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Conversion of sunflower stalk based cellulose to the valuable products using choline chloride based deep eutectic solvents

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  • Sert, Murat
  • Arslanoğlu, Alparslan
  • Ballice, Levent

Abstract

The direct conversion of cellulose into valuable products such as 5- hydroxymethyl furfural (5-HMF), levulinic acid, furfural and formic acid was studied using deep eutectic solvents in conventional and microwave reactors. Starting from sunflower stalk based cellulose, the mechanism of degradation was highlighted and applicability of deep eutectic solvents as solvent and catalyst was searched. Three different deep eutectic solvents (DES) were synthesized using choline chloride as hydrogen bond acceptor and oxalic acid/citric acid/tartaric acid as hydrogen bond donor. The most effective DES was found as DESO formed by choline chloride and oxalic acid. Using DESO as catalyst and solvent, 99.07% of carbon efficiency was achieved at 180 °C in microwave reactor within only 1 min. At these conditions, 76.2% of levulinic acid, 4.07% of 5-HMF, 5.57% of furfural and 15.24% of formic acid were obtained. We described simple, cheap, catalytically effective and environmentally friendly process for the conversion of cellulose into valuable products. DESs showed superior properties for the solvation of cellulose and catalyzed the reactions of cellulose.

Suggested Citation

  • Sert, Murat & Arslanoğlu, Alparslan & Ballice, Levent, 2018. "Conversion of sunflower stalk based cellulose to the valuable products using choline chloride based deep eutectic solvents," Renewable Energy, Elsevier, vol. 118(C), pages 993-1000.
    • Handle: RePEc:eee:renene:v:118:y:2018:i:c:p:993-1000
    DOI: 10.1016/j.renene.2017.10.083
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    Cited by:

    1. He, Zhuosen & Hou, Yucui & Li, He & Wei, Jian & Ren, Shuhang & Wu, Weize, 2023. "Novel chemical looping oxidation of biomass-derived carbohydrates to super-high-yield formic acid using heteropolyacids as oxygen carrier," Renewable Energy, Elsevier, vol. 207(C), pages 461-470.
    2. Lin, Jianying & Liu, Qiyu & Guan, Mingzhao & Liang, Haotong & Chen, Panpan & Ma, Qiaozhi & Jiang, Enchen, 2023. "Autohydrolysis pretreatment of corn stalk for improved 5-hydroxymethylfurfural production in molten salt hydrate/acetone," Renewable Energy, Elsevier, vol. 217(C).
    3. Shen, Feng & Li, Ye & Qin, Xiaoya & Guo, Haixin & Li, Jialu & Yang, Jirui & Ding, Yongzhen, 2022. "Selective oxidation of cellulose into formic acid over heteropolyacid-based temperature responsive catalysts," Renewable Energy, Elsevier, vol. 185(C), pages 139-146.
    4. Du, Ya-Peng & Tian, Xin-Yu & Zheng, Xiao-Ping & Chai, Yu & Zhang, Yu-Cang & Zheng, Yan-Zhen, 2024. "Efficient preparation of 5-hydroxymethylfurfural from cellulose via one-step combination of mechanical and chemical pre-treatment," Renewable Energy, Elsevier, vol. 229(C).
    5. Chai, Yu & Tian, Xin-Yu & Zheng, Xiao-Ping & Du, Ya-Peng & Zhang, Yu-Cang & Zheng, Yan-Zhen, 2024. "An effective approach for chitosan conversion to 5-hydroxymethylfurfural catalyzed by bio-based organic acid with ionic liquids additive," Renewable Energy, Elsevier, vol. 221(C).
    6. Yang, Luan & Zheng, Tianran & Huang, Chen & Yao, Jianfeng, 2022. "Using deep eutectic solvent pretreatment for enhanced enzymatic saccharification and lignin utilization of masson pine," Renewable Energy, Elsevier, vol. 195(C), pages 681-687.
    7. Lee, Cornelius Basil Tien Loong & Wu, Ta Yeong, 2021. "A review on solvent systems for furfural production from lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    8. Lu, Qiaomin & Yan, Dong & Wu, Peiwen & Chen, Li & Yagoub, Abu ElGasim A. & Ji, Qinghua & Yu, Xiaojie & Zhou, Cunshan, 2022. "Ultrasound-NATDES/DMSO system for corn straw biomass conversion into platform compounds," Renewable Energy, Elsevier, vol. 190(C), pages 675-683.
    9. Tang, Yiwei & Liu, Xiaoning & Xi, Ran & Liu, Le & Qi, Xinhua, 2022. "Catalytic one-pot conversion of biomass-derived furfural to ethyl levulinate over bifunctional Nb/Ni@OMC," Renewable Energy, Elsevier, vol. 200(C), pages 821-831.
    10. Xiao, Tianyuan & Hou, Minjie & Guo, Xu & Cao, Xinyu & Li, Changgeng & Zhang, Qi & Jia, Wenchao & Sun, Yanning & Guo, Yanzhu & Shi, Haiqiang, 2024. "Recent progress in deep eutectic solvent(DES) fractionation of lignocellulosic components ： A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    11. Mankar, Akshay R. & Pandey, Ashish & Modak, Arindam & Pant, K.K., 2021. "Microwave mediated enhanced production of 5-hydroxymethylfurfural using choline chloride-based eutectic mixture as sustainable catalyst," Renewable Energy, Elsevier, vol. 177(C), pages 643-651.
    12. Sert, Murat, 2020. "Catalytic effect of acidic deep eutectic solvents for the conversion of levulinic acid to ethyl levulinate," Renewable Energy, Elsevier, vol. 153(C), pages 1155-1162.

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