IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v190y2017icp165-171.html
   My bibliography  Save this article

Synthesis of flexible electrodes based on electrospun carbon nanofibers with Mn3O4 nanoparticles for vanadium redox flow battery application

Author

Listed:
  • Di Blasi, A.
  • Busaccaa, C.
  • Di Blasia, O.
  • Briguglioa, N.
  • Squadritoa, G.
  • Antonuccia, V.

Abstract

Flexible carbon nanofiber (CNF)-based electrodes and CNF with a 20% of manganese oxide incorporated (Mn3O4/CNF) are prepared by using the electrospinning method for vanadium redox flow battery (VRFB) application. A blend consisting of manganese acetate (Mn(OAc)2) and polyacrilonitrile (PAN) is electrospun and successively subjected to different thermal treatments in which the growth of Mn3O4 particles and CNFs occurred together guaranteeing an appropriate electron conductivity for electrodes thus synthesized. Cyclic voltammetry (CV) measurements show an interesting electrocatalytic activity toward the [VO]2+/[VO2]+ as well as the V2+/V3+ redox reactions for the Mn3O4/CNF electrospun sample. Charge-discharge tests, carried out at 80mAcm−2, show a state of charge (SOC) and a depth of discharge (DoD) of 81% and 73%, respectively, for the cells assembled with Mn3O4/CNF electrodes. These data are indicative of a high vanadium active species utilization thanks to the better electrocatalytic activity at high current densities. Furthermore, the cell with Mn3O4/CNF shows EE values of about 81% (88% of VE and 92% of CE) vs. 70% (75% of VE and 93% of CE) with respect to a commercial carbon felt (CF) electrode used for comparison. These results are attributable to the higher oxygen species content as well as the improved electron conductivity due to the synergetic effect of the more graphitic carbon and to the structural defects within the Mn3O4 spinel structure.

Suggested Citation

  • Di Blasi, A. & Busaccaa, C. & Di Blasia, O. & Briguglioa, N. & Squadritoa, G. & Antonuccia, V., 2017. "Synthesis of flexible electrodes based on electrospun carbon nanofibers with Mn3O4 nanoparticles for vanadium redox flow battery application," Applied Energy, Elsevier, vol. 190(C), pages 165-171.
    • Handle: RePEc:eee:appene:v:190:y:2017:i:c:p:165-171
    DOI: 10.1016/j.apenergy.2016.12.129
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916319122
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.12.129?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Shah, Rakibuzzaman & Mithulananthan, N. & Bansal, R.C., 2012. "Damping performance analysis of battery energy storage system, ultracapacitor and shunt capacitor with large-scale photovoltaic plants," Applied Energy, Elsevier, vol. 96(C), pages 235-244.
    2. Landgrebe, Albert R. & Donley, Samuel W., 1983. "Battery storage in residential applications of energy from photovoltaic sources," Applied Energy, Elsevier, vol. 15(2), pages 127-137.
    3. Di Blasi, O. & Briguglio, N. & Busacca, C. & Ferraro, M. & Antonucci, V. & Di Blasi, A., 2015. "Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery," Applied Energy, Elsevier, vol. 147(C), pages 74-81.
    4. Kim, Sun Ung & Monroe, Charles W., 2013. "Increasing the rate capability of batteries with electrolyte flow," Applied Energy, Elsevier, vol. 103(C), pages 207-211.
    5. Xiong, Fengjiao & Zhou, Debi & Xie, Zhipeng & Chen, Yunyang, 2012. "A study of the Ce3+/Ce4+ redox couple in sulfamic acid for redox battery application," Applied Energy, Elsevier, vol. 99(C), pages 291-296.
    6. Flox, Cristina & Skoumal, Marcel & Rubio-Garcia, Javier & Andreu, Teresa & Morante, Juan Ramón, 2013. "Strategies for enhancing electrochemical activity of carbon-based electrodes for all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 109(C), pages 344-351.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wei, L. & Zeng, L. & Wu, M.C. & Fan, X.Z. & Zhao, T.S., 2019. "Seawater as an alternative to deionized water for electrolyte preparations in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    2. Shang, Wenxu & Yu, Wentao & Xiao, Xu & Ma, Yanyi & Chen, Ziqi & Ni, Meng & Tan, Peng, 2022. "Optimizing the charging protocol to address the self-discharge issues in rechargeable alkaline Zn-Co batteries," Applied Energy, Elsevier, vol. 308(C).
    3. Kim, Jungmyung & Park, Heesung, 2017. "Experimental analysis of discharge characteristics in vanadium redox flow battery," Applied Energy, Elsevier, vol. 206(C), pages 451-457.
    4. Yue, Meng & Lv, Zhiqiang & Zheng, Qiong & Li, Xianfeng & Zhang, Huamin, 2019. "Battery assembly optimization: Tailoring the electrode compression ratio based on the polarization analysis in vanadium flow batteries," Applied Energy, Elsevier, vol. 235(C), pages 495-508.
    5. Kim, Jungmyung & Park, Heesung, 2018. "Impact of nanofluidic electrolyte on the energy storage capacity in vanadium redox flow battery," Energy, Elsevier, vol. 160(C), pages 192-199.
    6. Mehboob, Sheeraz & Ali, Ghulam & Shin, Hyun-Jin & Hwang, Jinyeon & Abbas, Saleem & Chung, Kyung Yoon & Ha, Heung Yong, 2018. "Enhancing the performance of all-vanadium redox flow batteries by decorating carbon felt electrodes with SnO2 nanoparticles," Applied Energy, Elsevier, vol. 229(C), pages 910-921.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Flox, Cristina & Skoumal, Marcel & Rubio-Garcia, Javier & Andreu, Teresa & Morante, Juan Ramón, 2013. "Strategies for enhancing electrochemical activity of carbon-based electrodes for all-vanadium redox flow batteries," Applied Energy, Elsevier, vol. 109(C), pages 344-351.
    2. Di Blasi, A. & Briguglio, N. & Di Blasi, O. & Antonucci, V., 2014. "Charge–discharge performance of carbon fiber-based electrodes in single cell and short stack for vanadium redox flow battery," Applied Energy, Elsevier, vol. 125(C), pages 114-122.
    3. Di Blasi, O. & Briguglio, N. & Busacca, C. & Ferraro, M. & Antonucci, V. & Di Blasi, A., 2015. "Electrochemical investigation of thermically treated graphene oxides as electrode materials for vanadium redox flow battery," Applied Energy, Elsevier, vol. 147(C), pages 74-81.
    4. Oh, Ki-Yong & Epureanu, Bogdan I., 2016. "Characterization and modeling of the thermal mechanics of lithium-ion battery cells," Applied Energy, Elsevier, vol. 178(C), pages 633-646.
    5. Wang, Q. & Qu, Z.G. & Jiang, Z.Y. & Yang, W.W., 2018. "Experimental study on the performance of a vanadium redox flow battery with non-uniformly compressed carbon felt electrode," Applied Energy, Elsevier, vol. 213(C), pages 293-305.
    6. Zhang, Peng & Li, Wenyuan & Li, Sherwin & Wang, Yang & Xiao, Weidong, 2013. "Reliability assessment of photovoltaic power systems: Review of current status and future perspectives," Applied Energy, Elsevier, vol. 104(C), pages 822-833.
    7. Wu, Maochun & Liu, Mingyao & Long, Guifa & Wan, Kai & Liang, Zhenxing & Zhao, Tim S., 2014. "A novel high-energy-density positive electrolyte with multiple redox couples for redox flow batteries," Applied Energy, Elsevier, vol. 136(C), pages 576-581.
    8. Zheng, Qiong & Li, Xianfeng & Cheng, Yuanhui & Ning, Guiling & Xing, Feng & Zhang, Huamin, 2014. "Development and perspective in vanadium flow battery modeling," Applied Energy, Elsevier, vol. 132(C), pages 254-266.
    9. Wang, Tao & Fu, Jiahui & Zheng, Menglian & Yu, Zitao, 2018. "Dynamic control strategy for the electrolyte flow rate of vanadium redox flow batteries," Applied Energy, Elsevier, vol. 227(C), pages 613-623.
    10. Li, Li & Zheng, Keqing & Ni, Meng & Leung, Michael K.H. & Xuan, Jin, 2015. "Partial modification of flow-through porous electrodes in microfluidic fuel cell," Energy, Elsevier, vol. 88(C), pages 563-571.
    11. Xiong, Dongbin & Li, Xifei & Shan, Hui & Yan, Bo & Li, Dejun & Langford, Craig & Sun, Xueliang, 2016. "Scalable synthesis of functionalized graphene as cathodes in Li-ion electrochemical energy storage devices," Applied Energy, Elsevier, vol. 175(C), pages 512-521.
    12. Wei, L. & Zeng, L. & Wu, M.C. & Fan, X.Z. & Zhao, T.S., 2019. "Seawater as an alternative to deionized water for electrolyte preparations in vanadium redox flow batteries," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    13. Wang, Shaoliang & Xu, Zeyu & Wu, Xiaoliang & Zhao, Huan & Zhao, Jinling & Liu, Jianguo & Yan, Chuanwei & Fan, Xinzhuang, 2020. "Analyses and optimization of electrolyte concentration on the electrochemical performance of iron-chromium flow battery," Applied Energy, Elsevier, vol. 271(C).
    14. Martin, Nigel & Rice, John, 2021. "Power outages, climate events and renewable energy: Reviewing energy storage policy and regulatory options for Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    15. Shang, Wenxu & Yu, Wentao & Xiao, Xu & Ma, Yanyi & Chen, Ziqi & Ni, Meng & Tan, Peng, 2022. "Optimizing the charging protocol to address the self-discharge issues in rechargeable alkaline Zn-Co batteries," Applied Energy, Elsevier, vol. 308(C).
    16. Tervo, Eric & Agbim, Kenechi & DeAngelis, Freddy & Hernandez, Jeffrey & Kim, Hye Kyung & Odukomaiya, Adewale, 2018. "An economic analysis of residential photovoltaic systems with lithium ion battery storage in the United States," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 1057-1066.
    17. Mohamed, M.R. & Leung, P.K. & Sulaiman, M.H., 2015. "Performance characterization of a vanadium redox flow battery at different operating parameters under a standardized test-bed system," Applied Energy, Elsevier, vol. 137(C), pages 402-412.
    18. Badrinarayanan, Rajagopalan & Tseng, King Jet & Soong, Boon Hee & Wei, Zhongbao, 2017. "Modelling and control of vanadium redox flow battery for profile based charging applications," Energy, Elsevier, vol. 141(C), pages 1479-1488.
    19. Jin, Tao & Liu, Siyi & Flesch, Rodolfo C.C. & Su, Wencong, 2017. "A method for the identification of low frequency oscillation modes in power systems subjected to noise," Applied Energy, Elsevier, vol. 206(C), pages 1379-1392.
    20. Yin, Cong & Guo, Shaoyun & Fang, Honglin & Liu, Jiayi & Li, Yang & Tang, Hao, 2015. "Numerical and experimental studies of stack shunt current for vanadium redox flow battery," Applied Energy, Elsevier, vol. 151(C), pages 237-248.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:190:y:2017:i:c:p:165-171. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.