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In situ catalytic fast pyrolysis of crude and torrefied Eucalyptus globulus using carbon aerogel-supported catalysts

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  • Arteaga-Pérez, Luis E.
  • Gómez Cápiro, Oscar
  • Romero, Romina
  • Delgado, Aaron
  • Olivera, Patricia
  • Ronsse, Frederik
  • Jiménez, Romel

Abstract

Nickel and iron supported on thermostable cellulose-derived carbon aerogels (CAG), were used for the catalytic fast pyrolysis (CFP) of crude and torrefied Eucalyptus globulus. Pyrolysis vapors produced from torrefied biomass under non-catalytic conditions were reduced by 70% in carboxylic acids with respect to vapors originating from crude biomass, but also were richer in ketones and aromatics. In the case of CFP of both crude and torrefied E.globulus on CAG-supported iron and nickel (Fe/CAG and Ni/CAG), the metallic clusters were activated for ketonization, while Ni0 provided additional hydrogenation sites, increasing the production of monoaromatics (c.a.18% selectivity), leading to a high acids-to-ketone (ξA-K = 1.3) and heavy-to-light (ξH-L = 1.0) ratios. Accordingly, Ni/CAG and Fe/CAG were more effective than HZSM-5 –a traditional cracking catalysts– for upgrading CFP vapors to light compounds. The combination of zeolite acid sites with the oxophilic Ni0 and Fe0 allows the deoxygenation of vapors while the ratio of polyaromatics to light aromatics (ξPAHs) was reduced by nearly 50%.

Suggested Citation

  • Arteaga-Pérez, Luis E. & Gómez Cápiro, Oscar & Romero, Romina & Delgado, Aaron & Olivera, Patricia & Ronsse, Frederik & Jiménez, Romel, 2017. "In situ catalytic fast pyrolysis of crude and torrefied Eucalyptus globulus using carbon aerogel-supported catalysts," Energy, Elsevier, vol. 128(C), pages 701-712.
    • Handle: RePEc:eee:energy:v:128:y:2017:i:c:p:701-712
    DOI: 10.1016/j.energy.2017.04.024
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    1. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    2. Arteaga-Pérez, Luis E. & Segura, Cristina & Bustamante-García, Verónica & Gómez Cápiro, Oscar & Jiménez, Romel, 2015. "Torrefaction of wood and bark from Eucalyptus globulus and Eucalyptus nitens: Focus on volatile evolution vs feasible temperatures," Energy, Elsevier, vol. 93(P2), pages 1731-1741.
    3. Wang, Duo & Yuan, Wenqiao & Ji, Wei, 2011. "Char and char-supported nickel catalysts for secondary syngas cleanup and conditioning," Applied Energy, Elsevier, vol. 88(5), pages 1656-1663, May.
    4. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
    5. Wigley, Tansy & Yip, Alex C.K. & Pang, Shusheng, 2016. "Pretreating biomass via demineralisation and torrefaction to improve the quality of crude pyrolysis oil," Energy, Elsevier, vol. 109(C), pages 481-494.
    6. Shen, Yafei & Zhao, Peitao & Shao, Qinfu & Takahashi, Fumitake & Yoshikawa, Kunio, 2015. "In situ catalytic conversion of tar using rice husk char/ash supported nickel–iron catalysts for biomass pyrolytic gasification combined with the mixing-simulation in fluidized-bed gasifier," Applied Energy, Elsevier, vol. 160(C), pages 808-819.
    7. Asadullah, Mohammad, 2014. "Biomass gasification gas cleaning for downstream applications: A comparative critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 118-132.
    8. Yildiz, Güray & Ronsse, Frederik & Duren, Ruben van & Prins, Wolter, 2016. "Challenges in the design and operation of processes for catalytic fast pyrolysis of woody biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1596-1610.
    9. Qiang Lu & Zhi-Fei Zhang & Chang-Qing Dong & Xi-Feng Zhu, 2010. "Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study," Energies, MDPI, vol. 3(11), pages 1-16, November.
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    5. Tang, Shouhang & Zhou, Sicheng & Li, Ge & Xin, Shanzhi & Huang, Fang & Liu, Xiaoye & Huang, Kai & Zeng, Lixi & Mi, Tie, 2023. "Combination of torrefaction and catalytic fast pyrolysis for aromatic hydrocarbon production from herbaceous medicine waste," Energy, Elsevier, vol. 270(C).
    6. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part II: Catalytic research," Renewable Energy, Elsevier, vol. 189(C), pages 315-338.

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