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Advanced rechargeable zinc-air battery with parameter optimization

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  • Wang, Keliang
  • Pei, Pucheng
  • Wang, Yichun
  • Liao, Cheng
  • Wang, Wei
  • Huang, Shangwei

Abstract

Zinc-air batteries will be a promising candidate for storage energy and power supply due to their high specific energy, environmental compatibility, and economic availability. However, the problem of cycle life of rechargeable zinc-air battery remains unresolved mainly because of dendrite growth of electrodeposited zinc and performance degradation of air electrode. Here we show that rechargeable zinc-air battery with an optimized structure can stably run at large current densities, where air electrode is connected to the charging electrode through a stainless steel frame, and the effective area of charging electrode is larger than that of zinc electrode by way of a trapezoidal structure. This battery structure can control morphological change of zinc electrode and monitor dendrite growth without increasing the battery volume. The results demonstrate that the charge-discharge efficiency of rechargeable zinc-air battery can be improved by nickel foam as gas diffusion layer of air electrode, calcium oxide additive to the electrolyte, or a permanent magnet in parallel with the electrode. The lifetime of rechargeable zinc-air battery can be extended by electrolyte flow or battery structure optimization. These findings will be available for other metal-air batteries and electrolytic metal industry.

Suggested Citation

  • Wang, Keliang & Pei, Pucheng & Wang, Yichun & Liao, Cheng & Wang, Wei & Huang, Shangwei, 2018. "Advanced rechargeable zinc-air battery with parameter optimization," Applied Energy, Elsevier, vol. 225(C), pages 848-856.
    • Handle: RePEc:eee:appene:v:225:y:2018:i:c:p:848-856
    DOI: 10.1016/j.apenergy.2018.05.071
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    References listed on IDEAS

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    Cited by:

    1. Thangavel Sangeetha & Po-Tuan Chen & Wu-Fu Cheng & Wei-Mon Yan & K. David Huang, 2019. "Optimization of the Electrolyte Parameters and Components in Zinc Particle Fuel Cells," Energies, MDPI, vol. 12(6), pages 1-13, March.
    2. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    3. Sangeetha, Thangavel & Chen, Po-Tuan & Yan, Wei-Mon & Huang, K. David, 2020. "Enhancement of air-flow management in Zn-air fuel cells by the optimization of air-flow parameters," Energy, Elsevier, vol. 197(C).
    4. Wang, Yifei & Kwok, Holly Y.H. & Pan, Wending & Zhang, Huimin & Lu, Xu & Leung, Dennis Y.C., 2019. "Parametric study and optimization of a low-cost paper-based Al-air battery with corrosion inhibition ability," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    5. Xu, Nengneng & Zhang, Yanxing & Wang, Yudong & Wang, Min & Su, Tianshun & Coco, Cameron A. & Qiao, Jinli & Zhou, Xiao-Dong, 2020. "Hierarchical bifunctional catalysts with tailored catalytic activity for high-energy rechargeable Zn-air batteries," Applied Energy, Elsevier, vol. 279(C).
    6. Pan, Lyuming & Chen, Dongfang & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "A novel structural design of air cathodes expanding three-phase reaction interfaces for zinc-air batteries," Applied Energy, Elsevier, vol. 290(C).
    7. Wei, Manhui & Wang, Keliang & Pei, Pucheng & Zuo, Yayu & Zhong, Liping & Shang, Nuo & Wang, Hengwei & Chen, Junfeng & Zhang, Pengfei & Chen, Zhuo, 2022. "An enhanced-performance Al-air battery optimizing the alkaline electrolyte with a strong Lewis acid ZnCl2," Applied Energy, Elsevier, vol. 324(C).
    8. Trocino, Stefano & Lo Faro, Massimiliano & Zignani, Sabrina Campagna & Antonucci, Vincenzo & Aricò, Antonino Salvatore, 2019. "High performance solid-state iron-air rechargeable ceramic battery operating at intermediate temperatures (500–650 °C)," Applied Energy, Elsevier, vol. 233, pages 386-394.
    9. Bonhyun Gu & Heeyun Lee & Changbeom Kang & Donghwan Sung & Sanghoon Lee & Sunghyun Yun & Sung Kwan Park & Gu-Young Cho & Namwook Kim & Suk Won Cha, 2020. "Receding Horizon Control of Cooling Systems for Large-Size Uninterruptible Power Supply Based on a Metal-Air Battery System," Energies, MDPI, vol. 13(7), pages 1-15, April.

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