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Chemical looping combustion of ultra low concentration of methane with Fe2O3/Al2O3 and CuO/SiO2

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  • Zhang, Yongxing
  • Doroodchi, Elham
  • Moghtaderi, Behdad

Abstract

This study examines the performance of two metal oxide species in oxidizing ultra low concentration of methane (below 1% in volume). The focus on low methane concentrations are driven by its practical importance in applications such as abatement of ventilation air methane (VAM) in mining operations. Two mixed metal oxides, Fe2O3/Al2O3 and CuO/SiO2, were selected as oxygen carriers and prepared using dry impregnation method. The metal oxide loading contents are found to be 45wt% and 48wt%, respectively. The redox reactivity of the selected oxygen carriers were studied at various methane concentrations (i.e., 0.1%, 0.5% and 1% in volume) and temperatures between 873K and 1073K using a thermogravimetric analyzer. At low methane concentrations and low temperatures (below 1073K) the conversion of Fe2O3 to Fe3O4 showed higher reduction reactivity than the reduction of CuO to Cu. The redox reactivity of Fe2O3/Al2O3 was also found to be quite stable even after 60 redox cycles at 1073K. The respective weight percentages for oxidation and reduction were found to be 100% and 96.67%, corresponding to a full oxidized state Fe2O3 and a reduced state between Fe3O4 and FeO respectively. Moreover, the results for the global reactivity of reduction and oxidation (calculated at X=0.5) showed that the reduction rates were temperature and concentration dependent, varying from 0.14%/s to 2.2%/s over the range of temperatures and methane concentrations of interest. The oxidation rates were much higher than their reduction counterpart. The values varied from 8.95%/s at 873K to 10.65% at 1073K.

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  • Zhang, Yongxing & Doroodchi, Elham & Moghtaderi, Behdad, 2014. "Chemical looping combustion of ultra low concentration of methane with Fe2O3/Al2O3 and CuO/SiO2," Applied Energy, Elsevier, vol. 113(C), pages 1916-1923.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:1916-1923
    DOI: 10.1016/j.apenergy.2013.06.005
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    References listed on IDEAS

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    1. Aisyah, L. & Ashman, P.J. & Kwong, C.W., 2013. "Performance of coal fly-ash based oxygen carrier for the chemical looping combustion of synthesis gas," Applied Energy, Elsevier, vol. 109(C), pages 44-50.
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    4. Siriwardane, Ranjani V. & Ksepko, Ewelina & Tian, Hanjing & Poston, James & Simonyi, Thomas & Sciazko, Marek, 2013. "Interaction of iron–copper mixed metal oxide oxygen carriers with simulated synthesis gas derived from steam gasification of coal," Applied Energy, Elsevier, vol. 107(C), pages 111-123.
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    4. Cheng, Xianming & Li, Kongzhai & Zhu, Xing & Wei, Yonggang & Li, Zhouhang & Long, Yanhui & Zheng, Min & Tian, Dong & Wang, Hua, 2018. "Enhanced performance of chemical looping combustion of methane by combining oxygen carriers via optimizing the stacking sequences," Applied Energy, Elsevier, vol. 230(C), pages 696-711.
    5. Qiu, Yu & Zhang, Shuai & Cui, Dongxu & Li, Min & Zeng, Jimin & Zeng, Dewang & Xiao, Rui, 2019. "Enhanced hydrogen production performance at intermediate temperatures through the synergistic effects of binary oxygen carriers," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    6. Shah, Vedant & Cheng, Zhuo & Baser, Deven S. & Fan, Jonathan A. & Fan, Liang-Shih, 2021. "Highly Selective Production of Syngas from Chemical Looping Reforming of Methane with CO2 Utilization on MgO-supported Calcium Ferrite Redox Materials," Applied Energy, Elsevier, vol. 282(PA).
    7. Huang, Liang & Tang, Mingchen & Fan, Maohong & Cheng, Hansong, 2015. "Density functional theory study on the reaction between hematite and methane during chemical looping process," Applied Energy, Elsevier, vol. 159(C), pages 132-144.
    8. Breault, Ronald W. & Monazam, Esmail R. & Carpenter, Jared T., 2015. "Analysis of hematite re-oxidation in the chemical looping process," Applied Energy, Elsevier, vol. 157(C), pages 174-182.
    9. Huang, Xin & Fan, Maohong & Wang, Xingjun & Wang, Yonggang & Argyle, Morris D. & Zhu, Yufei, 2018. "A cost-effective approach to realization of the efficient methane chemical-looping combustion by using coal fly ash as a support for oxygen carrier," Applied Energy, Elsevier, vol. 230(C), pages 393-402.
    10. Su, Shi & Yu, Xinxiang, 2015. "A 25 kWe low concentration methane catalytic combustion gas turbine prototype unit," Energy, Elsevier, vol. 79(C), pages 428-438.
    11. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    12. Akbari-Emadabadi, S. & Rahimpour, M.R. & Hafizi, A. & Keshavarz, P., 2017. "Production of hydrogen-rich syngas using Zr modified Ca-Co bifunctional catalyst-sorbent in chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 206(C), pages 51-62.
    13. Ksepko, Ewelina & Babiński, Piotr & Nalbandian, Lori, 2017. "The redox reaction kinetics of Sinai ore for chemical looping combustion applications," Applied Energy, Elsevier, vol. 190(C), pages 1258-1274.
    14. Tang, Mingchen & Xu, Long & Fan, Maohong, 2015. "Progress in oxygen carrier development of methane-based chemical-looping reforming: A review," Applied Energy, Elsevier, vol. 151(C), pages 143-156.

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