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Biodiesel production from waste cooking oil via supercritical methanol: Optimisation and reactor simulation

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  • Aboelazayem, Omar
  • Gadalla, Mamdouh
  • Saha, Basudeb

Abstract

Biodiesel production using supercritical methanol in the absence of catalyst has been analysed by studying the main factors affecting biodiesel yield. A quadratic polynomial model has been developed using Response Surface Methodology (RSM). Box-Behnken Design (BBD) has been used to evaluate the influence of four independent variables i.e. methanol to oil (M:O) molar ratio, temperature, pressure and time on biodiesel yield. The optimum biodiesel yield is 91% at M:O molar ratio, temperature, pressure and reaction time of 37:1, 253.5 °C, 198.5 bar and 14.8 min, respectively. Overall reaction kinetics has been studied at optimum conditions concluding a pseudo first order reaction with reaction rate constant of 0.0006s−1. Moreover, thermodynamics of the reaction has been analysed in the temperature range between 240 and 280 °C concluding frequency factor and activation energy of 4.05s−1 and 50.5 kJ/mol, respectively. A kinetic reactor has been simulated on HYSYS using the obtained kinetic data resulting in 91.7% conversion of triglycerides (TG) with 0.2% relative error from the experimental results.

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  • Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Biodiesel production from waste cooking oil via supercritical methanol: Optimisation and reactor simulation," Renewable Energy, Elsevier, vol. 124(C), pages 144-154.
    • Handle: RePEc:eee:renene:v:124:y:2018:i:c:p:144-154
    DOI: 10.1016/j.renene.2017.06.076
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    1. Jack P. C. Kleijnen, 2015. "Response Surface Methodology," International Series in Operations Research & Management Science, in: Michael C Fu (ed.), Handbook of Simulation Optimization, edition 127, chapter 0, pages 81-104, Springer.
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    1. Zhang, Tianyi & Shahbaz, Kaveh & Farid, Mohammed M., 2020. "Glycerolysis of free fatty acid in vegetable oil deodorizer distillate catalyzed by phosphonium-based deep eutectic solvent," Renewable Energy, Elsevier, vol. 160(C), pages 363-373.
    2. Aboelazayem, Omar & Gadalla, Mamdouh & Alhajri, Ibrahim & Saha, Basudeb, 2021. "Advanced process integration for supercritical production of biodiesel: Residual waste heat recovery via organic Rankine cycle (ORC)," Renewable Energy, Elsevier, vol. 164(C), pages 433-443.
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    5. Zahra Echresh Zadeh & Ali Abdulkhani & Basudeb Saha, 2020. "Characterization of Fast Pyrolysis Bio-Oil from Hardwood and Softwood Lignin," Energies, MDPI, vol. 13(4), pages 1-14, February.
    6. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2019. "Derivatisation-free characterisation and supercritical conversion of free fatty acids into biodiesel from high acid value waste cooking oil," Renewable Energy, Elsevier, vol. 143(C), pages 77-90.
    7. Matea Bačić & Anabela Ljubić & Martin Gojun & Anita Šalić & Ana Jurinjak Tušek & Bruno Zelić, 2021. "Continuous Integrated Process of Biodiesel Production and Purification—The End of the Conventional Two-Stage Batch Process?," Energies, MDPI, vol. 14(2), pages 1-17, January.
    8. Omar Aboelazayem & Mamdouh Gadalla & Basudeb Saha, 2022. "Comprehensive Optimisation of Biodiesel Production Conditions via Supercritical Methanolysis of Waste Cooking Oil," Energies, MDPI, vol. 15(10), pages 1-22, May.
    9. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Design and simulation of an integrated process for biodiesel production from waste cooking oil using supercritical methanolysis," Energy, Elsevier, vol. 161(C), pages 299-307.
    10. Aboelazayem, Omar & El-Gendy, Nour Sh. & Abdel-Rehim, Ahmed A. & Ashour, Fatma & Sadek, Mohamed A., 2018. "Biodiesel production from castor oil in Egypt: Process optimisation, kinetic study, diesel engine performance and exhaust emissions analysis," Energy, Elsevier, vol. 157(C), pages 843-852.
    11. Laskar, Ikbal Bahar & Deshmukhya, Tuhin & Bhanja, Piyali & Paul, Bappi & Gupta, Rajat & Chatterjee, Sushovan, 2020. "Transesterification of soybean oil at room temperature using biowaste as catalyst; an experimental investigation on the effect of co-solvent on biodiesel yield," Renewable Energy, Elsevier, vol. 162(C), pages 98-111.
    12. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Valorisation of high acid value waste cooking oil into biodiesel using supercritical methanolysis: Experimental assessment and statistical optimisation on typical Egyptian feedstock," Energy, Elsevier, vol. 162(C), pages 408-420.
    13. Mohadesi, Majid & Gouran, Ashkan & Dehghan Dehnavi, Amir, 2021. "Biodiesel production using low cost material as high effective catalyst in a microreactor," Energy, Elsevier, vol. 219(C).
    14. Liang, Jin & Yang, Shiliang & Gao, Wengui & Hu, Jianhang & Wang, Hua, 2022. "MP-PIC investigation of glycerol steam reforming in bubbling fluidized bed for high-quality hydrogen production," Renewable Energy, Elsevier, vol. 198(C), pages 319-333.
    15. Umar, Yusuf & Velasco, Orlando & Abdelaziz, Omar Y. & Aboelazayem, Omar & Gadalla, Mamdouh A. & Hulteberg, Christian P. & Saha, Basudeb, 2022. "A renewable lignin-derived bio-oil for boosting the oxidation stability of biodiesel," Renewable Energy, Elsevier, vol. 182(C), pages 867-878.
    16. Simões, S.S. & Ribeiro, J.S. & Celante, D. & Brondani, L.N. & Castilhos, F., 2020. "Heterogeneous catalyst screening for fatty acid methyl esters production through interesterification reaction," Renewable Energy, Elsevier, vol. 146(C), pages 719-726.

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