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Catalytic dehydration of fructose into 5-hydroxymethylfurfural by propyl sulfonic acid functionalized magnetic graphene oxide nanocomposite

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  • Karimi, Sabah
  • Seidi, Farzad
  • Niakan, Mahsa
  • Shekaari, Hemayat
  • Masteri-Farahani, Majid

Abstract

Covalent immobilization of propyl sulfonic acid groups on the surface of magnetic graphene oxide is reported as an efficient magnetically recoverable solid acid catalyst for the conversion of fructose into 5-hydroxymethylfurfural (5-HMF). The obtained nanocomposite has advantages of both graphene oxide (high surface area) and magnetic nanoparticles (fast and facile separation by a magnet). The numerous reaction parameters including solvent, reaction time, temperature, and amount of catalyst were optimized to attain maximum yield of 5-HMF. The results revealed that fructose could be effectively transformed into 5-HMF with a yield of 87% under the optimized reaction conditions. The catalyst could be magnetically separated from the reaction mixture. Moreover, the catalyst exhibited high stability and could be reused for at least five times without a discernible loss of catalytic performance.

Suggested Citation

  • Karimi, Sabah & Seidi, Farzad & Niakan, Mahsa & Shekaari, Hemayat & Masteri-Farahani, Majid, 2021. "Catalytic dehydration of fructose into 5-hydroxymethylfurfural by propyl sulfonic acid functionalized magnetic graphene oxide nanocomposite," Renewable Energy, Elsevier, vol. 180(C), pages 132-139.
    • Handle: RePEc:eee:renene:v:180:y:2021:i:c:p:132-139
    DOI: 10.1016/j.renene.2021.08.048
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    References listed on IDEAS

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    1. Masteri-Farahani, Majid & Hosseini, Mahdiyeh-Sadat & Forouzeshfar, Newsha, 2020. "Propyl-SO3H functionalized graphene oxide as multipurpose solid acid catalyst for biodiesel synthesis and acid-catalyzed esterification and acetalization reactions," Renewable Energy, Elsevier, vol. 151(C), pages 1092-1101.
    2. Najafi Sarpiri, Jaleh & Najafi Chermahini, Alireza & Saraji, Mohammad & Shahvar, Ali, 2021. "Dehydration of carbohydrates into 5-hydroxymethylfurfural over vanadyl pyrophosphate catalysts," Renewable Energy, Elsevier, vol. 164(C), pages 11-22.
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    1. Niakan, Mahsa & Masteri-Farahani, Majid & Seidi, Farzad, 2022. "Efficient glucose-to-HMF conversion in deep eutectic solvents over sulfonated dendrimer modified activated carbon," Renewable Energy, Elsevier, vol. 200(C), pages 1134-1140.
    2. Cai, Bo & Kang, Rui & Guo, Dayi & Feng, Junfeng & Ma, Tianyi & Pan, Hui, 2022. "An eco-friendly acidic catalyst phosphorus-doped graphitic carbon nitride for efficient conversion of fructose to 5-Hydroxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1629-1638.
    3. Feng, Weiliang & Tie, Xinlong & Duan, Xiaoling & Yan, Su & Fang, Si & Sun, Peiyong & Gan, Lin & Wang, Tielin, 2023. "Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from," Renewable Energy, Elsevier, vol. 210(C), pages 26-39.
    4. Niakan, Mahsa & Masteri-Farahani, Majid & Seidi, Farzad, 2023. "Sulfonated ionic liquid immobilized SBA-16 as an active solid acid catalyst for the synthesis of biofuel precursor 5-hydroxymethylfurfural from fructose," Renewable Energy, Elsevier, vol. 212(C), pages 50-56.
    5. Dowaki, Taishi & Guo, Haixin & Smith, Richard Lee, 2022. "Lignin-derived biochar solid acid catalyst for fructose conversion into 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 199(C), pages 1534-1542.
    6. Yang, Xiaoxun & Sadughi, Mohammad Mehdi & Bahadoran, Ashkan & Al-Haideri, Maysoon & Ghamari Kargar, Pouya & Noori, Aiyah S. & Sajjadinezhad, Seyed Mehrzad, 2023. "A new method for conversion of fructose and glucose to 5-hydroxymethylfurfural by magnetic mesoporous of SBA-16 was modified to sulfonic acid as Lewis's acid catalysts," Renewable Energy, Elsevier, vol. 209(C), pages 145-156.
    7. Wang, Shuai & Eberhardt, Thomas L. & Guo, Dayi & Feng, Junfeng & Pan, Hui, 2022. "Efficient conversion of glucose into 5-HMF catalyzed by lignin-derived mesoporous carbon solid acid in a biphasic system," Renewable Energy, Elsevier, vol. 190(C), pages 1-10.
    8. Shi, Xian & Xing, Xinyi & Liu, Wanni & Ruan, Mengya & Guan, Ying & Lyu, Gaojin & Gao, Hui & Xu, Siquan, 2024. "Cellulose conversion to 5-hydroxymethylfurfural via a simple and efficient phosphate-doped hafnium oxide catalyst," Renewable Energy, Elsevier, vol. 226(C).

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