IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v8y2015i5p3403-3417d48708.html
   My bibliography  Save this article

Comprehensive Characterization of Napier Grass as a Feedstock for Thermochemical Conversion

Author

Listed:
  • Isah Y. Mohammed

    (Energy, Fuel and Power Technology Research Division, School of Engineering, the University of Nottingham Malaysia Campus, Jalan Broga, Semenyih 43500, Selangor Darul Eshan, Malaysia)

  • Yousif A. Abakr

    (Energy, Fuel and Power Technology Research Division, School of Engineering, the University of Nottingham Malaysia Campus, Jalan Broga, Semenyih 43500, Selangor Darul Eshan, Malaysia)

  • Feroz K. Kazi

    (Department of Chemical Engineering and Applied Chemistry, Aston University, Aston Triangle, Birmingham B4 7ET, UK)

  • Suzana Yusup

    (Department of Chemical Engineering, Universiti Teknology Petronas (UTP), Bandar Seri Iskandar, Tronoh 31750, Malaysia)

  • Ibraheem Alshareef

    (Crops for the Future (CFF), the University of Nottingham Malaysia Campus, Jalan Broga, Semenyih 43500, Selangor Darul Eshan, Malaysia)

  • Soh A. Chin

    (Crops for the Future (CFF), the University of Nottingham Malaysia Campus, Jalan Broga, Semenyih 43500, Selangor Darul Eshan, Malaysia)

Abstract

Study on Napier grass leaf (NGL), stem (NGS) and leaf and stem (NGT) was carried out. Proximate, ultimate and structural analyses were evaluated. Functional groups and crystalline components in the biomass were examined. Pyrolysis study was conducted in a thermogravimetric analyzer under nitrogen atmosphere of 20 mL/min at constant heating rate of 10 K/min. The results reveal that Napier grass biomass has high volatile matter, higher heating value, high carbon content and lower ash, nitrogen and sulfur contents. Structural analysis shows that the biomass has considerable cellulose and lignin contents which are good candidates for good quality bio-oil production. From the pyrolysis study, degradation of extractives, hemicellulose, cellulose and lignin occurred at temperature around 478, 543, 600 and above 600 K, respectively. Kinetics of the process was evaluated using reaction order model. New equations that described the process were developed using the kinetic parameters and data compared with experimental data. The results of the models fit well to the experimental data. The proposed models may be a reliable means for describing thermal decomposition of lignocellulosic biomass under nitrogen atmosphere at constant heating rate.

Suggested Citation

  • Isah Y. Mohammed & Yousif A. Abakr & Feroz K. Kazi & Suzana Yusup & Ibraheem Alshareef & Soh A. Chin, 2015. "Comprehensive Characterization of Napier Grass as a Feedstock for Thermochemical Conversion," Energies, MDPI, vol. 8(5), pages 1-15, April.
    • Handle: RePEc:gam:jeners:v:8:y:2015:i:5:p:3403-3417:d:48708
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/8/5/3403/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/8/5/3403/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Xu, Feng & Yu, Jianming & Tesso, Tesfaye & Dowell, Floyd & Wang, Donghai, 2013. "Qualitative and quantitative analysis of lignocellulosic biomass using infrared techniques: A mini-review," Applied Energy, Elsevier, vol. 104(C), pages 801-809.
    2. Naik, Satyanarayan & Goud, Vaibhav V. & Rout, Prasant K. & Jacobson, Kathlene & Dalai, Ajay K., 2010. "Characterization of Canadian biomass for alternative renewable biofuel," Renewable Energy, Elsevier, vol. 35(8), pages 1624-1631.
    3. Chen, Wei-Hsin & Kuo, Po-Chih, 2011. "Isothermal torrefaction kinetics of hemicellulose, cellulose, lignin and xylan using thermogravimetric analysis," Energy, Elsevier, vol. 36(11), pages 6451-6460.
    4. Kezhen Qian & Ajay Kumar & Krushna Patil & Danielle Bellmer & Donghai Wang & Wenqiao Yuan & Raymond L. Huhnke, 2013. "Effects of Biomass Feedstocks and Gasification Conditions on the Physiochemical Properties of Char," Energies, MDPI, vol. 6(8), pages 1-15, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chettaphong Phuttaro & Alissara Reungsang & Piyarat Boonsawang & Sumate Chaiprapat, 2019. "Integrative Effects of Sonication and Particle Size on Biomethanation of Tropical Grass Pennisetum purpureum Using Superior Diverse Inocula Cultures," Energies, MDPI, vol. 12(22), pages 1-16, November.
    2. Lisandra Rocha-Meneses & Oghenetejiri Frances Otor & Nemailla Bonturi & Kaja Orupõld & Timo Kikas, 2019. "Bioenergy Yields from Sequential Bioethanol and Biomethane Production: An Optimized Process Flow," Sustainability, MDPI, vol. 12(1), pages 1-19, December.
    3. Sun Yong Park & Kwang Cheol Oh & Seok Jun Kim & La Hoon Cho & Young Kwang Jeon & DaeHyun Kim, 2023. "Development of a Biomass Component Prediction Model Based on Elemental and Proximate Analyses," Energies, MDPI, vol. 16(14), pages 1-17, July.
    4. Liu, Chao & Liu, Jingyong & Evrendilek, Fatih & Xie, Wuming & Kuo, Jiahong & Buyukada, Musa, 2020. "Bioenergy and emission characterizations of catalytic combustion and pyrolysis of litchi peels via TG-FTIR-MS and Py-GC/MS," Renewable Energy, Elsevier, vol. 148(C), pages 1074-1093.
    5. Łukasz Sobol & Karol Wolski & Adam Radkowski & Elżbieta Piwowarczyk & Maciej Jurkowski & Henryk Bujak & Arkadiusz Dyjakon, 2022. "Determination of Energy Parameters and Their Variability between Varieties of Fodder and Turf Grasses," Sustainability, MDPI, vol. 14(18), pages 1-19, September.
    6. Chen, Dengyu & Cen, Kehui & Cao, Xiaobing & Chen, Fan & Zhang, Jie & Zhou, Jianbin, 2021. "Insight into a new phenolic-leaching pretreatment on bamboo pyrolysis: Release characteristics of pyrolytic volatiles, upgradation of three phase products, migration of elements, and energy yield," Renewable and Sustainable Energy Reviews, Elsevier, vol. 136(C).
    7. Isah Yakub Mohammed & Feroz Kabir Kazi & Suzana Yusup & Peter Adeniyi Alaba & Yahaya Muhammad Sani & Yousif Abdalla Abakr, 2016. "Catalytic Intermediate Pyrolysis of Napier Grass in a Fixed Bed Reactor with ZSM-5, HZSM-5 and Zinc-Exchanged Zeolite-A as the Catalyst," Energies, MDPI, vol. 9(4), pages 1-17, March.
    8. Soyoung Han & Yong-Chul Jang & Yeon-Seok Choi & Sang-Kyu Choi, 2020. "Thermogravimetric Kinetic Study of Automobile Shredder Residue (ASR) Pyrolysis," Energies, MDPI, vol. 13(6), pages 1-16, March.
    9. Kotchakarn Nantasaksiri & Patcharawat Charoen-Amornkitt & Takashi Machimura, 2021. "Land Potential Assessment of Napier Grass Plantation for Power Generation in Thailand Using SWAT Model. Model Validation and Parameter Calibration," Energies, MDPI, vol. 14(5), pages 1-15, March.
    10. Rafael Freitas & Tatiane Barbé & Rogério Daher & Ana Kesia Vidal & Wanessa Stida & Verônica da Silva & Bruna Rafaela Menezes & Antônio Pereira, 2017. "Chemical Composition and Energy Yield of Elephant-Grass Biomass as Function of Five Different Production Ages," Journal of Agricultural Science, Canadian Center of Science and Education, vol. 10(1), pages 343-343, December.
    11. Rahaman, Touhidur & Biswas, Subhadeep & Ghorai, Shubhankar & Bera, Sudeshna & Dey, Sonali & Guha, Suman & Maity, Debabrata & De, Sukanta & Ganguly, Jhuma & Das, Malay, 2023. "Integrated application of morphological, anatomical, biochemical and physico-chemical methods to identify superior, lignocellulosic grass feedstocks for bioenergy purposes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 187(C).
    12. Wang, Bo & Xu, Fanfan & Zong, Peijie & Zhang, Jinhong & Tian, Yuanyu & Qiao, Yingyun, 2019. "Effects of heating rate on fast pyrolysis behavior and product distribution of Jerusalem artichoke stalk by using TG-FTIR and Py-GC/MS," Renewable Energy, Elsevier, vol. 132(C), pages 486-496.
    13. Qatan, Hesham Sadeq Obaid & Wan Ab Karim Ghani, Wan Azlina & Md Said, Mohamad Syazarudin, 2023. "Prediction and optimization of syngas production from Napier grass air gasification via kinetic modelling and response surface methodology," Energy, Elsevier, vol. 270(C).
    14. Nabila, Rakhmawati & Hidayat, Wahyu & Haryanto, Agus & Hasanudin, Udin & Iryani, Dewi Agustina & Lee, Sihyun & Kim, Sangdo & Kim, Soohyun & Chun, Donghyuk & Choi, Hokyung & Im, Hyuk & Lim, Jeonghwan &, 2023. "Oil palm biomass in Indonesia: Thermochemical upgrading and its utilization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Collazo, Joaquín & Pazó, José Antonio & Granada, Enrique & Saavedra, Ángeles & Eguía, Pablo, 2012. "Determination of the specific heat of biomass materials and the combustion energy of coke by DSC analysis," Energy, Elsevier, vol. 45(1), pages 746-752.
    2. Singh, Yengkhom Disco & Mahanta, Pinakeswar & Bora, Utpal, 2017. "Comprehensive characterization of lignocellulosic biomass through proximate, ultimate and compositional analysis for bioenergy production," Renewable Energy, Elsevier, vol. 103(C), pages 490-500.
    3. Granados, D.A. & Ruiz, R.A. & Vega, L.Y. & Chejne, F., 2017. "Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process," Energy, Elsevier, vol. 139(C), pages 818-827.
    4. Siddiqi, Hammad & Bal, Manisha & Kumari, Usha & Meikap, B.C., 2020. "In-depth physiochemical characterization and detailed thermo-kinetic study of biomass wastes to analyze its energy potential," Renewable Energy, Elsevier, vol. 148(C), pages 756-771.
    5. Shadangi, Krushna Prasad & Mohanty, Kaustubha, 2014. "Kinetic study and thermal analysis of the pyrolysis of non-edible oilseed powders by thermogravimetric and differential scanning calorimetric analysis," Renewable Energy, Elsevier, vol. 63(C), pages 337-344.
    6. Hameed, Zeeshan & Aslam, Muhammad & Khan, Zakir & Maqsood, Khuram & Atabani, A.E. & Ghauri, Moinuddin & Khurram, Muhammad Shahzad & Rehan, Mohammad & Nizami, Abdul-Sattar, 2021. "Gasification of municipal solid waste blends with biomass for energy production and resources recovery: Current status, hybrid technologies and innovative prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 136(C).
    7. Pitak, Lakkana & Sirisomboon, Panmanas & Saengprachatanarug, Khwantri & Wongpichet, Seree & Posom, Jetsada, 2021. "Rapid elemental composition measurement of commercial pellets using line-scan hyperspectral imaging analysis," Energy, Elsevier, vol. 220(C).
    8. Krishna, Bhavya B. & Biswas, Bijoy & Ohri, Priyanka & Kumar, Jitendra & Singh, Rawel & Bhaskar, Thallada, 2016. "Pyrolysis of Cedrus deodara saw mill shavings in hydrogen and nitrogen atmosphere for the production of bio-oil," Renewable Energy, Elsevier, vol. 98(C), pages 238-244.
    9. Hu, Lin & Xu, Mei-Ling & Wei, Xian-Yong & Yu, Changlin & Wu, Jingcheng & Wang, Haiyong & Liu, Tianlong, 2024. "Effect of ethanolysis on the structure evolution, pyrolysis kinetics, and volatile products of waste poplar sawdust," Energy, Elsevier, vol. 305(C).
    10. El may, Yassine & Jeguirim, Mejdi & Dorge, Sophie & Trouvé, Gwenaelle & Said, Rachid, 2012. "Study on the thermal behavior of different date palm residues: Characterization and devolatilization kinetics under inert and oxidative atmospheres," Energy, Elsevier, vol. 44(1), pages 702-709.
    11. Lu, Ke-Miao & Lee, Wen-Jhy & Chen, Wei-Hsin & Lin, Ta-Chang, 2013. "Thermogravimetric analysis and kinetics of co-pyrolysis of raw/torrefied wood and coal blends," Applied Energy, Elsevier, vol. 105(C), pages 57-65.
    12. Kłosowski, Grzegorz & Mikulski, Dawid, 2023. "Changes in various lignocellulose biomasses structure after microwave-assisted hydrotropic pretreatment," Renewable Energy, Elsevier, vol. 219(P1).
    13. Batidzirai, B. & Mignot, A.P.R. & Schakel, W.B. & Junginger, H.M. & Faaij, A.P.C., 2013. "Biomass torrefaction technology: Techno-economic status and future prospects," Energy, Elsevier, vol. 62(C), pages 196-214.
    14. Fan, Yuyang & Tippayawong, Nakorn & Wei, Guoqiang & Huang, Zhen & Zhao, Kun & Jiang, Liqun & Zheng, Anqing & Zhao, Zengli & Li, Haibin, 2020. "Minimizing tar formation whilst enhancing syngas production by integrating biomass torrefaction pretreatment with chemical looping gasification," Applied Energy, Elsevier, vol. 260(C).
    15. López-González, D. & Avalos-Ramirez, A. & Giroir-Fendler, A. & Godbout, S. & Fernandez-Lopez, M. & Sanchez-Silva, L. & Valverde, J.L., 2015. "Combustion kinetic study of woody and herbaceous crops by thermal analysis coupled to mass spectrometry," Energy, Elsevier, vol. 90(P2), pages 1626-1635.
    16. Arthur M. James R. & Wenqiao Yuan & Michael D. Boyette, 2016. "The Effect of Biomass Physical Properties on Top-Lit Updraft Gasification of Woodchips," Energies, MDPI, vol. 9(4), pages 1-13, April.
    17. Junying Chen & Lijun Wang & Bo Zhang & Rui Li & Abolghasem Shahbazi, 2018. "Hydrothermal Liquefaction Enhanced by Various Chemicals as a Means of Sustainable Dairy Manure Treatment," Sustainability, MDPI, vol. 10(1), pages 1-14, January.
    18. Wenjia Jin & Kaushlendra Singh & John Zondlo, 2013. "Pyrolysis Kinetics of Physical Components of Wood and Wood-Polymers Using Isoconversion Method," Agriculture, MDPI, vol. 3(1), pages 1-21, January.
    19. Erić, Aleksandar & Cvetinović, Dejan & Milutinović, Nada & Škobalj, Predrag & Bakić, Vukman, 2022. "Combined parametric modelling of biomass devolatilisation process," Renewable Energy, Elsevier, vol. 193(C), pages 13-22.
    20. Xing Yang & Hailong Wang & Peter James Strong & Song Xu & Shujuan Liu & Kouping Lu & Kuichuan Sheng & Jia Guo & Lei Che & Lizhi He & Yong Sik Ok & Guodong Yuan & Ying Shen & Xin Chen, 2017. "Thermal Properties of Biochars Derived from Waste Biomass Generated by Agricultural and Forestry Sectors," Energies, MDPI, vol. 10(4), pages 1-12, April.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:8:y:2015:i:5:p:3403-3417:d:48708. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.