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Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process

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  • Granados, D.A.
  • Ruiz, R.A.
  • Vega, L.Y.
  • Chejne, F.

Abstract

A complete study of torrefaction process to sugarcane bagasse under different thermal conditions was developed. After torrefaction process, chars were burned in an oxidizing atmosphere and its reactivities were studied. The torrefied biomass was characterized through chemical and physical analysis such as proximate and elemental analyses, lignocellulosic composition, High Heating Value (HHV), Fourier Transform Infrared Spectroscopy (FTIR) and observations in Scanning Electron Microscopy (SEM). The torrefied biomass was also evaluated in oxidizing conditions in order to analyze the impact of torrefaction process over biomass combustion process. Remarkable changes of the main functional groups were observed as the severity of the torrefaction process increased. The main structural carbohydrates affected in the process were hemicellulose and cellulose, which break down largely as a result of decarboxylation reactions, and breakage of links with methyl and acetyl groups. This was evidenced qualitatively when the material was observed in SEM, an increase in the decomposition of the cell wall structures as the process temperature increased was noted. These changes in the material were also verified with FTIR tests, and lignified matrix with higher content of aromatic groups and greater thermal stability is yielded with temperature increases.

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  • Granados, D.A. & Ruiz, R.A. & Vega, L.Y. & Chejne, F., 2017. "Study of reactivity reduction in sugarcane bagasse as consequence of a torrefaction process," Energy, Elsevier, vol. 139(C), pages 818-827.
    • Handle: RePEc:eee:energy:v:139:y:2017:i:c:p:818-827
    DOI: 10.1016/j.energy.2017.08.013
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    5. Huang, Shengxiong & Lei, Can & Qin, Jie & Yi, Cheng & Chen, Tao & Yao, Lingling & Li, Bo & Wen, Yujiao & Zhou, Zhi & Xia, Mao, 2022. "Properties, kinetics and pyrolysis products distribution of oxidative torrefied camellia shell in different oxygen concentration," Energy, Elsevier, vol. 251(C).
    6. Sun Yong Park & Kwang Cheol Oh & Seok Jun Kim & La Hoon Cho & Young Kwang Jeon & DaeHyun Kim, 2023. "Development of a Biomass Component Prediction Model Based on Elemental and Proximate Analyses," Energies, MDPI, vol. 16(14), pages 1-17, July.
    7. Lin, Yi-Li & Zheng, Nai-Yun & Lin, Ching-Shi, 2021. "Repurposing Washingtonia filifera petiole and Sterculia foetida follicle waste biomass for renewable energy through torrefaction," Energy, Elsevier, vol. 223(C).
    8. Ahmad, Razi & Mohd Ishak, Mohd Azlan & Kasim, Nur Nasulhah & Ismail, Khudzir, 2019. "Properties and thermal analysis of upgraded palm kernel shell and Mukah Balingian coal," Energy, Elsevier, vol. 167(C), pages 538-547.
    9. Sher, Farooq & Yaqoob, Aqsa & Saeed, Farrukh & Zhang, Shengfu & Jahan, Zaib & Klemeš, Jiří Jaromír, 2020. "Torrefied biomass fuels as a renewable alternative to coal in co-firing for power generation," Energy, Elsevier, vol. 209(C).
    10. Germán Álvarez-López & Alejandra María Múnera & Juan G. Villegas, 2023. "Multicriteria Decision-Making Tools for the Selection of Biomasses as Supplementary Cementitious Materials," Sustainability, MDPI, vol. 15(13), pages 1-17, June.
    11. Niu, Qi & Ronsse, Frederik & Qi, Zhiyong & Zhang, Dongdong, 2022. "Fast torrefaction of large biomass particles by superheated steam: Enhanced solid products for multipurpose production," Renewable Energy, Elsevier, vol. 185(C), pages 552-563.

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