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Thermodynamic analysis of chemical-looping hydrogen generation

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  • Zhang, Xiaosong
  • Jin, Hongguang

Abstract

Recently, interest in chemical-looping combustion (CLC) has grown because it is a technique that could allow cost-effective carbon capture and storage. Recently, the chemical-looping process was also proposed for the production of hydrogen. Chemical-looping hydrogen (CLH) generation, which is a derivation of CLC, is a water-splitting process that involves the reduction–oxidation of a metal oxide. CLC and CLH can reduce the irreversibility and the extent of heat rejection, thereby improving the cycle efficiency. The current paper presents a thermodynamic analysis of CLH to illustrate its potential for improved efficiency. A methodology for selecting oxygen carriers based on their thermodynamic properties is developed, and several candidate materials are reviewed. From a thermodynamic perspective, metals such as Ni and Fe are more suitable for CLH, whereas metals such as Ca and Cd can provide higher efficiency for CLC. Finally, comments on the practical implementations of CLH in power plants are presented.

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  • Zhang, Xiaosong & Jin, Hongguang, 2013. "Thermodynamic analysis of chemical-looping hydrogen generation," Applied Energy, Elsevier, vol. 112(C), pages 800-807.
    • Handle: RePEc:eee:appene:v:112:y:2013:i:c:p:800-807
    DOI: 10.1016/j.apenergy.2013.02.058
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    2. Liu, Y.W. & Liu, X. & Yuan, X.Zh. & Wang, X.J., 2016. "Optimizing design of a new zero boil off cryogenic storage tank in microgravity," Applied Energy, Elsevier, vol. 162(C), pages 1678-1686.
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    4. Sun, Zhao & Chen, Shiyi & Hu, Jun & Chen, Aimin & Rony, Asif Hasan & Russell, Christopher K. & Xiang, Wenguo & Fan, Maohong & Darby Dyar, M. & Dklute, Elizabeth C., 2018. "Ca2Fe2O5: A promising oxygen carrier for CO/CH4 conversion and almost-pure H2 production with inherent CO2 capture over a two-step chemical looping hydrogen generation process," Applied Energy, Elsevier, vol. 211(C), pages 431-442.
    5. Wang, Xun & Fu, Genshen & Xiao, Bo & Xu, Tingting, 2022. "Optimization of nickel-iron bimetallic oxides for coproduction of hydrogen and syngas in chemical looping reforming with water splitting process," Energy, Elsevier, vol. 246(C).
    6. Sreenivasulu, B. & Gayatri, D.V. & Sreedhar, I. & Raghavan, K.V., 2015. "A journey into the process and engineering aspects of carbon capture technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1324-1350.
    7. Ghandehariun, S. & Wang, Z. & Naterer, G.F. & Rosen, M.A., 2015. "Experimental investigation of molten salt droplet quenching and solidification processes of heat recovery in thermochemical hydrogen production," Applied Energy, Elsevier, vol. 157(C), pages 267-275.
    8. Xiang, Dong & Zhou, Yunpeng, 2018. "Concept design and techno-economic performance of hydrogen and ammonia co-generation by coke-oven gas-pressure swing adsorption integrated with chemical looping hydrogen process," Applied Energy, Elsevier, vol. 229(C), pages 1024-1034.
    9. Akbari-Emadabadi, S. & Rahimpour, M.R. & Hafizi, A. & Keshavarz, P., 2017. "Production of hydrogen-rich syngas using Zr modified Ca-Co bifunctional catalyst-sorbent in chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 206(C), pages 51-62.

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