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Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study

Author

Listed:
  • Qiang Lu

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, Beijing 102206, China)

  • Zhi-Fei Zhang

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, Beijing 102206, China)

  • Chang-Qing Dong

    (National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, Beijing 102206, China)

  • Xi-Feng Zhu

    (Key Laboratory for Biomass Clean Energy of Anhui Province, University of Science and Technology of China, Hefei 230026, China)

Abstract

Fast pyrolysis of poplar wood followed with catalytic cracking of the pyrolysis vapors was performed using analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The catalysts applied in this study were nano MgO, CaO, TiO 2 , Fe 2 O 3 , NiO and ZnO. These catalysts displayed different catalytic capabilities towards the pyrolytic products. The catalysis by CaO significantly reduced the levels of phenols and anhydrosugars, and eliminated the acids, while it increased the formation of cyclopentanones, hydrocarbons and several light compounds. ZnO was a mild catalyst, as it only slightly altered the pyrolytic products. The other four catalysts all decreased the linear aldehydes dramatically, while the increased the ketones and cyclopentanones. They also reduced the anhydrosugars, except for NiO. Moreover, the catalysis by Fe 2 O 3 resulted in the formation of various hydrocarbons. However, none of these catalysts except CaO were able to greatly reduce the acids.

Suggested Citation

  • Qiang Lu & Zhi-Fei Zhang & Chang-Qing Dong & Xi-Feng Zhu, 2010. "Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study," Energies, MDPI, vol. 3(11), pages 1-16, November.
    • Handle: RePEc:gam:jeners:v:3:y:2010:i:11:p:1805-1820:d:10216
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    2. Eleni F. Iliopoulou & Kostas S. Triantafyllidis & Angelos A. Lappas, 2019. "Overview of catalytic upgrading of biomass pyrolysis vapors toward the production of fuels and high‐value chemicals," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 8(1), January.
    3. Cai, Yixi & Fan, Yongsheng & Li, Xiaohua & Chen, Lei & Wang, Jiajun, 2016. "Preparation of refined bio-oil by catalytic transformation of vapors derived from vacuum pyrolysis of rape straw over modified HZSM-5," Energy, Elsevier, vol. 102(C), pages 95-105.
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    11. Vichaphund, Supawan & Aht-ong, Duangdao & Sricharoenchaikul, Viboon & Atong, Duangduen, 2015. "Production of aromatic compounds from catalytic fast pyrolysis of Jatropha residues using metal/HZSM-5 prepared by ion-exchange and impregnation methods," Renewable Energy, Elsevier, vol. 79(C), pages 28-37.
    12. Ming, Zi-Qiang & Liu, Yun-Quan & Ye, Yue-Yuan & Li, Shui-Rong & Zhao, Ying-Ru & Wang, Duo, 2016. "Study of a new combined method for pre-extraction of essential oils and catalytic fast pyrolysis of pine sawdust," Energy, Elsevier, vol. 116(P1), pages 558-566.
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    14. Kabir, G. & Hameed, B.H., 2017. "Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 945-967.
    15. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
    16. Harsha Mysore Prabhakara & Eddy A. Bramer & Gerrit Brem, 2021. "Biomass Fast Pyrolysis Vapor Upgrading over γ-Alumina, Hydrotalcite, Dolomite and Effect of Na 2 CO 3 Loading: A Pyro Probe GCMS Study," Energies, MDPI, vol. 14(17), pages 1-17, August.
    17. Caio Campos Ferreira & Lucas Pinto Bernar & Augusto Fernando de Freitas Costa & Haroldo Jorge da Silva Ribeiro & Marcelo Costa Santos & Nathalia Lobato Moraes & Yasmin Santos Costa & Ana Cláudia Fonse, 2022. "Improving Fuel Properties and Hydrocarbon Content from Residual Fat Pyrolysis Vapors over Activated Red Mud Pellets in Two-Stage Reactor: Optimization of Reaction Time and Catalyst Content," Energies, MDPI, vol. 15(15), pages 1-33, August.
    18. Yichen Liu & James J. Leahy & Jacek Grams & Witold Kwapinski, 2019. "Hydro-Pyrolysis and Catalytic Upgrading of Biomass and Its Hydroxy Residue Fast Pyrolysis Vapors," Energies, MDPI, vol. 12(18), pages 1-18, September.
    19. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.
    20. Wang, Lijun & Agyemang, Samuel A. & Amini, Hossein & Shahbazi, Abolghasem, 2015. "Mathematical modeling of production and biorefinery of energy crops," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 530-544.
    21. Oh, Shinyoung & Lee, Jae Hoon & Choi, In-Gyu & Choi, Joon Weon, 2020. "Enhancement of bio-oil hydrodeoxygenation activity over Ni-based bimetallic catalysts supported on SBA-15," Renewable Energy, Elsevier, vol. 149(C), pages 1-10.
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