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Recent progress in deep eutectic solvent(DES) fractionation of lignocellulosic components ： A review

Author

Listed:
  • Xiao, Tianyuan
  • Hou, Minjie
  • Guo, Xu
  • Cao, Xinyu
  • Li, Changgeng
  • Zhang, Qi
  • Jia, Wenchao
  • Sun, Yanning
  • Guo, Yanzhu
  • Shi, Haiqiang

Abstract

High-value utilization of plant resources is crucial for achieving carbon neutrality and complete carbon transformation. Significant progress has already been made in the comprehensive utilization of plant resources through pretreatment methods, particularly the deep eutectic solvent (DES) method for the pretreatment of plant fibers. This method enables sustainable development of lignocellulose deconstruction and high-value utilization. This paper provided a review of the composition, classification, and properties of different types of DES. It also investigated the effects of stoichiometric ratio, temperature, time, microwave, ultrasonic, hydrothermal, and emulsification on lignocellulose deconstruction using the DES. Additionally, the study explored the use and prospects of lignocellulosic fractions in lignin extraction, enzymatic saccharification, and high-value cellulose production using functional DES systems. The evaluation of the DES functionality is conducted through quantum chemistry, molecular simulation calculations, and the DES recycling effects (optimum 10 cycles). The mechanism of DES in lignocellulosic extraction is elucidated, and the prospects for sustainable development are outlined.

Suggested Citation

  • Xiao, Tianyuan & Hou, Minjie & Guo, Xu & Cao, Xinyu & Li, Changgeng & Zhang, Qi & Jia, Wenchao & Sun, Yanning & Guo, Yanzhu & Shi, Haiqiang, 2024. "Recent progress in deep eutectic solvent(DES) fractionation of lignocellulosic components ： A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    • Handle: RePEc:eee:rensus:v:192:y:2024:i:c:s1364032123011012
    DOI: 10.1016/j.rser.2023.114243
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    References listed on IDEAS

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    1. Sert, Murat & Arslanoğlu, Alparslan & Ballice, Levent, 2018. "Conversion of sunflower stalk based cellulose to the valuable products using choline chloride based deep eutectic solvents," Renewable Energy, Elsevier, vol. 118(C), pages 993-1000.
    2. Yongzhuang Liu & Noemi Deak & Zhiwen Wang & Haipeng Yu & Lisanne Hameleers & Edita Jurak & Peter J. Deuss & Katalin Barta, 2021. "Tunable and functional deep eutectic solvents for lignocellulose valorization," Nature Communications, Nature, vol. 12(1), pages 1-15, December.
    3. Akinola David Olugbemide & Ana Oberlintner & Uroš Novak & Blaž Likozar, 2021. "Lignocellulosic Corn Stover Biomass Pre-Treatment by Deep Eutectic Solvents (DES) for Biomethane Production Process by Bioresource Anaerobic Digestion," Sustainability, MDPI, vol. 13(19), pages 1-13, September.
    4. Zhou, Man & Fakayode, Olugbenga Abiola & Ahmed Yagoub, Abu ElGasim & Ji, Qinghua & Zhou, Cunshan, 2022. "Lignin fractionation from lignocellulosic biomass using deep eutectic solvents and its valorization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    5. Xie, Junxian & Cheng, Zheng & Zhu, Shiyun & Xu, Jun, 2022. "Lewis base enhanced neutral deep eutectic solvent pretreatment for enzymatic hydrolysis of corn straw and lignin characterization," Renewable Energy, Elsevier, vol. 188(C), pages 320-328.
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