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Experimental investigation of butanol isomer combustion in Homogeneous Charge Compression Ignition (HCCI) engines

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  • Mack, J. Hunter
  • Schuler, Daniel
  • Butt, Ryan H.
  • Dibble, Robert W.

Abstract

Longer chain alcohols, such as butanol, possess major physiochemical advantages over ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. In this study, two butanol isomers (n-butanol and isobutanol) are investigated as potential fuels for Homogeneous Charge Compression Ignition (HCCI) engines. Wide ranges of intake pressure and equivalence ratio are investigated and the results are presented in comparison to ethanol and gasoline as reference fuels. Under all tested conditions, the butanol isomers require lower intake temperatures for a fixed combustion phasing, indicating higher HCCI reactivity. Both isomers show single-stage ignition behavior at all test points and behave similarly in regard to the combustion stability. Engine operation using n-butanol is slightly more stable under all conditions and misfiring occurs slightly later under very lean and naturally aspirated conditions. Similar to gasoline, n-butanol shows a higher heat release rate (HRR) at the beginning of combustion. The intermediate temperature heat release (ITHR) lowers the coefficient of variation (CoV) of IMEPg (gross indicated mean effective pressure), especially at retarded combustion timing and lean mixtures. However, the knock resistance of n-butanol is lower compared to isobutanol and the other tested fuels. The exhaust emissions of the two butanol isomers are in the same range as the two reference fuels. Overall, the results indicate that butanol is suited for use as a fuel in HCCI engines, either in neat form or in blend with gasoline.

Suggested Citation

  • Mack, J. Hunter & Schuler, Daniel & Butt, Ryan H. & Dibble, Robert W., 2016. "Experimental investigation of butanol isomer combustion in Homogeneous Charge Compression Ignition (HCCI) engines," Applied Energy, Elsevier, vol. 165(C), pages 612-626.
    • Handle: RePEc:eee:appene:v:165:y:2016:i:c:p:612-626
    DOI: 10.1016/j.apenergy.2015.12.105
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    References listed on IDEAS

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    1. Shota Atsumi & Taizo Hanai & James C. Liao, 2008. "Non-fermentative pathways for synthesis of branched-chain higher alcohols as biofuels," Nature, Nature, vol. 451(7174), pages 86-89, January.
    2. Maurya, Rakesh Kumar & Agarwal, Avinash Kumar, 2011. "Experimental study of combustion and emission characteristics of ethanol fuelled port injected homogeneous charge compression ignition (HCCI) combustion engine," Applied Energy, Elsevier, vol. 88(4), pages 1169-1180, April.
    3. Jin, Chao & Yao, Mingfa & Liu, Haifeng & Lee, Chia-fon F. & Ji, Jing, 2011. "Progress in the production and application of n-butanol as a biofuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 4080-4106.
    4. Mack, J. Hunter & Aceves, Salvador M. & Dibble, Robert W., 2009. "Demonstrating direct use of wet ethanol in a homogeneous charge compression ignition (HCCI) engine," Energy, Elsevier, vol. 34(6), pages 782-787.
    5. Viggiano, Annarita & Magi, Vinicio, 2012. "A comprehensive investigation on the emissions of ethanol HCCI engines," Applied Energy, Elsevier, vol. 93(C), pages 277-287.
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    9. André L. Olson & Martin Tunér & Sebastian Verhelst, 2023. "A Review of Isobutanol as a Fuel for Internal Combustion Engines," Energies, MDPI, vol. 16(22), pages 1-28, November.
    10. Ganesh, Duraisamy & Ayyappan, P.R. & Murugan, Rangasamy, 2019. "Experimental investigation of iso-butanol/diesel reactivity controlled compression ignition combustion in a non-road diesel engine," Applied Energy, Elsevier, vol. 242(C), pages 1307-1319.
    11. Bissoli, M. & Frassoldati, A. & Cuoci, A. & Ranzi, E. & Mehl, M. & Faravelli, T., 2016. "A new predictive multi-zone model for HCCI engine combustion," Applied Energy, Elsevier, vol. 178(C), pages 826-843.
    12. Komninos, N.P. & Rakopoulos, C.D., 2016. "Heat transfer in hcci phenomenological simulation models: A review," Applied Energy, Elsevier, vol. 181(C), pages 179-209.
    13. Jia, Guorui & Wang, Hu & Tong, Laihui & Wang, Xiaofeng & Zheng, Zunqing & Yao, Mingfa, 2017. "Experimental and numerical studies on three gasoline surrogates applied in gasoline compression ignition (GCI) mode," Applied Energy, Elsevier, vol. 192(C), pages 59-70.
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