IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v42y2015icp1437-1452.html
   My bibliography  Save this article

An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines

Author

Listed:
  • Calero, Juan
  • Luna, Diego
  • Sancho, Enrique D.
  • Luna, Carlos
  • Bautista, Felipa M.
  • Romero, Antonio A.
  • Posadillo, Alejandro
  • Berbel, Julio
  • Verdugo-Escamilla, Cristóbal

Abstract

Biodiesel is a biofuel obtained from vegetable oils or animal fats by transesterification with methanol, so that it offers a very promising alternative respect to diesel fuel, since it is able to provide a suitable substitute for the fossil diesel in unmodified internal combustion engines, pure or in blends. However, a major barrier exists to consolidate this conventional biodiesel, as the more suitable biofuel for the replacement of fossil fuel. This drawback is related to the significant amount of glycerol obtained as a byproduct in the transesterification process, which exceeds at least 10% by weight of oil used as raw material. Thus, future widespread use of biofuels depends on developing new process technologies to produce high quality transportation fuels from biologically derived feedstocks, which avoid this key handicap. These new biofuels, like the biodiesel, need to be also compatible with the fossil fuel as well as with existing transportation infrastructures to be economically feasible. In this respect, various alternative methods are currently under development to convert vegetable oils into a high quality diesel fuel, fully compatible with petroleum derived diesel fuel but avoiding the existing glycerol glut. The present review aims to explore the current state of available technologies and recent information in research, production practices and engineering developed to produce alternative high-quality diesel fuel from vegetable oils, by hydrotreating of triglycerides in conventional oil refineries (green diesel) as well as those novel biofuels that integrate glycerol into their composition ( Gliperol®, DMC-Biod® and Ecodiesel®) and the respective technologies for their productions. These very recent biofuels obtained from oils and fats, seek to achieve greater atom efficiency (ideally 100%) because nor glycerol neither other byproduct is generated, avoiding any purification treatment, so that the overall production process of the biofuel is in large extension simplified.

Suggested Citation

  • Calero, Juan & Luna, Diego & Sancho, Enrique D. & Luna, Carlos & Bautista, Felipa M. & Romero, Antonio A. & Posadillo, Alejandro & Berbel, Julio & Verdugo-Escamilla, Cristóbal, 2015. "An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1437-1452.
    • Handle: RePEc:eee:rensus:v:42:y:2015:i:c:p:1437-1452
    DOI: 10.1016/j.rser.2014.11.007
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032114009381
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2014.11.007?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    2. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2010. "High quality biodiesel and its diesel engine application: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(7), pages 1999-2008, September.
    3. Haseeb, A.S.M.A. & Sia, S.Y. & Fazal, M.A. & Masjuki, H.H., 2010. "Effect of temperature on tribological properties of palm biodiesel," Energy, Elsevier, vol. 35(3), pages 1460-1464.
    4. Carlos Luna & Enrique Sancho & Diego Luna & Verónica Caballero & Juan Calero & Alejandro Posadillo & Cristóbal Verdugo & Felipa M. Bautista & Antonio A. Romero, 2013. "Biofuel that Keeps Glycerol as Monoglyceride by 1,3-Selective Ethanolysis with Pig Pancreatic Lipase Covalently Immobilized on AlPO 4 Support," Energies, MDPI, vol. 6(8), pages 1-22, July.
    5. Demirbas, Ayhan, 2009. "Political, economic and environmental impacts of biofuels: A review," Applied Energy, Elsevier, vol. 86(Supplemen), pages 108-117, November.
    6. Oh, Pin Pin & Lau, Harrison Lik Nang & Chen, Junghui & Chong, Mei Fong & Choo, Yuen May, 2012. "A review on conventional technologies and emerging process intensification (PI) methods for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5131-5145.
    7. Tan, Kok Tat & Lee, Keat Teong, 2011. "A review on supercritical fluids (SCF) technology in sustainable biodiesel production: Potential and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2452-2456, June.
    8. Xu, Yufu & Wang, Qiongjie & Hu, Xianguo & Li, Chuan & Zhu, Xifeng, 2010. "Characterization of the lubricity of bio-oil/diesel fuel blends by high frequency reciprocating test rig," Energy, Elsevier, vol. 35(1), pages 283-287.
    9. Leoneti, Alexandre Bevilacqua & Aragão-Leoneti, Valquiria & de Oliveira, Sonia Valle Walter Borges, 2012. "Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol," Renewable Energy, Elsevier, vol. 45(C), pages 138-145.
    10. Rahmat, Norhasyimi & Abdullah, Ahmad Zuhairi & Mohamed, Abdul Rahman, 2010. "Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(3), pages 987-1000, April.
    11. Naik, S.N. & Goud, Vaibhav V. & Rout, Prasant K. & Dalai, Ajay K., 2010. "Production of first and second generation biofuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 578-597, February.
    12. Niza, Noorzalila Muhammad & Tan, Kok Tat & Lee, Keat Teong & Ahmad, Zainal, 2013. "Biodiesel production by non-catalytic supercritical methyl acetate: Thermal stability study," Applied Energy, Elsevier, vol. 101(C), pages 198-202.
    13. Khan, Shakeel A. & Rashmi & Hussain, Mir Z. & Prasad, S. & Banerjee, U.C., 2009. "Prospects of biodiesel production from microalgae in India," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2361-2372, December.
    14. Bhale, Purnanand Vishwanathrao & Deshpande, Nishikant V. & Thombre, Shashikant B., 2009. "Improving the low temperature properties of biodiesel fuel," Renewable Energy, Elsevier, vol. 34(3), pages 794-800.
    15. Bezergianni, Stella & Dimitriadis, Athanasios, 2013. "Comparison between different types of renewable diesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 110-116.
    16. Jayed, M.H. & Masjuki, H.H. & Kalam, M.A. & Mahlia, T.M.I. & Husnawan, M. & Liaquat, A.M., 2011. "Prospects of dedicated biodiesel engine vehicles in Malaysia and Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 220-235, January.
    17. Chouhan, A.P. Singh & Sarma, A.K., 2011. "Modern heterogeneous catalysts for biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4378-4399.
    18. Atadashi, I.M. & Aroua, M.K. & Abdul Aziz, A.R. & Sulaiman, N.M.N., 2012. "The effects of water on biodiesel production and refining technologies: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3456-3470.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. De-Chang Li & Zhengyi Pan & Zhengbin Tian & Qian Zhang & Xiaohui Deng & Heqing Jiang & Guang-Hui Wang, 2024. "Frustrated Lewis pair catalyst realizes efficient green diesel production," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Szabados, György & Bereczky, Ákos, 2018. "Experimental investigation of physicochemical properties of diesel, biodiesel and TBK-biodiesel fuels and combustion and emission analysis in CI internal combustion engine," Renewable Energy, Elsevier, vol. 121(C), pages 568-578.
    3. Okoye, P.U. & Hameed, B.H., 2016. "Review on recent progress in catalytic carboxylation and acetylation of glycerol as a byproduct of biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 558-574.
    4. Abraham Casas & Ángel Pérez & María Jesús Ramos, 2023. "Effects of Diacetinmonoglycerides and Triacetin on Biodiesel Quality," Energies, MDPI, vol. 16(17), pages 1-16, August.
    5. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    6. Monteiro, Rodolpho R.C. & Arana-Peña, Sara & da Rocha, Thays N. & Miranda, Letícia P. & Berenguer-Murcia, Ángel & Tardioli, Paulo W. & dos Santos, José C.S. & Fernandez-Lafuente, Roberto, 2021. "Liquid lipase preparations designed for industrial production of biodiesel. Is it really an optimal solution?," Renewable Energy, Elsevier, vol. 164(C), pages 1566-1587.
    7. Barbosa, Ian V. & Scapim, Letícia A. & Cavalcante, Raquel M. & Young, André F., 2023. "Industrial production of green diesel in Brazil: Process simulation and economic perspectives," Renewable Energy, Elsevier, vol. 219(P2).
    8. Okoye, P.U. & Abdullah, A.Z. & Hameed, B.H., 2017. "A review on recent developments and progress in the kinetics and deactivation of catalytic acetylation of glycerol—A byproduct of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 387-401.
    9. Ahmad, Farah B. & Zhang, Zhanying & Doherty, William O.S. & O'Hara, Ian M., 2019. "The outlook of the production of advanced fuels and chemicals from integrated oil palm biomass biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 109(C), pages 386-411.
    10. Nor, Nurazira Mohd & Salih, Nadia & Salimon, Jumat, 2022. "Optimization and lubrication properties of Malaysian crude palm oil fatty acids based neopentyl glycol diester green biolubricant," Renewable Energy, Elsevier, vol. 200(C), pages 942-956.
    11. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    12. Keon Hee Kim & Eun Yeol Lee, 2017. "Environmentally-Benign Dimethyl Carbonate-Mediated Production of Chemicals and Biofuels from Renewable Bio-Oil," Energies, MDPI, vol. 10(11), pages 1-15, November.
    13. Laura Aguado-Deblas & Jesús Hidalgo-Carrillo & Felipa M. Bautista & Diego Luna & Carlos Luna & Juan Calero & Alejandro Posadillo & Antonio A. Romero & Rafael Estevez, 2020. "Diethyl Ether as an Oxygenated Additive for Fossil Diesel/Vegetable Oil Blends: Evaluation of Performance and Emission Quality of Triple Blends on a Diesel Engine," Energies, MDPI, vol. 13(7), pages 1-16, March.
    14. Ameen, Mariam & Azizan, Mohammad Tazli & Yusup, Suzana & Ramli, Anita & Yasir, Madiha, 2017. "Catalytic hydrodeoxygenation of triglycerides: An approach to clean diesel fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1072-1088.
    15. Rafael Estevez & Laura Aguado-Deblas & Alejandro Posadillo & Beatriz Hurtado & Felipa M. Bautista & José M. Hidalgo & Carlos Luna & Juan Calero & Antonio A. Romero & Diego Luna, 2019. "Performance and Emission Quality Assessment in a Diesel Engine of Straight Castor and Sunflower Vegetable Oils, in Diesel/Gasoline/Oil Triple Blends," Energies, MDPI, vol. 12(11), pages 1-13, June.
    16. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    17. Sedghi, Reza & Shahbeik, Hossein & Rastegari, Hajar & Rafiee, Shahin & Peng, Wanxi & Nizami, Abdul-Sattar & Gupta, Vijai Kumar & Chen, Wei-Hsin & Lam, Su Shiung & Pan, Junting & Tabatabaei, Meisam & A, 2022. "Turning biodiesel glycerol into oxygenated fuel additives and their effects on the behavior of internal combustion engines: A comprehensive systematic review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    18. Julio Berbel & Alejandro Posadillo, 2018. "Review and Analysis of Alternatives for the Valorisation of Agro-Industrial Olive Oil By-Products," Sustainability, MDPI, vol. 10(1), pages 1-9, January.
    19. Juan Calero & Diego Luna & Carlos Luna & Felipa M. Bautista & Beatriz Hurtado & Antonio A. Romero & Alejandro Posadillo & Rafael Estevez, 2019. "Rhizomucor miehei Lipase Supported on Inorganic Solids, as Biocatalyst for the Synthesis of Biofuels: Improving the Experimental Conditions by Response Surface Methodology," Energies, MDPI, vol. 12(5), pages 1-15, March.
    20. Rafael Estevez & Laura Aguado-Deblas & Francisco J. López-Tenllado & Carlos Luna & Juan Calero & Antonio A. Romero & Felipa M. Bautista & Diego Luna, 2022. "Biodiesel Is Dead: Long Life to Advanced Biofuels—A Comprehensive Critical Review," Energies, MDPI, vol. 15(9), pages 1-39, April.
    21. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    22. Simões, S.S. & Ribeiro, J.S. & Celante, D. & Brondani, L.N. & Castilhos, F., 2020. "Heterogeneous catalyst screening for fatty acid methyl esters production through interesterification reaction," Renewable Energy, Elsevier, vol. 146(C), pages 719-726.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jakeria, M.R. & Fazal, M.A. & Haseeb, A.S.M.A., 2014. "Influence of different factors on the stability of biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 154-163.
    2. Carlos Luna & Enrique Sancho & Diego Luna & Verónica Caballero & Juan Calero & Alejandro Posadillo & Cristóbal Verdugo & Felipa M. Bautista & Antonio A. Romero, 2013. "Biofuel that Keeps Glycerol as Monoglyceride by 1,3-Selective Ethanolysis with Pig Pancreatic Lipase Covalently Immobilized on AlPO 4 Support," Energies, MDPI, vol. 6(8), pages 1-22, July.
    3. Chakraborty, Rajat & Gupta, Abhishek.K. & Chowdhury, Ratul, 2014. "Conversion of slaughterhouse and poultry farm animal fats and wastes to biodiesel: Parametric sensitivity and fuel quality assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 120-134.
    4. Nitièma-Yefanova, Svitlana & Coniglio, Lucie & Schneider, Raphaël & Nébié, Roger H.C. & Bonzi-Coulibaly, Yvonne L., 2016. "Ethyl biodiesel production from non-edible oils of Balanites aegyptiaca, Azadirachta indica, and Jatropha curcas seeds – Laboratory scale development," Renewable Energy, Elsevier, vol. 96(PA), pages 881-890.
    5. Joshi, Girdhar & Pandey, Jitendra K. & Rana, Sravendra & Rawat, Devendra S., 2017. "Challenges and opportunities for the application of biofuel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 850-866.
    6. Carlos Luna & Cristobal Verdugo & Enrique D. Sancho & Diego Luna & Juan Calero & Alejandro Posadillo & Felipa M. Bautista & Antonio A. Romero, 2014. "A Biofuel Similar to Biodiesel Obtained by Using a Lipase from Rhizopus oryzae , Optimized by Response Surface Methodology," Energies, MDPI, vol. 7(5), pages 1-17, May.
    7. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    8. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Roberts, W.L. & Dibble, R.W., 2015. "Feasibility of using less viscous and lower cetane (LVLC) fuels in a diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1166-1190.
    9. Mofijur, M. & Atabani, A.E. & Masjuki, H.H. & Kalam, M.A. & Masum, B.M., 2013. "A study on the effects of promising edible and non-edible biodiesel feedstocks on engine performance and emissions production: A comparative evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 391-404.
    10. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Mofijur, M. & Bhuiya, M.M.K., 2016. "Prospects, feedstocks and challenges of biodiesel production from beauty leaf oil and castor oil: A nonedible oil sources in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 302-318.
    11. E, Jiaqiang & Pham, Minhhieu & Zhao, D. & Deng, Yuanwang & Le, DucHieu & Zuo, Wei & Zhu, Hao & Liu, Teng & Peng, Qingguo & Zhang, Zhiqing, 2017. "Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 620-647.
    12. Galadima, Ahmad & Muraza, Oki, 2014. "Biodiesel production from algae by using heterogeneous catalysts: A critical review," Energy, Elsevier, vol. 78(C), pages 72-83.
    13. Sanjid, A. & Masjuki, H.H. & Kalam, M.A. & Rahman, S.M. Ashrafur & Abedin, M.J. & Palash, S.M., 2013. "Impact of palm, mustard, waste cooking oil and Calophyllum inophyllum biofuels on performance and emission of CI engine," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 664-682.
    14. Fazal, M.A. & Haseeb, A.S.M.A. & Masjuki, H.H., 2011. "Biodiesel feasibility study: An evaluation of material compatibility; performance; emission and engine durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(2), pages 1314-1324, February.
    15. Habibullah, M. & Masjuki, H.H. & Kalam, M.A. & Rahman, S.M. Ashrafur & Mofijur, M. & Mobarak, H.M. & Ashraful, A.M., 2015. "Potential of biodiesel as a renewable energy source in Bangladesh," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 819-834.
    16. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.
    17. Maru, Marcia M. & Trommer, Rafael M. & Cavalcanti, Kátia F. & Figueiredo, Elizabeth S. & Silva, Rui F. & Achete, Carlos A., 2014. "The Stribeck curve as a suitable characterization method of the lubricity of biodiesel and diesel blends," Energy, Elsevier, vol. 69(C), pages 673-681.
    18. Silitonga, A.S. & Masjuki, H.H. & Mahlia, T.M.I. & Ong, H.C. & Chong, W.T. & Boosroh, M.H., 2013. "Overview properties of biodiesel diesel blends from edible and non-edible feedstock," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 346-360.
    19. Guimarães, José Renato & Fernandez-Lafuente, Roberto & Tardioli, Paulo Waldir, 2022. "Ethanolysis of soybean oil catalyzed by magnetic CLEA of porcine pancreas lipase to produce ecodiesel. Efficient separation of ethyl esters and monoglycerides," Renewable Energy, Elsevier, vol. 198(C), pages 455-462.
    20. Nongbe, Medy C. & Ekou, Tchirioua & Ekou, Lynda & Yao, Kouassi Benjamin & Le Grognec, Erwan & Felpin, François-Xavier, 2017. "Biodiesel production from palm oil using sulfonated graphene catalyst," Renewable Energy, Elsevier, vol. 106(C), pages 135-141.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:42:y:2015:i:c:p:1437-1452. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.