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Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3

Author

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  • Liu, Yongan
  • Wang, Xinhua
  • Dong, Zhaohui
  • Liu, Haizhen
  • Li, Shouquan
  • Ge, Hongwei
  • Yan, Mi

Abstract

A simple method of improving hydrogen generation from the reaction between highly activated Mg powder and water is established. The Mg–H2O reaction is found to become faster and more intense when magnesium is mixed with salts and subjected to by high-energy ball milling. Among the studied salts, AlCl3 has the best performance. The milling time and salt content significantly affect the final hydrogen yield and reaction kinetics. Among all studied samples, 6 h-milled Mg–3 mol% AlCl3 shows the best performance with a hydrogen yield of 93.86% and IHGR (initial hydrogen generation rate) of 455.9 ml min−1·(g Mg)−1 within 1 h. The initial temperature is also found to have a remarkable influence on the hydrolysis of the Mg–AlCl3 mixture, and the reaction can proceed to 100% conversion in 1 min with an IHGR of 933.3 ml min−1·(g Mg)−1 at 80 °C.

Suggested Citation

  • Liu, Yongan & Wang, Xinhua & Dong, Zhaohui & Liu, Haizhen & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2013. "Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3," Energy, Elsevier, vol. 53(C), pages 147-152.
    • Handle: RePEc:eee:energy:v:53:y:2013:i:c:p:147-152
    DOI: 10.1016/j.energy.2013.01.073
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    References listed on IDEAS

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    1. Kim, Taegyu, 2014. "NaBH4 (sodium borohydride) hydrogen generator with a volume-exchange fuel tank for small unmanned aerial vehicles powered by a PEM (proton exchange membrane) fuel cell," Energy, Elsevier, vol. 69(C), pages 721-727.
    2. Sun, Qian & Zou, Meishuai & Guo, Xiaoyan & Yang, Rongjie & Huang, Haitao & Huang, Peng & He, Xiangdong, 2015. "A study of hydrogen generation by reaction of an activated Mg–CoCl2 (magnesium–cobalt chloride) composite with pure water for portable applications," Energy, Elsevier, vol. 79(C), pages 310-314.
    3. Chou, Chang-Chen & Hsieh, Ching-Hsuan & Chen, Bing-Hung, 2015. "Hydrogen generation from catalytic hydrolysis of sodium borohydride using bimetallic Ni–Co nanoparticles on reduced graphene oxide as catalysts," Energy, Elsevier, vol. 90(P2), pages 1973-1982.
    4. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Effect of salts addition on the hydrogen generation of Al–LiH composite elaborated by ball milling," Energy, Elsevier, vol. 89(C), pages 907-913.
    5. Olesya A. Buryakovskaya & Anna I. Kurbatova & Mikhail S. Vlaskin & George E. Valyano & Anatoly V. Grigorenko & Grayr N. Ambaryan & Aleksandr O. Dudoladov, 2022. "Waste to Hydrogen: Elaboration of Hydroreactive Materials from Magnesium-Aluminum Scrap," Sustainability, MDPI, vol. 14(8), pages 1-34, April.
    6. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2014. "Improved hydrogen generation from the hydrolysis of aluminum ball milled with hydride," Energy, Elsevier, vol. 72(C), pages 421-426.
    7. Zou, Mei-Shuai & Huang, Hai-Tao & Sun, Qian & Guo, Xiao-Yan & Yang, Rong-Jie, 2014. "Effect of the storage environment on hydrogen production via hydrolysis reaction from activated Mg-based materials," Energy, Elsevier, vol. 76(C), pages 673-678.
    8. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah, 2014. "Hydrogen production through hydrolysis of sodium borohydride: Oleic acid stabilized Co–La–Zr–B nanoparticle as a novel catalyst," Energy, Elsevier, vol. 68(C), pages 152-159.
    9. Chai, Y.J. & Dong, Y.M. & Meng, H.X. & Jia, Y.Y. & Shen, J. & Huang, Y.M. & Wang, N., 2014. "Hydrogen generation by aluminum corrosion in cobalt (II) chloride and nickel (II) chloride aqueous solution," Energy, Elsevier, vol. 68(C), pages 204-209.
    10. Xiao, Fei & Guo, Yanpei & Li, Jianmin & Yang, Rongjie, 2018. "Hydrogen generation from hydrolysis of activated aluminum composites in tap water," Energy, Elsevier, vol. 157(C), pages 608-614.
    11. Ma, Miaolian & Yang, Lingli & Ouyang, Liuzhang & Shao, Huaiyu & Zhu, Min, 2019. "Promoting hydrogen generation from the hydrolysis of Mg-Graphite composites by plasma-assisted milling," Energy, Elsevier, vol. 167(C), pages 1205-1211.
    12. Öz, Çisem & Coşkuner Filiz, Bilge & Kantürk Figen, Aysel, 2017. "The effect of vinegar–acetic acid solution on the hydrogen generation performance of mechanochemically modified Magnesium (Mg) granules," Energy, Elsevier, vol. 127(C), pages 328-334.
    13. Li, Fang & Arthur, Ernest Evans & La, Dahye & Li, Qiming & Kim, Hern, 2014. "Immobilization of CoCl2 (cobalt chloride) on PAN (polyacrylonitrile) composite nanofiber mesh filled with carbon nanotubes for hydrogen production from hydrolysis of NaBH4 (sodium borohydride)," Energy, Elsevier, vol. 71(C), pages 32-39.
    14. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Investigation on the improved hydrolysis of aluminum–calcium hydride-salt mixture elaborated by ball milling," Energy, Elsevier, vol. 84(C), pages 714-721.
    15. Awad, A.S. & El-Asmar, E. & Tayeh, T. & Mauvy, F. & Nakhl, M. & Zakhour, M. & Bobet, J.-L., 2016. "Effect of carbons (G and CFs), TM (Ni, Fe and Al) and oxides (Nb2O5 and V2O5) on hydrogen generation from ball milled Mg-based hydrolysis reaction for fuel cell," Energy, Elsevier, vol. 95(C), pages 175-186.

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