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Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design

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  • Schmidt, Matthias
  • Linder, Marc

Abstract

Thermochemical storage systems offer in theory promising advantages for a wide range of applications. In particular the reversible reaction of calcium hydroxide to calcium oxide and water vapour is intensively discussed as an alternative storage solution for concentrated solar power plants. The material is cheap, environmentally friendly and discharge temperatures of the reaction of 600°C and above fit to the operating range of today’s power plants. However, experimental data on the operation of the system in lab scale and at load conditions comparable to the real application is rarely reported.

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  • Schmidt, Matthias & Linder, Marc, 2017. "Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design," Applied Energy, Elsevier, vol. 203(C), pages 594-607.
    • Handle: RePEc:eee:appene:v:203:y:2017:i:c:p:594-607
    DOI: 10.1016/j.apenergy.2017.06.063
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    Cited by:

    1. Ortiz, C. & Valverde, J.M. & Chacartegui, R. & Perez-Maqueda, L.A. & Giménez, P., 2019. "The Calcium-Looping (CaCO3/CaO) process for thermochemical energy storage in Concentrating Solar Power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    2. Stengler, Jana & Bürger, Inga & Linder, Marc, 2020. "Thermodynamic and kinetic investigations of the SrBr2 hydration and dehydration reactions for thermochemical energy storage and heat transformation," Applied Energy, Elsevier, vol. 277(C).
    3. Risthaus, Kai & Linder, Marc & Schmidt, Matthias, 2022. "Experimental investigation of a novel mechanically fluidized bed reactor for thermochemical energy storage with calcium hydroxide/calcium oxide," Applied Energy, Elsevier, vol. 315(C).
    4. Carro, A. & Chacartegui, R. & Ortiz, C. & Arcenegui-Troya, J. & Pérez-Maqueda, L.A. & Becerra, J.A., 2023. "Integration of calcium looping and calcium hydroxide thermochemical systems for energy storage and power production in concentrating solar power plants," Energy, Elsevier, vol. 283(C).
    5. Yan, J. & Pan, Z.H. & Zhao, C.Y., 2020. "Experimental study of MgO/Mg(OH)2 thermochemical heat storage with direct heat transfer mode," Applied Energy, Elsevier, vol. 275(C).
    6. Abanades, Stéphane & André, Laurie, 2018. "Design and demonstration of a high temperature solar-heated rotary tube reactor for continuous particles calcination," Applied Energy, Elsevier, vol. 212(C), pages 1310-1320.
    7. Wang, Mengyi & Chen, Li & Zhou, Yuhao & Tao, Wen-Quan, 2022. "Numerical simulation of the calcium hydroxide/calcium oxide system dehydration reaction in a shell-tube reactor," Applied Energy, Elsevier, vol. 312(C).
    8. Li, Caili & Li, Yingjie & Fang, Yi & Zhang, Chunxiao & Ren, Yu, 2024. "TiO2/MnFe2O4 co-modified alkaline papermaking waste for CaO-CaCO3 thermochemical energy storage," Applied Energy, Elsevier, vol. 362(C).
    9. Luo, Ji-Wang & Chen, Li & Wang, MengYi & Xia, Yang & Tao, WenQuan, 2022. "Particle-scale study of coupled physicochemical processes in Ca(OH)2 dehydration using the lattice Boltzmann method," Energy, Elsevier, vol. 250(C).
    10. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Castelain, Cathy, 2019. "Integration of a thermochemical energy storage system in a Rankine cycle driven by concentrating solar power: Energy and exergy analyses," Energy, Elsevier, vol. 167(C), pages 498-510.
    11. Jae Yong Lee & Taesu Yim & Hyouck Ju Kim & Sungkook Hong & Doo Won Seo & Hong Soo Kim, 2019. "Investigation on Long Term Operation of Thermochemical Heat Storage with MgO-Based Composite Honeycombs," Energies, MDPI, vol. 12(7), pages 1-18, April.
    12. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    13. Risthaus, Kai & Bürger, Inga & Linder, Marc & Schmidt, Matthias, 2020. "Numerical analysis of the hydration of calcium oxide in a fixed bed reactor based on lab-scale experiments," Applied Energy, Elsevier, vol. 261(C).
    14. Ma, Zhangke & Li, Yingjie & Zhang, Wan & Wang, Yuzhuo & Zhao, Jianli & Wang, Zeyan, 2020. "Energy storage and attrition performance of limestone under fluidization during CaO/CaCO3 cycles," Energy, Elsevier, vol. 207(C).
    15. Ortiz, C. & Romano, M.C. & Valverde, J.M. & Binotti, M. & Chacartegui, R., 2018. "Process integration of Calcium-Looping thermochemical energy storage system in concentrating solar power plants," Energy, Elsevier, vol. 155(C), pages 535-551.
    16. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
    17. Wang, Mengyi & Chen, Li & He, Pu & Tao, Wen-Quan, 2019. "Numerical study and enhancement of Ca(OH)2/CaO dehydration process with porous channels embedded in reactors," Energy, Elsevier, vol. 181(C), pages 417-428.
    18. Yi Yuan & Yingjie Li & Jianli Zhao, 2018. "Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review," Sustainability, MDPI, vol. 10(8), pages 1-24, July.
    19. Funayama, Shigehiko & Takasu, Hiroki & Kim, Seon Tae & Kato, Yukitaka, 2020. "Thermochemical storage performance of a packed bed of calcium hydroxide composite with a silicon-based ceramic honeycomb support," Energy, Elsevier, vol. 201(C).
    20. Vecchi, Andrea & Sciacovelli, Adriano, 2023. "Long-duration thermo-mechanical energy storage – Present and future techno-economic competitiveness," Applied Energy, Elsevier, vol. 334(C).

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