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Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties

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  • Gao, Xiu
  • Chen, Chao
  • Zhang, Wenlu
  • Hong, Yanping
  • Wang, Chunrong
  • Wu, Guoqiang

Abstract

A series of sulfated TiO2 supported Mo (xMo/1.5ST) catalysts were synthesized successfully and evaluated for the transesterification of Jatropha seed oil (JO) to biodiesel. Extensive characterization exhibits that the well dispersed Mo oxide species, with Mo6+ and Mo5+ oxidation states, were formed on the surface of the sulfated TiO2. The results indicate the presence of many sulfates species leads to the reduction of Mo6+ species to Mo5+ species. Furthermore, the catalytic activity of the xMo/1.5ST catalysts gradually increases with the increase of Mo-loading, although the sulfates content and the total acid intensity decrease. The transesterification process was fully investigated, and the 10Mo/1.5ST shows the highest yield of biodiesel of up to 97.42%. Additionally, the possible mechanism for the JO transesterification over Mo/1.5ST was described, and the fuel properties of the as-synthesized biodiesel conformed to the current international standards.

Suggested Citation

  • Gao, Xiu & Chen, Chao & Zhang, Wenlu & Hong, Yanping & Wang, Chunrong & Wu, Guoqiang, 2022. "Sulfated TiO2 supported molybdenum-based catalysts for transesterification of Jatropha seed oil: Effect of molybdenum species and acidity properties," Renewable Energy, Elsevier, vol. 191(C), pages 357-369.
    • Handle: RePEc:eee:renene:v:191:y:2022:i:c:p:357-369
    DOI: 10.1016/j.renene.2022.04.021
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    1. Zhang, Gaoqiang & Xie, Wenlei, 2024. "Hierarchical porous SAPO-34 decorated with Mo and W oxides for concurrent transesterification-esterifications for efficient biodiesel production from acidic soybean oil," Renewable Energy, Elsevier, vol. 222(C).

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