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Pyrolysis oil composition and catalytic activity estimated by cumulative mass analysis using Py-GC/MS EGA-MS

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  • Merckel, Ryan D.
  • Heydenrych, Mike D.
  • Sithole, Bruce B.

Abstract

An advancement in the analytical capabilities of pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) with evolved gas analysis-mass spectrometry (EGA-MS) is presented. The combined method of analysis can predict elemental composition and calorific content of pyrolysis products using linear regression between the mass fractions of elemental entities and the mass fractions of their respective compounds. The method also reduces the need for elemental analysis, bomb calorimetry, and Karl Fischer titration. Elemental compositions obtained from literature with a low level of characterisation of 29% could be estimated with a mean absolute error (MAE) of 6.1%, while calorific values could be predicted within a MAE of 3.5 MJ kg−1. The performance of various catalysts in upgrading Eucalyptus grandis sawdust-derived pyrolysis oil was also demonstrated with this method, whereby the mechanisms, changes to elemental composition, and impact on calorific value were assessed. It was found that catalytic fast pyrolysis by the calcium-aluminium layered double oxide (Ca–Al-LDO) is dominated by decarboxylation, with a dehydration to decarboxylation ratio of H2O/CO2 = 0.18, compared to the magnesium-aluminium layered double oxide (Mg–Al-LDO) (H2O/CO2 = 1.29) and bentonite (H2O/CO2 = 0.82). ZSM-5 on the other hand achieved decarboxylation by the dominant mechanism of dehydration, with H2O/CO2 = 3.55.

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  • Merckel, Ryan D. & Heydenrych, Mike D. & Sithole, Bruce B., 2021. "Pyrolysis oil composition and catalytic activity estimated by cumulative mass analysis using Py-GC/MS EGA-MS," Energy, Elsevier, vol. 219(C).
  • Handle: RePEc:eee:energy:v:219:y:2021:i:c:s0360544220325354
    DOI: 10.1016/j.energy.2020.119428
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    1. Theodore Dickerson & Juan Soria, 2013. "Catalytic Fast Pyrolysis: A Review," Energies, MDPI, vol. 6(1), pages 1-25, January.
    2. Merckel, R.D. & Labuschagne, F.J.W.J. & Heydenrych, M.D., 2019. "Oxygen consumption as the definitive factor in predicting heat of combustion," Applied Energy, Elsevier, vol. 235(C), pages 1041-1047.
    3. Kim, Kwang Ho & Kim, Tae-Seung & Lee, Soo-Min & Choi, Donha & Yeo, Hwanmyeong & Choi, In-Gyu & Choi, Joon Weon, 2013. "Comparison of physicochemical features of biooils and biochars produced from various woody biomasses by fast pyrolysis," Renewable Energy, Elsevier, vol. 50(C), pages 188-195.
    4. Alexander A. Myburg & Dario Grattapaglia & Gerald A. Tuskan & Uffe Hellsten & Richard D. Hayes & Jane Grimwood & Jerry Jenkins & Erika Lindquist & Hope Tice & Diane Bauer & David M. Goodstein & Inna D, 2014. "The genome of Eucalyptus grandis," Nature, Nature, vol. 510(7505), pages 356-362, June.
    5. Mohammad I. Jahirul & Mohammad G. Rasul & Ashfaque Ahmed Chowdhury & Nanjappa Ashwath, 2012. "Biofuels Production through Biomass Pyrolysis —A Technological Review," Energies, MDPI, vol. 5(12), pages 1-50, November.
    6. Yildiz, Güray & Ronsse, Frederik & Duren, Ruben van & Prins, Wolter, 2016. "Challenges in the design and operation of processes for catalytic fast pyrolysis of woody biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1596-1610.
    7. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    8. Qiang Lu & Zhi-Fei Zhang & Chang-Qing Dong & Xi-Feng Zhu, 2010. "Catalytic Upgrading of Biomass Fast Pyrolysis Vapors with Nano Metal Oxides: An Analytical Py-GC/MS Study," Energies, MDPI, vol. 3(11), pages 1-16, November.
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