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Frustrated Lewis pair catalyst realizes efficient green diesel production

Author

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  • De-Chang Li

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

  • Zhengyi Pan

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

  • Zhengbin Tian

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory)

  • Qian Zhang

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

  • Xiaohui Deng

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory)

  • Heqing Jiang

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

  • Guang-Hui Wang

    (Chinese Academy of Sciences
    Shandong Energy Institute
    Qingdao New Energy Shandong Laboratory
    University of Chinese Academy of Sciences)

Abstract

Hydrotreating renewable oils over sulfided metal catalysts is commercially applied to produce green diesel, but it requires a continuous sulfur replenishment to maintain catalyst activity, which inevitably results in sulfur contamination and increases production costs. We report a robust P-doped NiAl-oxide catalyst with frustrated Lewis pairs (i.e., P atom bonded with the O atom acts as an electron donor, while the spatially separated Ni atom acts as an electron acceptor) that allows efficient green diesel production without sulfur replenishment. The catalyst runs more than 500 h at a weight hourly space velocity (WHSV) of 28.3 h−1 without deactivation (methyl laurate as a model compound), and is able to completely convert a real feedstock of soybean oil to diesel-range hydrocarbons with selectivity >90% during 500 h of operation. This work is expected to open up a new avenue for designing non-sulfur catalysts that can make the green diesel production greener.

Suggested Citation

  • De-Chang Li & Zhengyi Pan & Zhengbin Tian & Qian Zhang & Xiaohui Deng & Heqing Jiang & Guang-Hui Wang, 2024. "Frustrated Lewis pair catalyst realizes efficient green diesel production," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-47591-z
    DOI: 10.1038/s41467-024-47591-z
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    References listed on IDEAS

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    1. Calero, Juan & Luna, Diego & Sancho, Enrique D. & Luna, Carlos & Bautista, Felipa M. & Romero, Antonio A. & Posadillo, Alejandro & Berbel, Julio & Verdugo-Escamilla, Cristóbal, 2015. "An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1437-1452.
    2. Giuseppe Di Vito Nolfi & Katia Gallucci & Leucio Rossi, 2021. "Green Diesel Production by Catalytic Hydrodeoxygenation of Vegetables Oils," IJERPH, MDPI, vol. 18(24), pages 1-28, December.
    3. Sai Zhang & Zheng-Qing Huang & Yuanyuan Ma & Wei Gao & Jing Li & Fangxian Cao & Lin Li & Chun-Ran Chang & Yongquan Qu, 2017. "Solid frustrated-Lewis-pair catalysts constructed by regulations on surface defects of porous nanorods of CeO2," Nature Communications, Nature, vol. 8(1), pages 1-11, August.
    4. Chen, Shuang & Zhou, Guilin & Miao, Caixia, 2019. "Green and renewable bio-diesel produce from oil hydrodeoxygenation: Strategies for catalyst development and mechanism," Renewable and Sustainable Energy Reviews, Elsevier, vol. 101(C), pages 568-589.
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