IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v146y2020icp719-726.html
   My bibliography  Save this article

Heterogeneous catalyst screening for fatty acid methyl esters production through interesterification reaction

Author

Listed:
  • Simões, S.S.
  • Ribeiro, J.S.
  • Celante, D.
  • Brondani, L.N.
  • Castilhos, F.

Abstract

This study aimed the investigation of a potential heterogeneous catalyst for the interesterification reaction for soybean biodiesel production. Different types of catalysts (Y Zeolite, MgO, Nb2O5 and mixed oxides) were tested in this work. Ca–Mg–Al mixed oxide with 40% wt. Ca was the more suitable catalyst for interesterification reaction. Effects of temperature, catalyst content and methyl acetate to oil molar ratio on product yields were investigated through kinetic experiments. Kinetic behavior of intermediate compounds was also assessed. The best experimental condition was 325 °C, 40:1 methyl acetate/oil molar ratio and 5% wt. of catalyst/oil, with a global yield of 68.55% reached in 80 min with pressure ranged between 5 and 10 MPa. A catalyst reusing test was carried out in this condition. The reaction could be performed for at least three times with the same initial catalyst without a significant activity decay.

Suggested Citation

  • Simões, S.S. & Ribeiro, J.S. & Celante, D. & Brondani, L.N. & Castilhos, F., 2020. "Heterogeneous catalyst screening for fatty acid methyl esters production through interesterification reaction," Renewable Energy, Elsevier, vol. 146(C), pages 719-726.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:719-726
    DOI: 10.1016/j.renene.2019.07.023
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119310432
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.07.023?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Bolonio, David & García-Martínez, María-Jesús & Ortega, Marcelo F. & Lapuerta, Magín & Rodríguez-Fernández, José & Canoira, Laureano, 2019. "Fatty acid ethyl esters (FAEEs) obtained from grapeseed oil: A fully renewable biofuel," Renewable Energy, Elsevier, vol. 132(C), pages 278-283.
    2. Calero, Juan & Luna, Diego & Sancho, Enrique D. & Luna, Carlos & Bautista, Felipa M. & Romero, Antonio A. & Posadillo, Alejandro & Berbel, Julio & Verdugo-Escamilla, Cristóbal, 2015. "An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1437-1452.
    3. Sandouqa, Arwa & Al-Hamamre, Zayed, 2019. "Energy analysis of biodiesel production from jojoba seed oil," Renewable Energy, Elsevier, vol. 130(C), pages 831-842.
    4. Sajjadi, Baharak & Raman, Abdul Aziz Abdul & Arandiyan, Hamidreza, 2016. "A comprehensive review on properties of edible and non-edible vegetable oil-based biodiesel: Composition, specifications and prediction models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 62-92.
    5. Mutreja, Vishal & Singh, Satnam & Ali, Amjad, 2011. "Biodiesel from mutton fat using KOH impregnated MgO as heterogeneous catalysts," Renewable Energy, Elsevier, vol. 36(8), pages 2253-2258.
    6. Likozar, Blaž & Levec, Janez, 2014. "Transesterification of canola, palm, peanut, soybean and sunflower oil with methanol, ethanol, isopropanol, butanol and tert-butanol to biodiesel: Modelling of chemical equilibrium, reaction kinetics ," Applied Energy, Elsevier, vol. 123(C), pages 108-120.
    7. Mendonça, Iasmin M. & Paes, Orlando A.R.L. & Maia, Paulo J.S. & Souza, Mayane P. & Almeida, Richardson A. & Silva, Cláudia C. & Duvoisin, Sérgio & de Freitas, Flávio A., 2019. "New heterogeneous catalyst for biodiesel production from waste tucumã peels (Astrocaryum aculeatum Meyer): Parameters optimization study," Renewable Energy, Elsevier, vol. 130(C), pages 103-110.
    8. Arumugam, A. & Ponnusami, V., 2019. "Biodiesel production from Calophyllum inophyllum oil a potential non-edible feedstock: An overview," Renewable Energy, Elsevier, vol. 131(C), pages 459-471.
    9. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Biodiesel production from waste cooking oil via supercritical methanol: Optimisation and reactor simulation," Renewable Energy, Elsevier, vol. 124(C), pages 144-154.
    10. Kanjaikaew, Utaiwan & Tongurai, Chakrit & Chongkhong, Sininart & Prasertsit, Kulchanat, 2018. "Two-step esterification of palm fatty acid distillate in ethyl ester production: Optimization and sensitivity analysis," Renewable Energy, Elsevier, vol. 119(C), pages 336-344.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wong, Wan-Ying & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Lam, Man-Kee & Tan, Inn-Shi & Chen, Wei-Hsin, 2023. "A comprehensive review of the production methods and effect of parameters for glycerol-free biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    2. Rafael Estevez & Laura Aguado-Deblas & Francisco J. López-Tenllado & Carlos Luna & Juan Calero & Antonio A. Romero & Felipa M. Bautista & Diego Luna, 2022. "Biodiesel Is Dead: Long Life to Advanced Biofuels—A Comprehensive Critical Review," Energies, MDPI, vol. 15(9), pages 1-39, April.
    3. Brondani, L.N. & Ribeiro, J.S. & Castilhos, F., 2020. "A new kinetic model for simultaneous interesterification and esterification reactions from methyl acetate and highly acidic oil," Renewable Energy, Elsevier, vol. 156(C), pages 579-590.
    4. Reza Nageubri Balfas & Azhari Muhammad Syam & Muhammad Muhammad & Adi Setiawan & Herman Fithra, 2024. "Characteristics of Biodiesel Produced from Crude Palm Oil through Non-Alcohol Synthesis Route Using Dimethyl Carbonate and Immobilized Eco-Enzyme Catalyst," Energies, MDPI, vol. 17(7), pages 1-16, March.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    2. Che Zhao & Hongyuan Chen & Xiao Wu & Rui Shan, 2023. "Exploiting the Waste Biomass of Durian Shell as a Heterogeneous Catalyst for Biodiesel Production at Room Temperature," IJERPH, MDPI, vol. 20(3), pages 1-10, January.
    3. Sierra-Cantor, Jonathan Fabián & Guerrero-Fajardo, Carlos Alberto, 2017. "Methods for improving the cold flow properties of biodiesel with high saturated fatty acids content: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 774-790.
    4. Dehghani, Sahar & Haghighi, Mohammad, 2020. "Sono-enhanced dispersion of CaO over Zr-Doped MCM-41 bifunctional nanocatalyst with various Si/Zr ratios for conversion of waste cooking oil to biodiesel," Renewable Energy, Elsevier, vol. 153(C), pages 801-812.
    5. De-Chang Li & Zhengyi Pan & Zhengbin Tian & Qian Zhang & Xiaohui Deng & Heqing Jiang & Guang-Hui Wang, 2024. "Frustrated Lewis pair catalyst realizes efficient green diesel production," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    6. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    7. Miladinović, Marija R. & Zdujić, Miodrag V. & Veljović, Djordje N. & Krstić, Jugoslav B. & Banković-Ilić, Ivana B. & Veljković, Vlada B. & Stamenković, Olivera S., 2020. "Valorization of walnut shell ash as a catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 147(P1), pages 1033-1043.
    8. Shunli Feng & Yihan Guo & Yulu Ran & Qingzhuoma Yang & Xiyue Cao & Huahao Yang & Yu Cao & Qingrui Xu & Dairong Qiao & Hui Xu & Yi Cao, 2023. "Production of Microbial Lipids by Saitozyma podzolica Zwy2-3 Using Corn Straw Hydrolysate, the Analysis of Lipid Composition, and the Prediction of Biodiesel Properties," Energies, MDPI, vol. 16(18), pages 1-22, September.
    9. Vela-García, Nicolas & Bolonio, David & Mosquera, Ana María & Ortega, Marcelo F. & García-Martínez, María-Jesús & Canoira, Laureano, 2020. "Techno-economic and life cycle assessment of triisobutane production and its suitability as biojet fuel," Applied Energy, Elsevier, vol. 268(C).
    10. Babatunde Oladipo & Tunde V Ojumu & Lekan M Latinwo & Eriola Betiku, 2020. "Pawpaw ( Carica papaya ) Peel Waste as a Novel Green Heterogeneous Catalyst for Moringa Oil Methyl Esters Synthesis: Process Optimization and Kinetic Study," Energies, MDPI, vol. 13(21), pages 1-25, November.
    11. Bet-Moushoul, Elsie & Farhadi, Khalil & Mansourpanah, Yaghoub & Molaie, Rahim & Forough, Mehrdad & Nikbakht, Ali Mohammad, 2016. "Development of novel Ag/bauxite nanocomposite as a heterogeneous catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 92(C), pages 12-21.
    12. Teoh, Y.H. & How, H.G. & Masjuki, H.H. & Nguyen, H.-T. & Kalam, M.A. & Alabdulkarem, A., 2019. "Investigation on particulate emissions and combustion characteristics of a common-rail diesel engine fueled with Moringa oleifera biodiesel-diesel blends," Renewable Energy, Elsevier, vol. 136(C), pages 521-534.
    13. Subramaniam, D. & Murugesan, A. & Avinash, A. & Kumaravel, A., 2013. "Bio-diesel production and its engine characteristics—An expatiate view," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 361-370.
    14. Mia Gotovuša & Ivan Pucko & Marko Racar & Fabio Faraguna, 2022. "Biodiesel Produced from Propanol and Longer Chain Alcohols—Synthesis and Properties," Energies, MDPI, vol. 15(14), pages 1-21, July.
    15. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2019. "Derivatisation-free characterisation and supercritical conversion of free fatty acids into biodiesel from high acid value waste cooking oil," Renewable Energy, Elsevier, vol. 143(C), pages 77-90.
    16. Milovancevic, Milos & Zandi, Yousef & Rahimi, Abouzar & Denić, Nebojša & Vujović, Vuk & Zlatković, Dragan & Ilic, Ivana D. & Stojanović, Jelena & Gavrilović, Snežana & Khadimallah, Mohamed Amine & Iva, 2022. "Engine performance fueled with jojoba biodiesel and enzymatic saccharification on the yield of glucose of microbial lipids biodiesel," Energy, Elsevier, vol. 239(PD).
    17. Sendzikiene, Egle & Sinkuniene, Dovile & Kazanceva, Irina & Kazancev, Kiril, 2016. "Optimization of low quality rapeseed oil transesterification with butanol by applying the response surface methodology," Renewable Energy, Elsevier, vol. 87(P1), pages 266-272.
    18. Mahmudul, H.M. & Hagos, F.Y. & Mamat, R. & Adam, A. Abdul & Ishak, W.F.W. & Alenezi, R., 2017. "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 497-509.
    19. Fang Yan & Kaili Xu & Deshun Li & Zhikai Cui, 2017. "A novel hazard assessment method for biomass gasification stations based on extended set pair analysis," PLOS ONE, Public Library of Science, vol. 12(9), pages 1-21, September.
    20. Aboelazayem, Omar & Gadalla, Mamdouh & Alhajri, Ibrahim & Saha, Basudeb, 2021. "Advanced process integration for supercritical production of biodiesel: Residual waste heat recovery via organic Rankine cycle (ORC)," Renewable Energy, Elsevier, vol. 164(C), pages 433-443.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:146:y:2020:i:c:p:719-726. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.