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Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design

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  • Schmidt, Matthias
  • Linder, Marc

Abstract

Thermochemical storage systems offer in theory promising advantages for a wide range of applications. In particular the reversible reaction of calcium hydroxide to calcium oxide and water vapour is intensively discussed as an alternative storage solution for concentrated solar power plants. The material is cheap, environmentally friendly and discharge temperatures of the reaction of 600°C and above fit to the operating range of today’s power plants. However, experimental data on the operation of the system in lab scale and at load conditions comparable to the real application is rarely reported.

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  • Schmidt, Matthias & Linder, Marc, 2017. "Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design," Applied Energy, Elsevier, vol. 203(C), pages 594-607.
    • Handle: RePEc:eee:appene:v:203:y:2017:i:c:p:594-607
    DOI: 10.1016/j.apenergy.2017.06.063
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    as
    1. Deutsch, Markus & Müller, Danny & Aumeyr, Christian & Jordan, Christian & Gierl-Mayer, Christian & Weinberger, Peter & Winter, Franz & Werner, Andreas, 2016. "Systematic search algorithm for potential thermochemical energy storage systems," Applied Energy, Elsevier, vol. 183(C), pages 113-120.
    2. Medrano, Marc & Gil, Antoni & Martorell, Ingrid & Potau, Xavi & Cabeza, Luisa F., 2010. "State of the art on high-temperature thermal energy storage for power generation. Part 2--Case studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 56-72, January.
    3. Chacartegui, R. & Alovisio, A. & Ortiz, C. & Valverde, J.M. & Verda, V. & Becerra, J.A., 2016. "Thermochemical energy storage of concentrated solar power by integration of the calcium looping process and a CO2 power cycle," Applied Energy, Elsevier, vol. 173(C), pages 589-605.
    4. Aydin, Devrim & Casey, Sean P. & Riffat, Saffa, 2015. "The latest advancements on thermochemical heat storage systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 356-367.
    5. Shkatulov, Alexandr & Ryu, Junichi & Kato, Yukitaka & Aristov, Yury, 2012. "Composite material “Mg(OH)2/vermiculite”: A promising new candidate for storage of middle temperature heat," Energy, Elsevier, vol. 44(1), pages 1028-1034.
    6. Schmidt, Matthias & Gutierrez, Andrea & Linder, Marc, 2017. "Thermochemical energy storage with CaO/Ca(OH)2 – Experimental investigation of the thermal capability at low vapor pressures in a lab scale reactor," Applied Energy, Elsevier, vol. 188(C), pages 672-681.
    7. Liu, Ming & Steven Tay, N.H. & Bell, Stuart & Belusko, Martin & Jacob, Rhys & Will, Geoffrey & Saman, Wasim & Bruno, Frank, 2016. "Review on concentrating solar power plants and new developments in high temperature thermal energy storage technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 1411-1432.
    8. Zhang, H.L. & Baeyens, J. & Degrève, J. & Cacères, G., 2013. "Concentrated solar power plants: Review and design methodology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 466-481.
    9. Meng, Z.N. & Zhang, P., 2017. "Experimental and numerical investigation of a tube-in-tank latent thermal energy storage unit using composite PCM," Applied Energy, Elsevier, vol. 190(C), pages 524-539.
    10. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    11. Cabeza, Luisa F. & Solé, Aran & Fontanet, Xavier & Barreneche, Camila & Jové, Aleix & Gallas, Manuel & Prieto, Cristina & Fernández, A. Inés, 2017. "Thermochemical energy storage by consecutive reactions for higher efficient concentrated solar power plants (CSP): Proof of concept," Applied Energy, Elsevier, vol. 185(P1), pages 836-845.
    12. Miró, Laia & Gasia, Jaume & Cabeza, Luisa F., 2016. "Thermal energy storage (TES) for industrial waste heat (IWH) recovery: A review," Applied Energy, Elsevier, vol. 179(C), pages 284-301.
    13. Xu, Yang & Ren, Qinlong & Zheng, Zhang-Jing & He, Ya-Ling, 2017. "Evaluation and optimization of melting performance for a latent heat thermal energy storage unit partially filled with porous media," Applied Energy, Elsevier, vol. 193(C), pages 84-95.
    14. Yan, J. & Zhao, C.Y., 2016. "Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage," Applied Energy, Elsevier, vol. 175(C), pages 277-284.
    15. Prieto, Cristina & Cooper, Patrick & Fernández, A. Inés & Cabeza, Luisa F., 2016. "Review of technology: Thermochemical energy storage for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 909-929.
    16. Nagel, T. & Shao, H. & Roßkopf, C. & Linder, M. & Wörner, A. & Kolditz, O., 2014. "The influence of gas–solid reaction kinetics in models of thermochemical heat storage under monotonic and cyclic loading," Applied Energy, Elsevier, vol. 136(C), pages 289-302.
    17. Gil, Antoni & Medrano, Marc & Martorell, Ingrid & Lázaro, Ana & Dolado, Pablo & Zalba, Belén & Cabeza, Luisa F., 2010. "State of the art on high temperature thermal energy storage for power generation. Part 1--Concepts, materials and modellization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 31-55, January.
    18. Wang, Wenqing & Kolditz, Olaf & Nagel, Thomas, 2017. "Parallel finite element modelling of multi-physical processes in thermochemical energy storage devices," Applied Energy, Elsevier, vol. 185(P2), pages 1954-1964.
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    Cited by:

    1. Ortiz, C. & Valverde, J.M. & Chacartegui, R. & Perez-Maqueda, L.A. & Giménez, P., 2019. "The Calcium-Looping (CaCO3/CaO) process for thermochemical energy storage in Concentrating Solar Power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    2. Wang, Mengyi & Chen, Li & Zhou, Yuhao & Tao, Wen-Quan, 2022. "Numerical simulation of the calcium hydroxide/calcium oxide system dehydration reaction in a shell-tube reactor," Applied Energy, Elsevier, vol. 312(C).
    3. Li, Caili & Li, Yingjie & Fang, Yi & Zhang, Chunxiao & Ren, Yu, 2024. "TiO2/MnFe2O4 co-modified alkaline papermaking waste for CaO-CaCO3 thermochemical energy storage," Applied Energy, Elsevier, vol. 362(C).
    4. Luo, Ji-Wang & Chen, Li & Wang, MengYi & Xia, Yang & Tao, WenQuan, 2022. "Particle-scale study of coupled physicochemical processes in Ca(OH)2 dehydration using the lattice Boltzmann method," Energy, Elsevier, vol. 250(C).
    5. Yi Yuan & Yingjie Li & Jianli Zhao, 2018. "Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review," Sustainability, MDPI, vol. 10(8), pages 1-24, July.
    6. Stengler, Jana & Bürger, Inga & Linder, Marc, 2020. "Thermodynamic and kinetic investigations of the SrBr2 hydration and dehydration reactions for thermochemical energy storage and heat transformation," Applied Energy, Elsevier, vol. 277(C).
    7. Risthaus, Kai & Linder, Marc & Schmidt, Matthias, 2022. "Experimental investigation of a novel mechanically fluidized bed reactor for thermochemical energy storage with calcium hydroxide/calcium oxide," Applied Energy, Elsevier, vol. 315(C).
    8. Carro, A. & Chacartegui, R. & Ortiz, C. & Arcenegui-Troya, J. & Pérez-Maqueda, L.A. & Becerra, J.A., 2023. "Integration of calcium looping and calcium hydroxide thermochemical systems for energy storage and power production in concentrating solar power plants," Energy, Elsevier, vol. 283(C).
    9. Yan, J. & Pan, Z.H. & Zhao, C.Y., 2020. "Experimental study of MgO/Mg(OH)2 thermochemical heat storage with direct heat transfer mode," Applied Energy, Elsevier, vol. 275(C).
    10. Abanades, Stéphane & André, Laurie, 2018. "Design and demonstration of a high temperature solar-heated rotary tube reactor for continuous particles calcination," Applied Energy, Elsevier, vol. 212(C), pages 1310-1320.
    11. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Castelain, Cathy, 2019. "Integration of a thermochemical energy storage system in a Rankine cycle driven by concentrating solar power: Energy and exergy analyses," Energy, Elsevier, vol. 167(C), pages 498-510.
    12. Jae Yong Lee & Taesu Yim & Hyouck Ju Kim & Sungkook Hong & Doo Won Seo & Hong Soo Kim, 2019. "Investigation on Long Term Operation of Thermochemical Heat Storage with MgO-Based Composite Honeycombs," Energies, MDPI, vol. 12(7), pages 1-18, April.
    13. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    14. Risthaus, Kai & Bürger, Inga & Linder, Marc & Schmidt, Matthias, 2020. "Numerical analysis of the hydration of calcium oxide in a fixed bed reactor based on lab-scale experiments," Applied Energy, Elsevier, vol. 261(C).
    15. Ma, Zhangke & Li, Yingjie & Zhang, Wan & Wang, Yuzhuo & Zhao, Jianli & Wang, Zeyan, 2020. "Energy storage and attrition performance of limestone under fluidization during CaO/CaCO3 cycles," Energy, Elsevier, vol. 207(C).
    16. Ortiz, C. & Romano, M.C. & Valverde, J.M. & Binotti, M. & Chacartegui, R., 2018. "Process integration of Calcium-Looping thermochemical energy storage system in concentrating solar power plants," Energy, Elsevier, vol. 155(C), pages 535-551.
    17. Piperopoulos, Elpida & Mastronardo, Emanuela & Fazio, Marianna & Lanza, Maurizio & Galvagno, Signorino & Milone, Candida, 2018. "Enhancing the volumetric heat storage capacity of Mg(OH)2 by the addition of a cationic surfactant during its synthesis," Applied Energy, Elsevier, vol. 215(C), pages 512-522.
    18. Wang, Mengyi & Chen, Li & He, Pu & Tao, Wen-Quan, 2019. "Numerical study and enhancement of Ca(OH)2/CaO dehydration process with porous channels embedded in reactors," Energy, Elsevier, vol. 181(C), pages 417-428.
    19. Funayama, Shigehiko & Takasu, Hiroki & Kim, Seon Tae & Kato, Yukitaka, 2020. "Thermochemical storage performance of a packed bed of calcium hydroxide composite with a silicon-based ceramic honeycomb support," Energy, Elsevier, vol. 201(C).
    20. Vecchi, Andrea & Sciacovelli, Adriano, 2023. "Long-duration thermo-mechanical energy storage – Present and future techno-economic competitiveness," Applied Energy, Elsevier, vol. 334(C).

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