IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v123y2014icp108-120.html
   My bibliography  Save this article

Transesterification of canola, palm, peanut, soybean and sunflower oil with methanol, ethanol, isopropanol, butanol and tert-butanol to biodiesel: Modelling of chemical equilibrium, reaction kinetics and mass transfer based on fatty acid composition

Author

Listed:
  • Likozar, Blaž
  • Levec, Janez

Abstract

Mechanism of alcoholysis (e.g. methanolysis) using different oils, alcohols and homogeneous base catalysts was utilized to devise chemical kinetics and thermodynamics based on fatty acid composition, differentiating among triglycerides, diglycerides, monoglycerides and fatty acid alkyl esters (e.g. fatty acid alkyl esters, FAME) with bonded gadoleic, linoleic, linolenic, oleic, palmitic and stearic acid-originating substituents. Their concentrations were measured using an optimized high-performance liquid chromatography (HPLC) method. Hydrodynamics and diffusion limitations in emulsion were considered in overall model by determining diffusivities, distribution coefficients, molar volumes, boiling points and viscosities of individual components. Pre-exponential factors and activation energies were related with structure of reactants, intermediates and products acknowledging number of carbons, double bonds and alkyl branches by linear and mixed response surface methodology. Developed model may be used with batch and continuous flow reactors, e.g. for novel micro-structured or industrial-scale process intensification, different vegetable or non-edible oils (waste cooking Jatropha or microalgae lipids).

Suggested Citation

  • Likozar, Blaž & Levec, Janez, 2014. "Transesterification of canola, palm, peanut, soybean and sunflower oil with methanol, ethanol, isopropanol, butanol and tert-butanol to biodiesel: Modelling of chemical equilibrium, reaction kinetics ," Applied Energy, Elsevier, vol. 123(C), pages 108-120.
    • Handle: RePEc:eee:appene:v:123:y:2014:i:c:p:108-120
    DOI: 10.1016/j.apenergy.2014.02.046
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261914001901
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2014.02.046?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Dawodu, Folasegun A. & Ayodele, Olubunmi & Xin, Jiayu & Zhang, Suojiang & Yan, Dongxia, 2014. "Effective conversion of non-edible oil with high free fatty acid into biodiesel by sulphonated carbon catalyst," Applied Energy, Elsevier, vol. 114(C), pages 819-826.
    2. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2013. "Ultrasound-assisted transesterification of crude Jatropha oil using alumina-supported heteropolyacid catalyst," Applied Energy, Elsevier, vol. 105(C), pages 380-388.
    3. Santori, Giulio & Di Nicola, Giovanni & Moglie, Matteo & Polonara, Fabio, 2012. "A review analyzing the industrial biodiesel production practice starting from vegetable oil refining," Applied Energy, Elsevier, vol. 92(C), pages 109-132.
    4. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Zarei, Alireza & Noshadi, Iman, 2013. "Transesterification of waste cooking oil by heteropoly acid (HPA) catalyst: Optimization and kinetic model," Applied Energy, Elsevier, vol. 102(C), pages 283-292.
    5. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    6. Yin, Xiulian & Ma, Haile & You, Qinghong & Wang, Zhenbin & Chang, Jinke, 2012. "Comparison of four different enhancing methods for preparing biodiesel through transesterification of sunflower oil," Applied Energy, Elsevier, vol. 91(1), pages 320-325.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.
    2. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    3. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2013. "Ultrasound-assisted transesterification of crude Jatropha oil using alumina-supported heteropolyacid catalyst," Applied Energy, Elsevier, vol. 105(C), pages 380-388.
    4. Navarro-Pineda, Freddy S. & Baz-Rodríguez, Sergio A. & Handler, Robert & Sacramento-Rivero, Julio C., 2016. "Advances on the processing of Jatropha curcas towards a whole-crop biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 247-269.
    5. Tan, Yie Hua & Abdullah, Mohammad Omar & Nolasco-Hipolito, Cirilo & Taufiq-Yap, Yun Hin, 2015. "Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: Catalyst characterization and biodiesel yield performance," Applied Energy, Elsevier, vol. 160(C), pages 58-70.
    6. Gude, Veera Gnaneswar & Grant, Georgene Elizabeth, 2013. "Biodiesel from waste cooking oils via direct sonication," Applied Energy, Elsevier, vol. 109(C), pages 135-144.
    7. Su, Chia-Hung, 2013. "Recoverable and reusable hydrochloric acid used as a homogeneous catalyst for biodiesel production," Applied Energy, Elsevier, vol. 104(C), pages 503-509.
    8. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    9. Lian, Shuang & Li, Huijuan & Tang, Jinqiang & Tong, Dongmei & Hu, Changwei, 2012. "Integration of extraction and transesterification of lipid from jatropha seeds for the production of biodiesel," Applied Energy, Elsevier, vol. 98(C), pages 540-547.
    10. Blanco-Marigorta, A.M. & Suárez-Medina, J. & Vera-Castellano, A., 2013. "Exergetic analysis of a biodiesel production process from Jatropha curcas," Applied Energy, Elsevier, vol. 101(C), pages 218-225.
    11. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    12. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    13. Badday, Ali Sabri & Abdullah, Ahmad Zuhairi & Lee, Keat-Teong, 2014. "Transesterification of crude Jatropha oil by activated carbon-supported heteropolyacid catalyst in an ultrasound-assisted reactor system," Renewable Energy, Elsevier, vol. 62(C), pages 10-17.
    14. Liu, Chien-Hung & Huang, Chien-Chang & Wang, Yao-Wen & Lee, Duu-Jong & Chang, Jo-Shu, 2012. "Biodiesel production by enzymatic transesterification catalyzed by Burkholderia lipase immobilized on hydrophobic magnetic particles," Applied Energy, Elsevier, vol. 100(C), pages 41-46.
    15. Borugadda, Venu Babu & Goud, Vaibhav V., 2012. "Biodiesel production from renewable feedstocks: Status and opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 4763-4784.
    16. Mat Yasin, Mohd Hafizil & Mamat, Rizalman & Najafi, G. & Ali, Obed Majeed & Yusop, Ahmad Fitri & Ali, Mohd Hafiz, 2017. "Potentials of palm oil as new feedstock oil for a global alternative fuel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1034-1049.
    17. Guan, Qingqing & Shang, Hua & Liu, Jing & Gu, Junjie & Li, Bin & Miao, Rongrong & Chen, Qiuling & Ning, Ping, 2016. "Biodiesel from transesterification at low temperature by AlCl3 catalysis in ethanol and carbon dioxide as cosolvent: Process, mechanism and application," Applied Energy, Elsevier, vol. 164(C), pages 380-386.
    18. Abdullah, Sharifah Hanis Yasmin Sayid & Hanapi, Nur Hanis Mohamad & Azid, Azman & Umar, Roslan & Juahir, Hafizan & Khatoon, Helena & Endut, Azizah, 2017. "A review of biomass-derived heterogeneous catalyst for a sustainable biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 70(C), pages 1040-1051.
    19. Zhang, Yue & Wong, Wing-Tak & Yung, Ka-Fu, 2014. "Biodiesel production via esterification of oleic acid catalyzed by chlorosulfonic acid modified zirconia," Applied Energy, Elsevier, vol. 116(C), pages 191-198.
    20. Kwon, Eilhann E. & Jeon, Eui-Chan & Yi, Haakrho & Kim, Sungpyo, 2014. "Transforming duck tallow into biodiesel via noncatalytic transesterification," Applied Energy, Elsevier, vol. 116(C), pages 20-25.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:123:y:2014:i:c:p:108-120. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.