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Selective oxidation of cellulose into formic acid over heteropolyacid-based temperature responsive catalysts

Author

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  • Shen, Feng
  • Li, Ye
  • Qin, Xiaoya
  • Guo, Haixin
  • Li, Jialu
  • Yang, Jirui
  • Ding, Yongzhen

Abstract

Formic acid (FA) is one of the most promising vectors for sustainable hydrogen energy and it can be synthesized from renewable biomass resources. In this work, a range of heteropolyacid derived temperature-responsive catalysts (ChnH4-nPMo11VO40, n=1–3) were prepared by modifying H3PMo12O40 heteropolyacid with an oxidation site V5+ and temperature-responsive monomer choline chloride (Ch+), and used for the cascade conversion of biomass derived cellulose into FA via hydrolysis-oxidation in water. The ChH3PMo11VO40 with a Ch/H ratio of 1/3 exhibited an outstanding catalytic performance to give a 49.5% yield of FA at 165 °C after 3 h reaction time. Catalytic activity of ChnH4-nPMo11VO40 was found to be related to its amount of H+ and V5+, while the recyclable ability of ChnH4-nPMo11VO40 was found to be related to its amount of Ch+. The as-prepared catalyst could be perfectly recycled with a single decrease the temperature of reaction systems, and be reused four times with limit loss in catalytic activity. The developed temperature-responsive catalysts have both advantages of homogeneous catalyst and heterogeneous catalyst, which should have potential application in other reactions of lignocellulosic biomass valorization.

Suggested Citation

  • Shen, Feng & Li, Ye & Qin, Xiaoya & Guo, Haixin & Li, Jialu & Yang, Jirui & Ding, Yongzhen, 2022. "Selective oxidation of cellulose into formic acid over heteropolyacid-based temperature responsive catalysts," Renewable Energy, Elsevier, vol. 185(C), pages 139-146.
    • Handle: RePEc:eee:renene:v:185:y:2022:i:c:p:139-146
    DOI: 10.1016/j.renene.2021.12.043
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    References listed on IDEAS

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    1. Sullivan, James A. & Burnham, Sarah, 2015. "The use of alkaline earth oxides as pH modifiers for selective glycerol oxidation over supported Au catalysts," Renewable Energy, Elsevier, vol. 78(C), pages 89-92.
    2. Bidyut Bikash Sarma & Ronny Neumann, 2014. "Polyoxometalate-mediated electron transfer–oxygen transfer oxidation of cellulose and hemicellulose to synthesis gas," Nature Communications, Nature, vol. 5(1), pages 1-6, December.
    3. Sert, Murat & Arslanoğlu, Alparslan & Ballice, Levent, 2018. "Conversion of sunflower stalk based cellulose to the valuable products using choline chloride based deep eutectic solvents," Renewable Energy, Elsevier, vol. 118(C), pages 993-1000.
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    1. He, Zhuosen & Hou, Yucui & Li, He & Wei, Jian & Ren, Shuhang & Wu, Weize, 2023. "Novel chemical looping oxidation of biomass-derived carbohydrates to super-high-yield formic acid using heteropolyacids as oxygen carrier," Renewable Energy, Elsevier, vol. 207(C), pages 461-470.
    2. Gromov, Nikolay V. & Medvedeva, Tatiana B. & Lukoyanov, Ivan A. & Ogorodnikova, Olga L. & Panchenko, Valentina N. & Parmon, Valentin N. & Timofeeva, Maria N., 2024. "Hydrolysis-oxidation of starch to formic acid in the presence of vanadium-containing molybdophosphoric heteropoly acid (H3+xPMo12-xVxO40): Effect of acidity and vanadium content on the yield of formic," Renewable Energy, Elsevier, vol. 220(C).

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