IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v230y2018icp393-402.html
   My bibliography  Save this article

A cost-effective approach to realization of the efficient methane chemical-looping combustion by using coal fly ash as a support for oxygen carrier

Author

Listed:
  • Huang, Xin
  • Fan, Maohong
  • Wang, Xingjun
  • Wang, Yonggang
  • Argyle, Morris D.
  • Zhu, Yufei

Abstract

Developing highly reactive, durable and low-cost oxygen carrier (OC) is the key to the advancement of the chemical looping combustion (CLC) technology that is regarded as the most energy-efficient way for the capture of CO2 emitted from fossil fuel combustion. In this study, the byproduct from coal power plant, coal fly ash (FA) was utilized as the support for Cu-based OC in methane CLC. Its performance was investigated with a thermogravimetric analyzer and a lab-scale fixed bed reactor. The results showed the FA is better as a support of OC than the most commonly used Al2O3 in anti-carbon deposition and thus beneficial to the importance of the stability of FA supported OCs. Among all the tested OCs, the Cu-based OC synthesized with FA support and impregnation method demonstrated the best performance, with CH4 conversion of 94–100% and CO2 selectivity of 91–94% in ten cycles at 800–850 °C, and minor deactivation. The characterization of the fresh and spent OCs revealed that the FA support itself could provide 1.0–2.9 wt% active oxygen for fuel combustion, which is enabled by the iron oxide in FA. In addition, the distribution of Cu on the FA support became more uniform on spent OC than on the fresh one. Also, the partially irreversible CuO decomposition into Cu2O during cyclic tests was the main reason for the deactivation of OC. Thus, Use of FA as an OC support is conducive to both development of cost-effective CLC and an environmental-friendly utilization of waste FA.

Suggested Citation

  • Huang, Xin & Fan, Maohong & Wang, Xingjun & Wang, Yonggang & Argyle, Morris D. & Zhu, Yufei, 2018. "A cost-effective approach to realization of the efficient methane chemical-looping combustion by using coal fly ash as a support for oxygen carrier," Applied Energy, Elsevier, vol. 230(C), pages 393-402.
    • Handle: RePEc:eee:appene:v:230:y:2018:i:c:p:393-402
    DOI: 10.1016/j.apenergy.2018.08.029
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S030626191831184X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2018.08.029?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Huang, Xin & Wang, Xingjun & Fan, Maohong & Wang, Yonggang & Adidharma, Hertanto & Gasem, Khaled A.M. & Radosz, Maciej, 2017. "A cost-effective approach to reducing carbon deposition and resulting deactivation of oxygen carriers for improvement of energy efficiency and CO2 capture during methane chemical-looping combustion," Applied Energy, Elsevier, vol. 193(C), pages 381-392.
    2. Gu, Zhenhua & Li, Kongzhai & Wang, Hua & Qing, Shan & Zhu, Xing & Wei, Yonggang & Cheng, Xianming & Yu, He & Cao, Yan, 2016. "Bulk monolithic Ce–Zr–Fe–O/Al2O3 oxygen carriers for a fixed bed scheme of the chemical looping combustion: Reactivity of oxygen carrier," Applied Energy, Elsevier, vol. 163(C), pages 19-31.
    3. Zhu, Lin & He, Yangdong & Li, Luling & Wu, Pengbin, 2018. "Tech-economic assessment of second-generation CCS: Chemical looping combustion," Energy, Elsevier, vol. 144(C), pages 915-927.
    4. Källén, Malin & Rydén, Magnus & Lyngfelt, Anders & Mattisson, Tobias, 2015. "Chemical-looping combustion using combined iron/manganese/silicon oxygen carriers," Applied Energy, Elsevier, vol. 157(C), pages 330-337.
    5. Aisyah, L. & Ashman, P.J. & Kwong, C.W., 2013. "Performance of coal fly-ash based oxygen carrier for the chemical looping combustion of synthesis gas," Applied Energy, Elsevier, vol. 109(C), pages 44-50.
    6. Zhang, Yongxing & Doroodchi, Elham & Moghtaderi, Behdad, 2014. "Chemical looping combustion of ultra low concentration of methane with Fe2O3/Al2O3 and CuO/SiO2," Applied Energy, Elsevier, vol. 113(C), pages 1916-1923.
    7. Lyngfelt, Anders, 2014. "Chemical-looping combustion of solid fuels – Status of development," Applied Energy, Elsevier, vol. 113(C), pages 1869-1873.
    8. Ku, Young & Wu, Hsuan-Chih & Chiu, Ping-Chin & Tseng, Yao-Hsuan & Kuo, Yu-Lin, 2014. "Methane combustion by moving bed fuel reactor with Fe2O3/Al2O3 oxygen carriers," Applied Energy, Elsevier, vol. 113(C), pages 1909-1915.
    9. Siriwardane, Ranjani & Tian, Hanjing & Miller, Duane & Richards, George, 2015. "Fluidized bed testing of commercially prepared MgO-promoted hematite and CuO–Fe2O3 mixed metal oxide oxygen carriers for methane and coal chemical looping combustion," Applied Energy, Elsevier, vol. 157(C), pages 348-357.
    10. Bao, Jinhua & Li, Zhenshan & Cai, Ningsheng, 2014. "Interaction between iron-based oxygen carrier and four coal ashes during chemical looping combustion," Applied Energy, Elsevier, vol. 115(C), pages 549-558.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chang, F.C. & Liao, P.H. & Tsai, C.K. & Hsiao, M.C. & Paul Wang, H., 2014. "Chemical-looping combustion of syngas with nano CuO–NiO on chabazite," Applied Energy, Elsevier, vol. 113(C), pages 1731-1736.
    2. Nandy, Anirban & Loha, Chanchal & Gu, Sai & Sarkar, Pinaki & Karmakar, Malay K. & Chatterjee, Pradip K., 2016. "Present status and overview of Chemical Looping Combustion technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 597-619.
    3. Sreenivasulu, B. & Gayatri, D.V. & Sreedhar, I. & Raghavan, K.V., 2015. "A journey into the process and engineering aspects of carbon capture technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 1324-1350.
    4. Hua, Xiuning & Fan, Yiran & Wang, Yidi & Fu, Tiantian & Fowler, G.D. & Zhao, Dongmei & Wang, Wei, 2017. "The behaviour of multiple reaction fronts during iron (III) oxide reduction in a non-steady state packed bed for chemical looping water splitting," Applied Energy, Elsevier, vol. 193(C), pages 96-111.
    5. Cho, Won Chul & Lee, Jun Kyu & Nam, Gyeong Duk & Kim, Chang Hee & Cho, Hyun-Seok & Joo, Jong Hoon, 2019. "Degradation analysis of mixed ionic-electronic conductor-supported iron-oxide oxygen carriers for chemical-looping conversion of methane," Applied Energy, Elsevier, vol. 239(C), pages 644-657.
    6. Ksepko, Ewelina & Babiński, Piotr & Nalbandian, Lori, 2017. "The redox reaction kinetics of Sinai ore for chemical looping combustion applications," Applied Energy, Elsevier, vol. 190(C), pages 1258-1274.
    7. Huang, Liang & Tang, Mingchen & Fan, Maohong & Cheng, Hansong, 2015. "Density functional theory study on the reaction between hematite and methane during chemical looping process," Applied Energy, Elsevier, vol. 159(C), pages 132-144.
    8. Lin, Shen & Gu, Zhenhua & Zhu, Xing & Wei, Yonggang & Long, Yanhui & Yang, Kun & He, Fang & Wang, Hua & Li, Kongzhai, 2020. "Synergy of red mud oxygen carrier with MgO and NiO for enhanced chemical-looping combustion," Energy, Elsevier, vol. 197(C).
    9. Zhu, Min & Chen, Shiyi & Soomro, Ahsanullah & Hu, Jun & Sun, Zhao & Ma, Shiwei & Xiang, Wenguo, 2018. "Effects of supports on reduction activity and carbon deposition of iron oxide for methane chemical looping hydrogen generation," Applied Energy, Elsevier, vol. 225(C), pages 912-921.
    10. Zhu, Lin & He, Yangdong & Li, Luling & Lv, Liping & He, Jingling, 2018. "Thermodynamic assessment of SNG and power polygeneration with the goal of zero CO2 emission," Energy, Elsevier, vol. 149(C), pages 34-46.
    11. Akbari-Emadabadi, S. & Rahimpour, M.R. & Hafizi, A. & Keshavarz, P., 2017. "Production of hydrogen-rich syngas using Zr modified Ca-Co bifunctional catalyst-sorbent in chemical looping steam methane reforming," Applied Energy, Elsevier, vol. 206(C), pages 51-62.
    12. Cheng, Xianming & Li, Kongzhai & Zhu, Xing & Wei, Yonggang & Li, Zhouhang & Long, Yanhui & Zheng, Min & Tian, Dong & Wang, Hua, 2018. "Enhanced performance of chemical looping combustion of methane by combining oxygen carriers via optimizing the stacking sequences," Applied Energy, Elsevier, vol. 230(C), pages 696-711.
    13. Lee, Jaehee & Han, Sang-Jun & Wee, Jung-Ho, 2014. "Synthesis of dry sorbents for carbon dioxide capture using coal fly ash and its performance," Applied Energy, Elsevier, vol. 131(C), pages 40-47.
    14. Khasani, & Prasidha, Willie & Widyatama, Arif & Aziz, Muhammad, 2021. "Energy-saving and environmentally-benign integrated ammonia production system," Energy, Elsevier, vol. 235(C).
    15. Zhang, Hao & Liu, Xiangyu & Hong, Hui & Jin, Hongguang, 2018. "Characteristics of a 10 kW honeycomb reactor for natural gas fueled chemical-looping combustion," Applied Energy, Elsevier, vol. 213(C), pages 285-292.
    16. Tian, Xin & Zhao, Haibo & Ma, Jinchen, 2017. "Cement bonded fine hematite and copper ore particles as oxygen carrier in chemical looping combustion," Applied Energy, Elsevier, vol. 204(C), pages 242-253.
    17. Iloeje, Chukwunwike O. & Zhao, Zhenlong & Ghoniem, Ahmed F., 2017. "A reduced fidelity model for the rotary chemical looping combustion reactor," Applied Energy, Elsevier, vol. 190(C), pages 725-739.
    18. Breault, Ronald W. & Monazam, Esmail R. & Carpenter, Jared T., 2015. "Analysis of hematite re-oxidation in the chemical looping process," Applied Energy, Elsevier, vol. 157(C), pages 174-182.
    19. Güleç, Fatih & Meredith, Will & Sun, Cheng-Gong & Snape, Colin E., 2019. "Selective low temperature chemical looping combustion of higher alkanes with Cu- and Mn- oxides," Energy, Elsevier, vol. 173(C), pages 658-666.
    20. Samuel Bayham & Ronald Breault & Justin Weber, 2017. "Chemical Looping Combustion of Hematite Ore with Methane and Steam in a Fluidized Bed Reactor," Energies, MDPI, vol. 10(8), pages 1-22, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:230:y:2018:i:c:p:393-402. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.