sensible heat storage," Applied Energy, Elsevier, vol. 111(C), pages 1114-1119.
    4. Sebastian Schich & Byoung-Hwan Kim, 2011. "Systemic Financial Crises: How to Fund Resolution," OECD Journal: Financial Market Trends, OECD Publishing, vol. 2010(2), pages 1-34.
    5. Shkatulov, Alexandr & Ryu, Junichi & Kato, Yukitaka & Aristov, Yury, 2012. "Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat," Energy, Elsevier, vol. 44(1), pages 1028-1034.
    6. Kato, Y. & Sasaki, Y. & Yoshizawa, Y., 2005. "Magnesium oxide/water chemical heat pump to enhance energy utilization of a cogeneration system," Energy, Elsevier, vol. 30(11), pages 2144-2155.
    7. Shkatulov, Alexandr & Aristov, Yuri, 2015. "Modification of magnesium and calcium hydroxides with salts: An efficient way to advanced materials for storage of middle-temperature heat," Energy, Elsevier, vol. 85(C), pages 667-676.
    8. Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Lanza, M. & Milone, C., 2016. "Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 181(C), pages 232-243.
    9. André, Laurie & Abanades, Stéphane & Flamant, Gilles, 2016. "Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 703-715.
    10. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    11. Knoll, Christian & Müller, Danny & Artner, Werner & Welch, Jan M. & Werner, Andreas & Harasek, Michael & Weinberger, Peter, 2017. "Probing cycle stability and reversibility in thermochemical energy storage – CaC2O4·H2O as perfect match?," Applied Energy, Elsevier, vol. 187(C), pages 1-9.
    12. Yan, T. & Wang, R.Z. & Li, T.X. & Wang, L.W. & Fred, Ishugah T., 2015. "A review of promising candidate reactions for chemical heat storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 13-31.
    13. Yan, J. & Zhao, C.Y., 2016. "Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage," Applied Energy, Elsevier, vol. 175(C), pages 277-284.
    14. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
    15. Prieto, Cristina & Cooper, Patrick & Fernández, A. Inés & Cabeza, Luisa F., 2016. "Review of technology: Thermochemical energy storage for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 909-929.
    16. Emanuela Mastronardo & Yukitaka Kato & Lucio Bonaccorsi & Elpida Piperopoulos & Candida Milone, 2017. "Thermochemical Storage of Middle Temperature Wasted Heat by Functionalized C/Mg(OH) 2 Hybrid Materials," Energies, MDPI, vol. 10(1), pages 1-16, January.
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    Cited by:

    1. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    2. Mamani, V. & Gutiérrez, A. & Fernández, A.I. & Ushak, S., 2020. "Industrial carnallite-waste for thermochemical energy storage application," Applied Energy, Elsevier, vol. 265(C).
    3. Saman Setoodeh Jahromy & Mudassar Azam & Christian Jordan & Michael Harasek & Franz Winter, 2021. "The Potential Use of Fly Ash from the Pulp and Paper Industry as Thermochemical Energy and CO 2 Storage Material," Energies, MDPI, vol. 14(11), pages 1-21, June.
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    5. Yan, J. & Pan, Z.H. & Zhao, C.Y., 2020. "Experimental study of MgO/Mg(OH)2 thermochemical heat storage with direct heat transfer mode," Applied Energy, Elsevier, vol. 275(C).

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