IDEAS home Printed from https://ideas.repec.org/a/eee/recore/v59y2012icp23-31.html
   My bibliography  Save this article

Influence of temperature on biomass pyrolysis in a conical spouted bed reactor

Author

Listed:
  • Amutio, M.
  • Lopez, G.
  • Artetxe, M.
  • Elordi, G.
  • Olazar, M.
  • Bilbao, J.

Abstract

Pinewood sawdust flash pyrolysis has been performed in continuous mode in a pilot plant provided with a conical spouted bed reactor, in the 400–600°C range. The influence of temperature on the pyrolysis yields and product properties has been studied. Product analysis has been carried out on-line by means of chromatographic methods. High liquid yields have been achieved, with the maximum bio-oil yield (75wt%) at 500°C. Gas yield is very low at low temperatures and this fraction is mainly composed of carbon dioxide, carbon monoxide and small amounts of methane, hydrogen and C2–C4 hydrocarbons. Bio-oil has been characterized and its major compounds are phenols, specifically guaiacols at low temperatures and catechols at high temperatures. At 600°C, there is an increase in light compounds due to the cracking reactions, but no aromatic compounds have been detected due to the low residence time of the volatiles in the reactor. The fuel properties of the bio-oil have been measured and the results indicate that it can be a potential substitute to conventional fuels, although its heating value should be improved by subjecting to further treatments. Char can be used as energy source or as active carbon. The char obtained at 600°C has a high surface area and is suitable for active carbon production.

Suggested Citation

  • Amutio, M. & Lopez, G. & Artetxe, M. & Elordi, G. & Olazar, M. & Bilbao, J., 2012. "Influence of temperature on biomass pyrolysis in a conical spouted bed reactor," Resources, Conservation & Recycling, Elsevier, vol. 59(C), pages 23-31.
    • Handle: RePEc:eee:recore:v:59:y:2012:i:c:p:23-31
    DOI: 10.1016/j.resconrec.2011.04.002
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0921344911000516
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.resconrec.2011.04.002?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ioannidou, O. & Zabaniotou, A., 2007. "Agricultural residues as precursors for activated carbon production--A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(9), pages 1966-2005, December.
    2. Chiaramonti, David & Oasmaa, Anja & Solantausta, Yrjö, 2007. "Power generation using fast pyrolysis liquids from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(6), pages 1056-1086, August.
    3. Bridgwater, A. V. & Peacocke, G. V. C., 2000. "Fast pyrolysis processes for biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 4(1), pages 1-73, March.
    4. Williams, Paul T. & Besler, Serpil, 1996. "The influence of temperature and heating rate on the slow pyrolysis of biomass," Renewable Energy, Elsevier, vol. 7(3), pages 233-250.
    5. Gupta, K.K. & Rehman, A. & Sarviya, R.M., 2010. "Bio-fuels for the gas turbine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 2946-2955, December.
    6. Effendi, A. & Gerhauser, H. & Bridgwater, A.V., 2008. "Production of renewable phenolic resins by thermochemical conversion of biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(8), pages 2092-2116, October.
    7. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
    8. Johannes Lehmann & John Gaunt & Marco Rondon, 2006. "Bio-char Sequestration in Terrestrial Ecosystems – A Review," Mitigation and Adaptation Strategies for Global Change, Springer, vol. 11(2), pages 395-419, March.
    9. Naik, S.N. & Goud, Vaibhav V. & Rout, Prasant K. & Dalai, Ajay K., 2010. "Production of first and second generation biofuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 578-597, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kakku, Sivasankar & Naidu, Sowkhya & Chakinala, Anand G. & Joshi, Jyeshtharaj & Thota, Chiranjeevi & Maity, Pintu & Sharma, Abhishek, 2024. "Co-processing of organic fraction from groundnut shell biocrude with VGO in FCC unit to produce petrochemical products," Renewable Energy, Elsevier, vol. 224(C).
    2. Alhashimi, Hashim A. & Aktas, Can B., 2017. "Life cycle environmental and economic performance of biochar compared with activated carbon: A meta-analysis," Resources, Conservation & Recycling, Elsevier, vol. 118(C), pages 13-26.
    3. Moon, Hyeong-Bin & Lee, Ji-Hwan & Kim, Hyung-Tae & Lee, Jin-Wook & Lee, Byoung-Hwa & Jeon, Chung-Hwan, 2024. "Effect of high-pressure pyrolysis on syngas and char structure of petroleum coke," Energy, Elsevier, vol. 299(C).
    4. Zhang, Haifeng & Ju, Shuai & Jin, Xin & Yuan, Yan & Wu, Yingji & Nadda, Ashok Kumar & Pugazhendhi, Arivalagan & Cai, Liping & Xia, Changlei, 2022. "A review of sensor applications towards precise control of pyrolysis of solid waste and biomasses," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    5. Fernandez, Enara & Santamaria, Laura & Amutio, Maider & Artetxe, Maite & Arregi, Aitor & Lopez, Gartzen & Bilbao, Javier & Olazar, Martin, 2022. "Role of temperature in the biomass steam pyrolysis in a conical spouted bed reactor," Energy, Elsevier, vol. 238(PC).
    6. Hwang, Jae Gyu & Lee, Byeong Kyu & Choi, Myung Kyu & Park, Hoon Chae & Choi, Hang Seok, 2023. "Optimal production of waste tire pyrolysis oil and recovery of high value-added D-limonene in a conical spouted bed reactor," Energy, Elsevier, vol. 262(PB).
    7. Niu, Miaomiao & Sun, Rongyue & Ding, Kuan & Gu, Haiming & Cui, Xiaobo & Wang, Liang & Hu, Jichu, 2022. "Synergistic effect on thermal behavior and product characteristics during co-pyrolysis of biomass and waste tire: Influence of biomass species and waste blending ratios," Energy, Elsevier, vol. 240(C).
    8. Yao, Xiwen & Liu, Qinghua & Kang, Zijian & An, Zhixing & Zhou, Haodong & Xu, Kaili, 2023. "Quantitative study on thermal conversion behaviours and gas emission properties of biomass in nitrogen and in CO2/N2 mixtures by TGA/DTG and a fixed-bed tube furnace," Energy, Elsevier, vol. 270(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Suopajärvi, Hannu & Pongrácz, Eva & Fabritius, Timo, 2013. "The potential of using biomass-based reducing agents in the blast furnace: A review of thermochemical conversion technologies and assessments related to sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 511-528.
    2. Braimakis, Konstantinos & Atsonios, Konstantinos & Panopoulos, Kyriakos D. & Karellas, Sotirios & Kakaras, Emmanuel, 2014. "Economic evaluation of decentralized pyrolysis for the production of bio-oil as an energy carrier for improved logistics towards a large centralized gasification plant," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 57-72.
    3. Nanduri, Arvind & Kulkarni, Shreesh S. & Mills, Patrick L., 2021. "Experimental techniques to gain mechanistic insight into fast pyrolysis of lignocellulosic biomass: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    4. Li, Rui & Zeng, Kuo & Soria, José & Mazza, Germán & Gauthier, Daniel & Rodriguez, Rosa & Flamant, Gilles, 2016. "Product distribution from solar pyrolysis of agricultural and forestry biomass residues," Renewable Energy, Elsevier, vol. 89(C), pages 27-35.
    5. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    6. Antoniou, N. & Stavropoulos, G. & Zabaniotou, A., 2014. "Activation of end of life tyres pyrolytic char for enhancing viability of pyrolysis – Critical review, analysis and recommendations for a hybrid dual system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 1053-1073.
    7. Kung, Chih-Chun & McCarl, Bruce A. & Cao, Xiaoyong, 2013. "Economics of pyrolysis-based energy production and biochar utilization: A case study in Taiwan," Energy Policy, Elsevier, vol. 60(C), pages 317-323.
    8. Mirkouei, Amin & Haapala, Karl R. & Sessions, John & Murthy, Ganti S., 2017. "A review and future directions in techno-economic modeling and optimization of upstream forest biomass to bio-oil supply chains," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 15-35.
    9. Makarfi Isa, Yusuf & Ganda, Elvis Tinashe, 2018. "Bio-oil as a potential source of petroleum range fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 69-75.
    10. M. N. Uddin & Kuaanan Techato & Juntakan Taweekun & Md Mofijur Rahman & M. G. Rasul & T. M. I. Mahlia & S. M. Ashrafur, 2018. "An Overview of Recent Developments in Biomass Pyrolysis Technologies," Energies, MDPI, vol. 11(11), pages 1-24, November.
    11. Perkins, Greg & Bhaskar, Thallada & Konarova, Muxina, 2018. "Process development status of fast pyrolysis technologies for the manufacture of renewable transport fuels from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 292-315.
    12. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    13. Kambo, Harpreet Singh & Dutta, Animesh, 2015. "A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 359-378.
    14. Sulaiman, F. & Abdullah, N., 2011. "Optimum conditions for maximising pyrolysis liquids of oil palm empty fruit bunches," Energy, Elsevier, vol. 36(5), pages 2352-2359.
    15. Granada, E. & Eguía, P. & Vilan, J.A. & Comesaña, J.A. & Comesaña, R., 2012. "FTIR quantitative analysis technique for gases. Application in a biomass thermochemical process," Renewable Energy, Elsevier, vol. 41(C), pages 416-421.
    16. Chiaramonti, David & Rizzo, Andrea Maria & Spadi, Adriano & Prussi, Matteo & Riccio, Giovanni & Martelli, Francesco, 2013. "Exhaust emissions from liquid fuel micro gas turbine fed with diesel oil, biodiesel and vegetable oil," Applied Energy, Elsevier, vol. 101(C), pages 349-356.
    17. Juan Luis Aguirre & Juan Baena & María Teresa Martín & Leonor Nozal & Sergio González & José Luis Manjón & Manuel Peinado, 2020. "Composition, Ageing and Herbicidal Properties of Wood Vinegar Obtained through Fast Biomass Pyrolysis," Energies, MDPI, vol. 13(10), pages 1-17, May.
    18. Feng, Qunjie & Lin, Yunqin, 2017. "Integrated processes of anaerobic digestion and pyrolysis for higher bioenergy recovery from lignocellulosic biomass: A brief review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1272-1287.
    19. Kung, Chih-Chun & Lan, Xiaolong & Yang, Yunxia & Kung, Shan-Shan & Chang, Meng-Shiuh, 2022. "Effects of green bonds on Taiwan's bioenergy development," Energy, Elsevier, vol. 238(PA).
    20. Collazo, Joaquín & Pazó, José Antonio & Granada, Enrique & Saavedra, Ángeles & Eguía, Pablo, 2012. "Determination of the specific heat of biomass materials and the combustion energy of coke by DSC analysis," Energy, Elsevier, vol. 45(1), pages 746-752.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:recore:v:59:y:2012:i:c:p:23-31. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Kai Meng (email available below). General contact details of provider: https://www.journals.elsevier.com/resources-conservation-and-recycling .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.