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Experiment assessment of hydrogen production from activated aluminum alloys in portable generator for fuel cell applications

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  • Fan, Mei–qiang
  • Sun, Li–xian
  • Xu, Fen

Abstract

An experiment assessment of hydrogen production from activated aluminum alloy in portable hydrogen generator for fuel cell applications was investigated. The optimum hydrogen capacity of the high–reactive Al–Bi–NaCl alloys (the abbreviation of milled material of aluminum, bismuth and NaCl particles) is about 9–9.4 wt.%, meeting the targets (9 wt.%) of the US Department of Energy in 2015. Hydrogen production rate can be controlled via controlling the water flow rate in the generator, being 1.369–6.198 L hydrogen/min while the water flow rate ranges in 5–20 mL/min. The larger water flow rate often leads to higher temperature and results in unsafety in the generator as the hydrolysis reaction of aluminum alloy and water releases 15 kJ/g heat. However, the heat problem can be successfully eliminated by using effective cooling stytles, which enable the maximum temperature of Al–H2O mixture (the abbreviation of hydrolysis products of aluminum alloy in water) controlled less than 474 K even though the water flow rate is 20 mL/min. Therefore, the experiment results show that the portable hydrogen generator from aluminum alloy could supply the CO2–free, high hydrogen capacity and safe hydrogen for fuel cell applications.

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  • Fan, Mei–qiang & Sun, Li–xian & Xu, Fen, 2010. "Experiment assessment of hydrogen production from activated aluminum alloys in portable generator for fuel cell applications," Energy, Elsevier, vol. 35(7), pages 2922-2926.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:7:p:2922-2926
    DOI: 10.1016/j.energy.2010.03.023
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    4. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Effect of salts addition on the hydrogen generation of Al–LiH composite elaborated by ball milling," Energy, Elsevier, vol. 89(C), pages 907-913.
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    6. Liu, Yongan & Wang, Xinhua & Dong, Zhaohui & Liu, Haizhen & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2013. "Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3," Energy, Elsevier, vol. 53(C), pages 147-152.
    7. Jamey Davies & Stephanus P. Du Preez & Dmitri G. Bessarabov, 2022. "The Hydrolysis of Ball-Milled Aluminum–Bismuth–Nickel Composites for On-Demand Hydrogen Generation," Energies, MDPI, vol. 15(7), pages 1-22, March.
    8. Wang, Shuofeng & Ji, Changwei & Zhang, Jian & Zhang, Bo, 2011. "Comparison of the performance of a spark-ignited gasoline engine blended with hydrogen and hydrogen–oxygen mixtures," Energy, Elsevier, vol. 36(10), pages 5832-5837.
    9. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Cao, Guozhou & Yan, Mi, 2014. "Hydrogen generation from Mg–LiBH4 hydrolysis improved by AlCl3 addition," Energy, Elsevier, vol. 68(C), pages 548-554.
    10. Zhao, Zhongwei & Chen, Xingyu & Hao, Mingming, 2011. "Hydrogen generation by splitting water with Al–Ca alloy," Energy, Elsevier, vol. 36(5), pages 2782-2787.
    11. Xiao, Fei & Yang, Rongjie & Li, Jianmin, 2019. "Hydrogen generation from hydrolysis of activated aluminum/organic fluoride/bismuth composites with high hydrogen generation rate and good aging resistance in air," Energy, Elsevier, vol. 170(C), pages 159-169.
    12. Yang, Weijuan & Zhang, Tianyou & Liu, Jianzhong & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature," Energy, Elsevier, vol. 93(P1), pages 451-457.
    13. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2014. "Improved hydrogen generation from the hydrolysis of aluminum ball milled with hydride," Energy, Elsevier, vol. 72(C), pages 421-426.
    14. Shkolnikov, E.I. & Zhuk, A.Z. & Vlaskin, M.S., 2011. "Aluminum as energy carrier: Feasibility analysis and current technologies overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4611-4623.
    15. Xiao, Fei & Guo, Yanpei & Li, Jianmin & Yang, Rongjie, 2018. "Hydrogen generation from hydrolysis of activated aluminum composites in tap water," Energy, Elsevier, vol. 157(C), pages 608-614.
    16. Ma, Miaolian & Yang, Lingli & Ouyang, Liuzhang & Shao, Huaiyu & Zhu, Min, 2019. "Promoting hydrogen generation from the hydrolysis of Mg-Graphite composites by plasma-assisted milling," Energy, Elsevier, vol. 167(C), pages 1205-1211.
    17. Zhuk, A.Z. & Shkolnikov, E.I. & Borodina, T.I. & Valiano, G.E. & Dolzhenko, A.V. & Kiseleva, E.A. & Kochanova, S.A. & Filippov, E.D. & Semenova, V.A., 2023. "Aluminium – Water hydrogen generator for domestic and mobile application," Applied Energy, Elsevier, vol. 334(C).
    18. Yang, Weijuan & Zhang, Tianyou & Zhou, Junhu & Shi, Wei & Liu, Jianzhong & Cen, Kefa, 2015. "Experimental study on the effect of low melting point metal additives on hydrogen production in the aluminum–water reaction," Energy, Elsevier, vol. 88(C), pages 537-543.
    19. Öz, Çisem & Coşkuner Filiz, Bilge & Kantürk Figen, Aysel, 2017. "The effect of vinegar–acetic acid solution on the hydrogen generation performance of mechanochemically modified Magnesium (Mg) granules," Energy, Elsevier, vol. 127(C), pages 328-334.
    20. Macanás, Jorge & Soler, Lluís & Candela, Angélica María & Muñoz, Maria & Casado, Juan, 2011. "Hydrogen generation by aluminum corrosion in aqueous alkaline solutions of inorganic promoters: The AlHidrox process," Energy, Elsevier, vol. 36(5), pages 2493-2501.
    21. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Investigation on the improved hydrolysis of aluminum–calcium hydride-salt mixture elaborated by ball milling," Energy, Elsevier, vol. 84(C), pages 714-721.

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