IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i11p3215-d566126.html
   My bibliography  Save this article

Progress in the Use of Biobutanol Blends in Diesel Engines

Author

Listed:
  • David Fernández-Rodríguez

    (Hydrogen National Centre, Prolongación Fernando el Santo s/n, Puertollano, 13500 Ciudad Real, Spain)

  • Magín Lapuerta

    (Edificio Politécnico, Escuela Técnica Superior de Ingenieros Industriales, University of Castilla-La Mancha, Avda. Camilo José Cela s/n, 13071 Ciudad Real, Spain)

  • Lizzie German

    (E4tech UK Ltd., 83 Victoria St., London SW1H 0HW, UK)

Abstract

Nowadays, the transport sector is trying to face climate change and to contribute to a sustainable world by introducing modern after-treatment systems or by using biofuels. In sectors such as road freight transportation, agricultural or cogeneration in which the electrification is not considered feasible with the current infrastructure, renewable options for diesel engines such as alcohols produced from waste or lignocellulosic materials with advanced production techniques show a significant potential to reduce the life-cycle greenhouse emissions with respect to diesel fuel. This study concludes that lignocellulosic biobutanol can achieve 60% lower greenhouse gas emissions than diesel fuel. Butanol-diesel blends, with up to 40% butanol content, could be successfully used in a diesel engine calibrated for 100% diesel fuel without any additional engine modification nor electronic control unit recalibration at a warm ambient temperature. When n-butanol is introduced, particulate matter emissions are sharply reduced for butanol contents up to 16% (by volume), whereas NO X emissions are not negatively affected. Butanol-diesel blends could be introduced without startability problems up to 13% (by volume) butanol content at a cold ambient temperature. Therefore, biobutanol can be considered as an interesting option to be blended with diesel fuel, contributing to the decarbonization of these sectors.

Suggested Citation

  • David Fernández-Rodríguez & Magín Lapuerta & Lizzie German, 2021. "Progress in the Use of Biobutanol Blends in Diesel Engines," Energies, MDPI, vol. 14(11), pages 1-22, May.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:11:p:3215-:d:566126
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/11/3215/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/11/3215/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Li, Xiaolu & Qiao, Xinqi & Zhang, Liang & Fang, Junhua & Huang, Zhen & Xia, Huimin, 2005. "Combustion and emission characteristics of a two-stroke diesel engine operating on alcohol," Renewable Energy, Elsevier, vol. 30(13), pages 2075-2084.
    2. Pullen, James & Saeed, Khizer, 2012. "An overview of biodiesel oxidation stability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5924-5950.
    3. Mack, J. Hunter & Schuler, Daniel & Butt, Ryan H. & Dibble, Robert W., 2016. "Experimental investigation of butanol isomer combustion in Homogeneous Charge Compression Ignition (HCCI) engines," Applied Energy, Elsevier, vol. 165(C), pages 612-626.
    4. Imran, A. & Varman, M. & Masjuki, H.H. & Kalam, M.A., 2013. "Review on alcohol fumigation on diesel engine: A viable alternative dual fuel technology for satisfactory engine performance and reduction of environment concerning emission," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 739-751.
    5. Jakub Čedík & Martin Pexa & Michal Holúbek & Zdeněk Aleš & Radek Pražan & Peter Kuchar, 2020. "Effect of Diesel Fuel-Coconut Oil-Butanol Blends on Operational Parameters of Diesel Engine," Energies, MDPI, vol. 13(15), pages 1-16, July.
    6. Liu, Haifeng & Li, Shanju & Zheng, Zunqing & Xu, Jia & Yao, Mingfa, 2013. "Effects of n-butanol, 2-butanol, and methyl octynoate addition to diesel fuel on combustion and emissions over a wide range of exhaust gas recirculation (EGR) rates," Applied Energy, Elsevier, vol. 112(C), pages 246-256.
    7. Ghadikolaei, Meisam Ahmadi, 2016. "Effect of alcohol blend and fumigation on regulated and unregulated emissions of IC engines—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1440-1495.
    8. Lapuerta, Magín & Hernández, Juan José & Fernández-Rodríguez, David & Cova-Bonillo, Alexis, 2017. "Autoignition of blends of n-butanol and ethanol with diesel or biodiesel fuels in a constant-volume combustion chamber," Energy, Elsevier, vol. 118(C), pages 613-621.
    9. Rajesh Kumar, B. & Saravanan, S., 2016. "Use of higher alcohol biofuels in diesel engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 84-115.
    10. Makarevičienė, Violeta & Kazancev, Kiril & Kazanceva, Irina, 2015. "Possibilities for improving the cold flow properties of biodiesel fuel by blending with butanol," Renewable Energy, Elsevier, vol. 75(C), pages 805-807.
    11. Rodríguez-Fernández, José & Lapuerta, Magín & Sánchez-Valdepeñas, Jesús, 2017. "Regeneration of diesel particulate filters: Effect of renewable fuels," Renewable Energy, Elsevier, vol. 104(C), pages 30-39.
    12. Choi, Byungchul & Jiang, Xiaolong & Kim, Young Kwon & Jung, Gilsung & Lee, Chunhwan & Choi, Inchul & Song, Chi Sung, 2015. "Effect of diesel fuel blend with n-butanol on the emission of a turbocharged common rail direct injection diesel engine," Applied Energy, Elsevier, vol. 146(C), pages 20-28.
    13. M, Vinod Babu & K, Madhu Murthy & G, Amba Prasad Rao, 2017. "Butanol and pentanol: The promising biofuels for CI engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 1068-1088.
    14. Jin, Chao & Yao, Mingfa & Liu, Haifeng & Lee, Chia-fon F. & Ji, Jing, 2011. "Progress in the production and application of n-butanol as a biofuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 4080-4106.
    15. Giakoumis, Evangelos G. & Rakopoulos, Constantine D. & Dimaratos, Athanasios M. & Rakopoulos, Dimitrios C., 2013. "Exhaust emissions with ethanol or n-butanol diesel fuel blends during transient operation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 17(C), pages 170-190.
    16. Yang, Po-Ming & Lin, Yuan-Chung & Lin, Kuang C. & Jhang, Syu-Ruei & Chen, Shang-Cyuan & Wang, Chia-Chi & Lin, Ying-Chi, 2015. "Comparison of carbonyl compound emissions from a diesel engine generator fueled with blends of n-butanol, biodiesel and diesel," Energy, Elsevier, vol. 90(P1), pages 266-273.
    17. Chen, Zheng & Liu, Jingping & Han, Zhiyu & Du, Biao & Liu, Yun & Lee, Chiafon, 2013. "Study on performance and emissions of a passenger-car diesel engine fueled with butanol–diesel blends," Energy, Elsevier, vol. 55(C), pages 638-646.
    18. Fayad, M.A. & Tsolakis, A. & Fernández-Rodríguez, D. & Herreros, J.M. & Martos, F.J. & Lapuerta, M., 2017. "Manipulating modern diesel engine particulate emission characteristics through butanol fuel blending and fuel injection strategies for efficient diesel oxidation catalysts," Applied Energy, Elsevier, vol. 190(C), pages 490-500.
    19. Rakopoulos, Constantine D. & Dimaratos, Athanasios M. & Giakoumis, Evangelos G. & Rakopoulos, Dimitrios C., 2010. "Investigating the emissions during acceleration of a turbocharged diesel engine operating with bio-diesel or n-butanol diesel fuel blends," Energy, Elsevier, vol. 35(12), pages 5173-5184.
    20. Qi, D.H. & Geng, L.M. & Chen, H. & Bian, Y.ZH. & Liu, J. & Ren, X.CH., 2009. "Combustion and performance evaluation of a diesel engine fueled with biodiesel produced from soybean crude oil," Renewable Energy, Elsevier, vol. 34(12), pages 2706-2713.
    21. Zhang, Yu & Huang, Ronghua & Huang, Yuhan & Huang, Sheng & Zhou, Pei & Chen, Xi & Qin, Tian, 2018. "Experimental study on combustion characteristics of an n-butanol-biodiesel droplet," Energy, Elsevier, vol. 160(C), pages 490-499.
    22. Iannuzzi, Stefano E. & Valentino, Gerardo, 2014. "Comparative behavior of gasoline–diesel/butanol–diesel blends and injection strategy management on performance and emissions of a light duty diesel engine," Energy, Elsevier, vol. 71(C), pages 321-331.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Giorgia De Guido & Chiara Monticelli & Elvira Spatolisano & Laura Annamaria Pellegrini, 2021. "Separation of the Mixture 2-Propanol + Water by Heterogeneous Azeotropic Distillation with Isooctane as an Entrainer," Energies, MDPI, vol. 14(17), pages 1-18, September.
    2. José Javier López & Oscar A. de la Garza & Joaquín De la Morena & Simón Martínez-Martínez, 2021. "Influence of Cavitation in Common-Rail Diesel Nozzles on the Soot Formation Process through Measuring Soot Emissions," Energies, MDPI, vol. 14(19), pages 1-11, October.
    3. Omid Doustdar & Soheil Zeraati-Rezaei & Jose Martin Herreros & Athanasios Tsolakis & Karl D. Dearn & Miroslaw Lech Wyszynski, 2021. "Tribological Performance of Biomass-Derived Bio-Alcohol and Bio-Ketone Fuels," Energies, MDPI, vol. 14(17), pages 1-11, August.
    4. Yangxun Liu & Weinan Liu & Huihong Liao & Hasier Ashan & Wenhua Zhou & Cangsu Xu, 2022. "An Experimental and a Kinetic Modelling Study of Ethanol/Acetone/Ethyl Acetate Mixtures," Energies, MDPI, vol. 15(9), pages 1-15, April.
    5. Manju Dhakad Tanwar & Felipe Andrade Torres & Ali Mubarak Alqahtani & Pankaj Kumar Tanwar & Yashas Bhand & Omid Doustdar, 2023. "Promising Bioalcohols for Low-Emission Vehicles," Energies, MDPI, vol. 16(2), pages 1-22, January.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ghadikolaei, Meisam Ahmadi & Wong, Pak Kin & Cheung, Chun Shun & Ning, Zhi & Yung, Ka-Fu & Zhao, Jing & Gali, Nirmal Kumar & Berenjestanaki, Alireza Valipour, 2021. "Impact of lower and higher alcohols on the physicochemical properties of particulate matter from diesel engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    2. M, Vinod Babu & K, Madhu Murthy & G, Amba Prasad Rao, 2017. "Butanol and pentanol: The promising biofuels for CI engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 1068-1088.
    3. Rajesh Kumar, B. & Saravanan, S., 2016. "Use of higher alcohol biofuels in diesel engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 84-115.
    4. Zhen, Xudong & Wang, Yang & Liu, Daming, 2020. "Bio-butanol as a new generation of clean alternative fuel for SI (spark ignition) and CI (compression ignition) engines," Renewable Energy, Elsevier, vol. 147(P1), pages 2494-2521.
    5. Lapuerta, Magín & Ramos, Ángel & Barba, Javier & Fernández-Rodríguez, David, 2018. "Cold- and warm-temperature emissions assessment of n-butanol blends in a Euro 6 vehicle," Applied Energy, Elsevier, vol. 218(C), pages 173-183.
    6. Yusri, I.M. & Mamat, R. & Najafi, G. & Razman, A. & Awad, Omar I. & Azmi, W.H. & Ishak, W.F.W. & Shaiful, A.I.M., 2017. "Alcohol based automotive fuels from first four alcohol family in compression and spark ignition engine: A review on engine performance and exhaust emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 169-181.
    7. Algayyim, Sattar Jabbar Murad & Wandel, Andrew P. & Yusaf, Talal & Hamawand, Ihsan, 2017. "The impact of n-butanol and iso-butanol as components of butanol-acetone (BA) mixture-diesel blend on spray, combustion characteristics, engine performance and emission in direct injection diesel engi," Energy, Elsevier, vol. 140(P1), pages 1074-1086.
    8. Yadav, Jaykumar & Ramesh, A., 2018. "Injection strategies for reducing smoke and improving the performance of a butanol-diesel common rail dual fuel engine," Applied Energy, Elsevier, vol. 212(C), pages 1-12.
    9. Ganesh, Duraisamy & Ayyappan, P.R. & Murugan, Rangasamy, 2019. "Experimental investigation of iso-butanol/diesel reactivity controlled compression ignition combustion in a non-road diesel engine," Applied Energy, Elsevier, vol. 242(C), pages 1307-1319.
    10. Rakopoulos, Dimitrios C. & Rakopoulos, Constantine D. & Kyritsis, Dimitrios C., 2016. "Butanol or DEE blends with either straight vegetable oil or biodiesel excluding fossil fuel: Comparative effects on diesel engine combustion attributes, cyclic variability and regulated emissions trad," Energy, Elsevier, vol. 115(P1), pages 314-325.
    11. Manju Dhakad Tanwar & Felipe Andrade Torres & Ali Mubarak Alqahtani & Pankaj Kumar Tanwar & Yashas Bhand & Omid Doustdar, 2023. "Promising Bioalcohols for Low-Emission Vehicles," Energies, MDPI, vol. 16(2), pages 1-22, January.
    12. Chistyakov, A.V. & Nikolaev, S.A. & Zharova, P.A. & Tsodikov, M.V. & Manenti, F., 2019. "Linear α-alcohols production from supercritical ethanol over Cu/Al2O3 catalyst," Energy, Elsevier, vol. 166(C), pages 569-576.
    13. Lapuerta, Magín & Hernández, Juan José & Fernández-Rodríguez, David & Cova-Bonillo, Alexis, 2017. "Autoignition of blends of n-butanol and ethanol with diesel or biodiesel fuels in a constant-volume combustion chamber," Energy, Elsevier, vol. 118(C), pages 613-621.
    14. Wei Tian & Yunlu Chu & Zhiqiang Han & Xiang Wang & Wenbin Yu & Xueshun Wu, 2019. "Experimental Study of the Effect of Intake Oxygen Concentration on Engine Combustion Process and Hydrocarbon Emissions with N-Butanol-Diesel Blended Fuel," Energies, MDPI, vol. 12(7), pages 1-17, April.
    15. Wei, Liangjie & Cheung, C.S. & Huang, Zuohua, 2014. "Effect of n-pentanol addition on the combustion, performance and emission characteristics of a direct-injection diesel engine," Energy, Elsevier, vol. 70(C), pages 172-180.
    16. Fayad, Mohammed A. & Tsolakis, Athanasios & Martos, Francisco J., 2020. "Influence of alternative fuels on combustion and characteristics of particulate matter morphology in a compression ignition diesel engine," Renewable Energy, Elsevier, vol. 149(C), pages 962-969.
    17. Li, Yuqiang & Chen, Yong & Wu, Gang & Liu, Jiangwei, 2018. "Experimental evaluation of water-containing isopropanol-n-butanol-ethanol and gasoline blend as a fuel candidate in spark-ignition engine," Applied Energy, Elsevier, vol. 219(C), pages 42-52.
    18. Wei, L. & Cheung, C.S. & Ning, Z., 2018. "Effects of biodiesel-ethanol and biodiesel-butanol blends on the combustion, performance and emissions of a diesel engine," Energy, Elsevier, vol. 155(C), pages 957-970.
    19. Rakopoulos, Dimitrios C. & Rakopoulos, Constantine D. & Giakoumis, Evangelos G. & Papagiannakis, Roussos G. & Kyritsis, Dimitrios C., 2014. "Influence of properties of various common bio-fuels on the combustion and emission characteristics of high-speed DI (direct injection) diesel engine: Vegetable oil, bio-diesel, ethanol, n-butanol, die," Energy, Elsevier, vol. 73(C), pages 354-366.
    20. Liu, Kaimin & Fu, Jianqin & Deng, Banglin & Yang, Jing & Tang, Qijun & Liu, Jingping, 2014. "The influences of pressure and temperature on laminar flame propagations of n-butanol, iso-octane and their blends," Energy, Elsevier, vol. 73(C), pages 703-715.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:11:p:3215-:d:566126. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.