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Optimization of low quality rapeseed oil transesterification with butanol by applying the response surface methodology

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  • Sendzikiene, Egle
  • Sinkuniene, Dovile
  • Kazanceva, Irina
  • Kazancev, Kiril

Abstract

This paper discusses the determination of the optimal conditions for enzymatic transesterification of model waste oil (with 4% acid value) with butanol. It was found that biodiesel synthesis by the enzymatic transesterification of waste rapeseed oil rich in free fatty acid with butanol can be very effective if the catalysis is carried out in two steps. Both transesterification steps were catalysed by Lipozyme RM IM. The optimal conditions for the first step were determined: temperature of 39 °C, butanol and oil molar ratio of 4.5, lipase concentration of 6%, and reaction time of 9.8 h, with an expected yield of 60.1%. The removal of glycerol, enzyme renewal and subsequent addition of 7.8% lipase, with a 1.5 butanol and oil molar ratio and 8-h incubation at 39 °C predicted a 96.7% yield and resulted in a 96.6% butyl ester yield.

Suggested Citation

  • Sendzikiene, Egle & Sinkuniene, Dovile & Kazanceva, Irina & Kazancev, Kiril, 2016. "Optimization of low quality rapeseed oil transesterification with butanol by applying the response surface methodology," Renewable Energy, Elsevier, vol. 87(P1), pages 266-272.
    • Handle: RePEc:eee:renene:v:87:y:2016:i:p1:p:266-272
    DOI: 10.1016/j.renene.2015.10.024
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    1. Jack P. C. Kleijnen, 2015. "Response Surface Methodology," International Series in Operations Research & Management Science, in: Michael C Fu (ed.), Handbook of Simulation Optimization, edition 127, chapter 0, pages 81-104, Springer.
    2. Gog, Adriana & Roman, Marius & Toşa, Monica & Paizs, Csaba & Irimie, Florin Dan, 2012. "Biodiesel production using enzymatic transesterification – Current state and perspectives," Renewable Energy, Elsevier, vol. 39(1), pages 10-16.
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    4. Likozar, Blaž & Levec, Janez, 2014. "Transesterification of canola, palm, peanut, soybean and sunflower oil with methanol, ethanol, isopropanol, butanol and tert-butanol to biodiesel: Modelling of chemical equilibrium, reaction kinetics ," Applied Energy, Elsevier, vol. 123(C), pages 108-120.
    5. Wu, Xuan & Leung, Dennis Y.C., 2011. "Optimization of biodiesel production from camelina oil using orthogonal experiment," Applied Energy, Elsevier, vol. 88(11), pages 3615-3624.
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    2. Vávra, Aleš & Hájek, Martin & Kocián, David, 2021. "The influence of vegetable oils composition on separation of transesterification products, especially quality of glycerol," Renewable Energy, Elsevier, vol. 176(C), pages 262-268.
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    4. Mia Gotovuša & Marko Racar & Lucija Konjević & Jelena Parlov Vuković & Fabio Faraguna, 2023. "The Influence of the Reaction Parameters on the Synthesis of Fatty Acid Octyl Esters and Investigation of Applications Properties of Its Blends with Mineral Diesel," Energies, MDPI, vol. 16(7), pages 1-17, March.
    5. Violeta Makareviciene & Egle Sendzikiene & Milda Gumbyte, 2020. "Application of Simultaneous Oil Extraction and Transesterification in Biodiesel Fuel Synthesis: A Review," Energies, MDPI, vol. 13(9), pages 1-16, May.
    6. Violeta Makareviciene & Egle Sendzikiene, 2022. "Application of Microalgae Biomass for Biodiesel Fuel Production," Energies, MDPI, vol. 15(11), pages 1-33, June.
    7. Egle Sendzikiene & Violeta Makareviciene & Migle Santaraite, 2022. "Simultaneous Extraction of Rapeseed Oil and Enzymatic Transesterification with Butanol in the Mineral Diesel Medium," Energies, MDPI, vol. 15(18), pages 1-12, September.

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