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A comprehensive review of the production methods and effect of parameters for glycerol-free biodiesel production

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  • Wong, Wan-Ying
  • Lim, Steven
  • Pang, Yean-Ling
  • Shuit, Siew-Hoong
  • Lam, Man-Kee
  • Tan, Inn-Shi
  • Chen, Wei-Hsin

Abstract

This review appraises the latest scientific progress and the accomplishments of interesterification technology as an alternative to conventional transesterification reaction. The merits and limitations of various types of catalytic techniques as well as non-catalytic supercritical glycerol-free processes have been elucidated with a comprehensive comparison. Contrary to the cheap price of glycerol, the higher-revenue by-products, triacetin and glycerol carbonate, will boost the gross profit margin of biodiesel production. The influences of reaction parameters such as reactant ratio, catalyst loading, reaction time, temperature, and co-solvent addition are also addressed. According to the latest research, the alkali-catalyzed and non-catalytic supercritical interesterifications are preferable due to higher yield. Methyl acetate, ethyl acetate and dimethyl carbonate do not inhibit lipase activity, unlike typical alcohols. Acidic catalysis may be the way forward to resolve the extreme operating conditions of non-catalytic supercritical interesterification, high cost of enzymes and manage waste feedstocks with high free fatty acid and water contents under moderate conditions. Currently, the majority of interesterification reactions were undertaken on laboratory size, whereas just a handful was evaluated on a pilot scale. A continuous research in interesterification technology is necessary by conducting a thorough investigation of the feasibility of state-of-the-art technology to engage a wide array of feedstocks. Future study should also concentrate on microbes and agricultural waste as a sustainable route for energy recovery from renewable feedstocks.

Suggested Citation

  • Wong, Wan-Ying & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Lam, Man-Kee & Tan, Inn-Shi & Chen, Wei-Hsin, 2023. "A comprehensive review of the production methods and effect of parameters for glycerol-free biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    • Handle: RePEc:eee:rensus:v:182:y:2023:i:c:s136403212300254x
    DOI: 10.1016/j.rser.2023.113397
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    1. Jegannathan, Kenthorai Raman & Eng-Seng, Chan & Ravindra, Pogaku, 2011. "Economic assessment of biodiesel production: Comparison of alkali and biocatalyst processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 745-751, January.
    2. Rahmath Abdulla & Eryati Derman & Thivyasri K.Mathialagan & Abu Zahrim Yaser & Mohd Armi Abu Samah & Jualang Azlan Gansau & Syed Umar Faruq Syed Najmuddin, 2022. "Biodiesel Production from Waste Palm Cooking Oil Using Immobilized Candida rugosa Lipase," Sustainability, MDPI, vol. 14(20), pages 1-18, October.
    3. Brondani, L.N. & Ribeiro, J.S. & Castilhos, F., 2020. "A new kinetic model for simultaneous interesterification and esterification reactions from methyl acetate and highly acidic oil," Renewable Energy, Elsevier, vol. 156(C), pages 579-590.
    4. Li, Dongming & Feng, Wenping & Chen, Chao & Chen, Shangxing & Fan, Guorong & Liao, Shengliang & Wu, Guoqiang & Wang, Zongde, 2021. "Transesterification of Litsea cubeba kernel oil to biodiesel over zinc supported on zirconia heterogeneous catalysts," Renewable Energy, Elsevier, vol. 177(C), pages 13-22.
    5. Tavares, Gilmar Roberto & Massa, Thainara Bovo & Gonçalves, José Eduardo & da Silva, Camila & dos Santos, Wanderley Dantas, 2017. "Assessment of ultrasound-assisted extraction of crambe seed oil for biodiesel synthesis by in situ interesterification," Renewable Energy, Elsevier, vol. 111(C), pages 659-665.
    6. Kampars, Valdis & Abelniece, Zane & Lazdovica, Kristine & Kampare, Ruta, 2020. "Interesterification of rapeseed oil with methyl acetate in the presence of potassium tert-butoxide solution in tetrahydrofuran," Renewable Energy, Elsevier, vol. 158(C), pages 668-674.
    7. Dawodu, Folasegun A. & Ayodele, Olubunmi O. & Xin, Jiayu & Zhang, Suojiang, 2014. "Dimethyl carbonate mediated production of biodiesel at different reaction temperatures," Renewable Energy, Elsevier, vol. 68(C), pages 581-587.
    8. Tomasz Szymczak & Justyna Cybulska & Marcin Podleśny & Magdalena Frąc, 2021. "Various Perspectives on Microbial Lipase Production Using Agri-Food Waste and Renewable Products," Agriculture, MDPI, vol. 11(6), pages 1-22, June.
    9. Go, Alchris Woo & Sutanto, Sylviana & Ong, Lu Ki & Tran-Nguyen, Phuong Lan & Ismadji, Suryadi & Ju, Yi-Hsu, 2016. "Developments in in-situ (trans) esterification for biodiesel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 284-305.
    10. Maghrebi, R. & Buffi, M. & Bondioli, P. & Chiaramonti, D., 2021. "Isomerization of long-chain fatty acids and long-chain hydrocarbons: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    11. Chuepeng, Sathaporn & Komintarachat, Cholada, 2018. "Interesterification optimization of waste cooking oil and ethyl acetate over homogeneous catalyst for biofuel production with engine validation," Applied Energy, Elsevier, vol. 232(C), pages 728-739.
    12. Oyetola Ogunkunle & Noor A. Ahmed, 2021. "Overview of Biodiesel Combustion in Mitigating the Adverse Impacts of Engine Emissions on the Sustainable Human–Environment Scenario," Sustainability, MDPI, vol. 13(10), pages 1-28, May.
    13. Goembira, Fadjar & Saka, Shiro, 2015. "Advanced supercritical Methyl acetate method for biodiesel production from Pongamia pinnata oil," Renewable Energy, Elsevier, vol. 83(C), pages 1245-1249.
    14. Simões, S.S. & Ribeiro, J.S. & Celante, D. & Brondani, L.N. & Castilhos, F., 2020. "Heterogeneous catalyst screening for fatty acid methyl esters production through interesterification reaction," Renewable Energy, Elsevier, vol. 146(C), pages 719-726.
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    3. Kivevele, Thomas & Kichonge, Baraka, 2024. "Techno-economic evaluation of transesterification processes for biodiesel production from low quality non-edible feedstocks: Process design and simulation," Energy, Elsevier, vol. 297(C).

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