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Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery

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  • Di Blasi, O.
  • Briguglio, N.
  • Busacca, C.
  • Ferraro, M.
  • Antonucci, V.
  • Di Blasi, A.

Abstract

Thermically treated graphene oxides (TT-GOs) are synthesized at different temperatures, 100°C, 150°C, 200°C and 300°C in a reducing environment (20% H2/He) and investigated as electrode materials for vanadium redox flow battery (VRFB) applications. The treated graphene oxide-based electrodes are prepared by the wet impregnation method using carbon felt (CF) as support. The main aim is to achieve a suitable distribution of the dispersed graphene oxides on the CF surface in order to investigate the electrocatalytic activity for the VO2+/VO2+ and V2+/V3+ redox reactions in the perspective of a feasible large area electrodes scale-up for battery configuration of practical interest. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) are carried out in a three electrode half-cell to characterize the electrochemical properties of the TT-GO-based electrodes. Physico-chemical characterizations are carried out to corroborate the electrochemical results. The TT-GO sample treated at 100°C (TT-GO-100) shows the highest electrocatalytic activity in terms of peak to peak separation (ΔE=0.03V) and current density intensity (∼0.24Acm−2 at 30mV/s) both toward the VO2+/VO2+ and V2+/V3+ redox reactions. This result is correlated to the presence of hydroxyl (OH) and carboxyl (COOH) species that act as active sites. A valid candidate is individuated as effective anode and cathode electrode in the perspective of electrodes scale-up for battery configuration of practical interest.

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  • Di Blasi, O. & Briguglio, N. & Busacca, C. & Ferraro, M. & Antonucci, V. & Di Blasi, A., 2015. "Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery," Applied Energy, Elsevier, vol. 147(C), pages 74-81.
    • Handle: RePEc:eee:appene:v:147:y:2015:i:c:p:74-81
    DOI: 10.1016/j.apenergy.2015.02.073
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    1. Flox, Cristina & Skoumal, Marcel & Rubio-Garcia, Javier & Andreu, Teresa & Morante, Juan Ramón, 2013. "Strategies for enhancing electrochemical activity of carbon-based electrodes for all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 109(C), pages 344-351.
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    2. Yang, WeiWei & Liu, JianGuo & Zhang, Xiang & Chen, Liang & Zhou, Yong & Zou, ZhiGang, 2017. "Ultrathin LiFePO4 nanosheets self-assembled with reduced graphene oxide applied in high rate lithium ion batteries for energy storage," Applied Energy, Elsevier, vol. 195(C), pages 1079-1085.
    3. Wei, L. & Zeng, L. & Wu, M.C. & Fan, X.Z. & Zhao, T.S., 2019. "Seawater as an alternative to deionized water for electrolyte preparations in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
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    5. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Experimental study on the performance of a vanadium redox flow battery with non-uniformly compressed carbon felt electrode," Applied Energy, Elsevier, vol. 213(C), pages 293-305.
    6. Wang, Shaoliang & Xu, Zeyu & Wu, Xiaoliang & Zhao, Huan & Zhao, Jinling & Liu, Jianguo & Yan, Chuanwei & Fan, Xinzhuang, 2020. "Analyses and optimization of electrolyte concentration on the electrochemical performance of iron-chromium flow battery," Applied Energy, Elsevier, vol. 271(C).
    7. Wei, L. & Zhao, T.S. & Xu, Q. & Zhou, X.L. & Zhang, Z.H., 2017. "In-situ investigation of hydrogen evolution behavior in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 190(C), pages 1112-1118.
    8. Di Blasi, A. & Busaccaa, C. & Di Blasia, O. & Briguglioa, N. & Squadritoa, G. & Antonuccia, V., 2017. "Synthesis of flexible electrodes based on electrospun carbon nanofibers with Mn3O4 nanoparticles for vanadium redox flow battery application," Applied Energy, Elsevier, vol. 190(C), pages 165-171.
    9. Guarnieri, Massimo & Trovò, Andrea & D'Anzi, Angelo & Alotto, Piergiorgio, 2018. "Developing vanadium redox flow technology on a 9-kW 26-kWh industrial scale test facility: Design review and early experiments," Applied Energy, Elsevier, vol. 230(C), pages 1425-1434.
    10. Wei, L. & Zhao, T.S. & Zeng, L. & Zhou, X.L. & Zeng, Y.K., 2016. "Copper nanoparticle-deposited graphite felt electrodes for all vanadium redox flow batteries," Applied Energy, Elsevier, vol. 180(C), pages 386-391.
    11. Jiang, H.R. & Wu, M.C. & Ren, Y.X. & Shyy, W. & Zhao, T.S., 2018. "Towards a uniform distribution of zinc in the negative electrode for zinc bromine flow batteries," Applied Energy, Elsevier, vol. 213(C), pages 366-374.

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