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Microwave mediated enhanced production of 5-hydroxymethylfurfural using choline chloride-based eutectic mixture as sustainable catalyst

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  • Mankar, Akshay R.
  • Pandey, Ashish
  • Modak, Arindam
  • Pant, K.K.

Abstract

The present work is a significant contribution to the production of 5-hydroxymethylfurfural (5-HMF) from carbohydrates-based feedstocks using environmentally benign choline chloride (ChCl)-based deep eutectic solvents (DESs) as catalyst in the presence of an inexpensive acetone/water solvent system. Under microwave irradiations, the acidity of organic acids in DESs can be a key criterion in screening out different eutectic mixtures. Among others, the ChCl: Lactic acid (LA) mixture was found to be the most efficient DES giving a 5-HMF yield of 30.12% on fructose dehydration. Optimization of different reaction parameters resulted in an enhanced 5-HMF yield of 87.2% in 30 min at 140 °C using ChCl: LA DES. The synergistic effect between LA and ChCl is also highlighted in boosting the 5-HMF yield. As compared to conventional oil bath heating, microwave heating resulted in significantly higher 5-HMF yield at a lower reaction time. The catalytic system ChCl: LA showed an appreciable yield of 5-HMF ranging from 83.1 to 71.2% for 5 recycle runs. Overall, we have developed a low cost, easy, energy-effective, green, and sustainable process ensuring high 5-HMF production.

Suggested Citation

  • Mankar, Akshay R. & Pandey, Ashish & Modak, Arindam & Pant, K.K., 2021. "Microwave mediated enhanced production of 5-hydroxymethylfurfural using choline chloride-based eutectic mixture as sustainable catalyst," Renewable Energy, Elsevier, vol. 177(C), pages 643-651.
    • Handle: RePEc:eee:renene:v:177:y:2021:i:c:p:643-651
    DOI: 10.1016/j.renene.2021.05.157
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    References listed on IDEAS

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    1. Liu, Ying & Yan, Hanzhao & Liu, Jia & Dong, Wanglai & Cao, Zhi & Hu, Xingbang & Zhou, Zheng, 2020. "Acidic deep eutectic solvents with long carbon chains as catalysts and reaction media for biodiesel production," Renewable Energy, Elsevier, vol. 162(C), pages 1842-1853.
    2. Sert, Murat & Arslanoğlu, Alparslan & Ballice, Levent, 2018. "Conversion of sunflower stalk based cellulose to the valuable products using choline chloride based deep eutectic solvents," Renewable Energy, Elsevier, vol. 118(C), pages 993-1000.
    3. Najafi Sarpiri, Jaleh & Najafi Chermahini, Alireza & Saraji, Mohammad & Shahvar, Ali, 2021. "Dehydration of carbohydrates into 5-hydroxymethylfurfural over vanadyl pyrophosphate catalysts," Renewable Energy, Elsevier, vol. 164(C), pages 11-22.
    4. Sert, Murat, 2020. "Catalytic effect of acidic deep eutectic solvents for the conversion of levulinic acid to ethyl levulinate," Renewable Energy, Elsevier, vol. 153(C), pages 1155-1162.
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    1. Tu, Shanshan & Yu, Xiaojie & Ji, Qinghua & Ma, Qiannan & Zhou, Cunshan & Chen, Li & Okonkwo, Clinton Emeka, 2022. "Exploration of lower critical solution temperature DES in a thermoreversible aqueous two-phase system for integrating glucose conversion and 5-HMF separation," Renewable Energy, Elsevier, vol. 189(C), pages 392-401.
    2. Niakan, Mahsa & Masteri-Farahani, Majid & Seidi, Farzad, 2022. "Efficient glucose-to-HMF conversion in deep eutectic solvents over sulfonated dendrimer modified activated carbon," Renewable Energy, Elsevier, vol. 200(C), pages 1134-1140.

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