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Hydrogen generation as a clean energy through hydrolysis of sodium borohydride over Cu-Fe-B nano powders: Effect of polymers and surfactants

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  • Loghmani, Mohammad Hassan
  • Shojaei, Abdollah Fallah
  • Khakzad, Morteza

Abstract

The aim of this study is to prepare Cu-Fe-B catalysts with different Cu:Fe molar ratios under ultrasonic conditions. The catalytic activity of all catalysts is tested for hydrogen generation through hydrolysis of alkaline sodium borohydride solution. The effect of polymers (PEG and PVP) and surfactants (CTAB, SDS and Triton X-100) as stabilizer agents on size, morphology and catalytic activity was studied. XRD, TEM, FE-SEM, ICP-OES and BET techniques have been employed for the characterization of catalysts. The TEM image depicts that PEG-stabilized Cu:Fe (3:1) catalyst is a flaky shaped particle containing many nanosheets. The various morphologies of Cu-Fe-B nano catalysts were also confirmed by FE-SEM images. It can be found that PEG and PVP resulted in puffy and nanoparticle shapes, respectively. FE-SEM images of surfactants stabilized Cu-Fe-B powders, CTAB, SDS and Triton X-100, show platy form and agglomerated particles. The PEG-stabilized Cu-Fe-B catalyst with a Cu: Fe molar ratio of 3:1 shows the best catalytic activity at 318 K. In addition, the effects of the concentration of NaBH4, NaOH and the reaction temperature on catalytic activity of Cu-Fe-B have been studied for the hydrogen generation rate. The results of the kinetic study show that the catalytic hydrolysis of NaBH4 is first order with respect to the catalyst dosage and is also first order with respect to the NaBH4 concentration. The activation energy of the hydrolysis for PEG-stabilized Cu-Fe (3:1) catalysts is calculated as 57 kJ mol−1. The results of reusability tests show that PEG-stabilized Cu-Fe (3:1) catalyst is active even up to the third run.

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  • Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah & Khakzad, Morteza, 2017. "Hydrogen generation as a clean energy through hydrolysis of sodium borohydride over Cu-Fe-B nano powders: Effect of polymers and surfactants," Energy, Elsevier, vol. 126(C), pages 830-840.
    • Handle: RePEc:eee:energy:v:126:y:2017:i:c:p:830-840
    DOI: 10.1016/j.energy.2017.03.006
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    References listed on IDEAS

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    1. Ozbilen, Ahmet & Dincer, Ibrahim & Rosen, Marc A., 2014. "Development of new heat exchanger network designs for a four-step Cu–Cl cycle for hydrogen production," Energy, Elsevier, vol. 77(C), pages 338-351.
    2. Chen, Wei-Hsin & Shen, Chun-Ting & Lin, Bo-Jhih & Liu, Shih-Chun, 2015. "Hydrogen production from methanol partial oxidation over Pt/Al2O3 catalyst with low Pt content," Energy, Elsevier, vol. 88(C), pages 399-407.
    3. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.
    4. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah, 2014. "Hydrogen production through hydrolysis of sodium borohydride: Oleic acid stabilized Co–La–Zr–B nanoparticle as a novel catalyst," Energy, Elsevier, vol. 68(C), pages 152-159.
    5. Yu, Linping & Lei, Ting & Nan, Bo & Jiang, Yao & He, Yuehui & Liu, C.T., 2016. "Characteristics of a sintered porous Ni–Cu alloy cathode for hydrogen production in a potassium hydroxide solution," Energy, Elsevier, vol. 97(C), pages 498-505.
    6. Sahiner, Nurettin & Turhan, Tugce & Lyon, L. Andrew, 2014. "ILC (ionic liquid colloids) based on p(4-VP) (poly(4-vinyl pyridine)) microgels: Synthesis, characterization and use in hydrogen production," Energy, Elsevier, vol. 66(C), pages 256-263.
    7. Tamboli, Ashif H. & Chaugule, Avinash A. & Sheikh, Faheem A. & Chung, Wook-Jin & Kim, Hern, 2015. "Synthesis and application of CeO2–NiO loaded TiO2 nanofiber as novel catalyst for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 89(C), pages 568-575.
    8. Cai, Haokun & Liu, Liping & Chen, Qiang & Lu, Ping & Dong, Jian, 2016. "Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride," Energy, Elsevier, vol. 99(C), pages 129-135.
    9. Gokon, Nobuyuki & Hasegawa, Tomoki & Takahashi, Shingo & Kodama, Tatsuya, 2008. "Thermochemical two-step water-splitting for hydrogen production using Fe-YSZ particles and a ceramic foam device," Energy, Elsevier, vol. 33(9), pages 1407-1416.
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