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A study of the Ce3+/Ce4+ redox couple in sulfamic acid for redox battery application

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  • Xiong, Fengjiao
  • Zhou, Debi
  • Xie, Zhipeng
  • Chen, Yunyang

Abstract

The present paper reports a cerium sulfamate electrolyte for use in redox battery. The electrochemical behavior of Ce3+/Ce4+ in sulfamic acid (SA) media has been investigated using linear-sweep voltammetry and cyclic voltammetry. The formal potential of the Ce3+/Ce4+ redox couple in SA is approximately 1.52V vs. NHE. The exchange current density and standard rate constant of the Ce3+/Ce4+ redox reaction on platinum electrode in SA are determined as 5.95×10−4Acm−2 and 4.95×10−5cms−1 respectively. The diffusion coefficient of Ce3+ in SA is 5.93×10−6cm2s−1. The conductivity of cerium(III) sulfamate solution is improved significantly by adding NH4+. A zinc–cerium test cell with Ce3+/Ce4+ sulfamate solution as the positive electrolyte is constructed and the charge-discharge performance is evaluated. The coulombic efficiency of the Zn–Ce cell is calculated to be 90%. The preliminary exploration shows that the cerium sulfamate electrolyte is promising for redox battery application and is worthy of further study.

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  • Xiong, Fengjiao & Zhou, Debi & Xie, Zhipeng & Chen, Yunyang, 2012. "A study of the Ce3+/Ce4+ redox couple in sulfamic acid for redox battery application," Applied Energy, Elsevier, vol. 99(C), pages 291-296.
    • Handle: RePEc:eee:appene:v:99:y:2012:i:c:p:291-296
    DOI: 10.1016/j.apenergy.2012.05.021
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    2. Arenas, Luis F. & Loh, Adeline & Trudgeon, David P. & Li, Xiaohong & Ponce de León, Carlos & Walsh, Frank C., 2018. "The characteristics and performance of hybrid redox flow batteries with zinc negative electrodes for energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 992-1016.
    3. Wu, Maochun & Liu, Mingyao & Long, Guifa & Wan, Kai & Liang, Zhenxing & Zhao, Tim S., 2014. "A novel high-energy-density positive electrolyte with multiple redox couples for redox flow batteries," Applied Energy, Elsevier, vol. 136(C), pages 576-581.
    4. Shang, Wenxu & Yu, Wentao & Xiao, Xu & Ma, Yanyi & Chen, Ziqi & Ni, Meng & Tan, Peng, 2022. "Optimizing the charging protocol to address the self-discharge issues in rechargeable alkaline Zn-Co batteries," Applied Energy, Elsevier, vol. 308(C).
    5. Flox, Cristina & Skoumal, Marcel & Rubio-Garcia, Javier & Andreu, Teresa & Morante, Juan Ramón, 2013. "Strategies for enhancing electrochemical activity of carbon-based electrodes for all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 109(C), pages 344-351.
    6. Di Blasi, O. & Briguglio, N. & Busacca, C. & Ferraro, M. & Antonucci, V. & Di Blasi, A., 2015. "Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery," Applied Energy, Elsevier, vol. 147(C), pages 74-81.
    7. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    8. Di Blasi, A. & Briguglio, N. & Di Blasi, O. & Antonucci, V., 2014. "Charge–discharge performance of carbon fiber-based electrodes in single cell and short stack for vanadium redox flow battery," Applied Energy, Elsevier, vol. 125(C), pages 114-122.

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