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Strategies for enhancing electrochemical activity of carbon-based electrodes for all-vanadium redox flow batteries

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  • Flox, Cristina
  • Skoumal, Marcel
  • Rubio-Garcia, Javier
  • Andreu, Teresa
  • Morante, Juan Ramón

Abstract

Two strategies for improving the electroactivity towards VO2+/VO2+ redox pair, the limiting process in all-vanadium redox flow batteries (VFBs), were presented. CuPt3 nanoparticles supported onto graphene substrate and nitrogen and oxygen polyacrylonitrile (PAN)-functionalized electrodes materials have been evaluated. The morphology, composition, electrochemical properties of all electrodes prepared was characterized with field emission-scanning electrode microscopy, X-ray photoelectron spectroscopy, cyclic voltammetry, electrochemical impedance spectroscopy and cell charge–discharge test. The presence of the CuPt3 nanocubes and nitrogen and oxygen functionalities enhance the electrocatalytic activity of the electrodes materials accelerating the oxygen and electron transfer processes. The battery performance was also evaluated using PAN-functionalized electrodes exhibiting a high of energy efficiency of 84% (at current density 20mAcm−2) up to 30th cycle, indicating a promising alternative for improving the VFB.

Suggested Citation

  • Flox, Cristina & Skoumal, Marcel & Rubio-Garcia, Javier & Andreu, Teresa & Morante, Juan Ramón, 2013. "Strategies for enhancing electrochemical activity of carbon-based electrodes for all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 109(C), pages 344-351.
    • Handle: RePEc:eee:appene:v:109:y:2013:i:c:p:344-351
    DOI: 10.1016/j.apenergy.2013.02.001
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    6. Wang, Tao & Fu, Jiahui & Zheng, Menglian & Yu, Zitao, 2018. "Dynamic control strategy for the electrolyte flow rate of vanadium redox flow batteries," Applied Energy, Elsevier, vol. 227(C), pages 613-623.
    7. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Experimental study on the performance of a vanadium redox flow battery with non-uniformly compressed carbon felt electrode," Applied Energy, Elsevier, vol. 213(C), pages 293-305.
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    9. Li, Li & Nikiforidis, Georgios & Leung, Michael K.H. & Daoud, Walid A., 2016. "Vanadium microfluidic fuel cell with novel multi-layer flow-through porous electrodes: Model, simulations and experiments," Applied Energy, Elsevier, vol. 177(C), pages 729-739.
    10. Di Blasi, O. & Briguglio, N. & Busacca, C. & Ferraro, M. & Antonucci, V. & Di Blasi, A., 2015. "Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery," Applied Energy, Elsevier, vol. 147(C), pages 74-81.
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    12. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    13. Mohamed, M.R. & Leung, P.K. & Sulaiman, M.H., 2015. "Performance characterization of a vanadium redox flow battery at different operating parameters under a standardized test-bed system," Applied Energy, Elsevier, vol. 137(C), pages 402-412.
    14. Di Blasi, A. & Briguglio, N. & Di Blasi, O. & Antonucci, V., 2014. "Charge–discharge performance of carbon fiber-based electrodes in single cell and short stack for vanadium redox flow battery," Applied Energy, Elsevier, vol. 125(C), pages 114-122.
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