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Efficiency of two-step solar thermochemical non-stoichiometric redox cycles with heat recovery

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  • Lapp, J.
  • Davidson, J.H.
  • Lipiński, W.

Abstract

Improvements in the effectiveness of solid phase heat recovery and in the thermodynamic properties of metal oxides are the most important paths to achieving unprecedented thermal efficiencies of 10% and higher in non-stoichiometric solar redox reactors. In this paper, the impact of solid and gas phase heat recovery on the efficiency of a non-stoichiometric cerium dioxide-based H2O/CO2 splitting cycle realized in a solar-driven reactor are evaluated in a parametric thermodynamic analysis. Application of solid phase heat recovery to the cycling metal oxide allows for lower reduction zone operating temperatures, simplifying reactor design. An optimum temperature for metal oxide reduction results from two competing phenomena as the reduction temperature is increased: increasing re-radiation losses from the reactor aperture and decreasing heat loss due to imperfect solid phase heat recovery. Additionally, solid phase heat recovery increases the efficiency gains made possible by gas phase heat recovery.

Suggested Citation

  • Lapp, J. & Davidson, J.H. & Lipiński, W., 2012. "Efficiency of two-step solar thermochemical non-stoichiometric redox cycles with heat recovery," Energy, Elsevier, vol. 37(1), pages 591-600.
    • Handle: RePEc:eee:energy:v:37:y:2012:i:1:p:591-600
    DOI: 10.1016/j.energy.2011.10.045
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    1. Blank, David A. & Wu, Chih, 1995. "Power optimization of an extra-terrestrial, solar-radiant stirling heat engine," Energy, Elsevier, vol. 20(6), pages 523-530.
    2. Kaneko, H. & Miura, T. & Ishihara, H. & Taku, S. & Yokoyama, T. & Nakajima, H. & Tamaura, Y., 2007. "Reactive ceramics of CeO2–MOx (M=Mn, Fe, Ni, Cu) for H2 generation by two-step water splitting using concentrated solar thermal energy," Energy, Elsevier, vol. 32(5), pages 656-663.
    3. Alexopoulos, Spiros & Hoffschmidt, Bernhard, 2010. "Solar tower power plant in Germany and future perspectives of the development of the technology in Greece and Cyprus," Renewable Energy, Elsevier, vol. 35(7), pages 1352-1356.
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    Cited by:

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    17. Zhu, Liya & Lu, Youjun & Shen, Shaohua, 2016. "Solar fuel production at high temperatures using ceria as a dense membrane," Energy, Elsevier, vol. 104(C), pages 53-63.
    18. Imponenti, Luca & Albrecht, Kevin J. & Kharait, Rounak & Sanders, Michael D. & Jackson, Gregory S., 2018. "Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C," Applied Energy, Elsevier, vol. 230(C), pages 1-18.
    19. Lidor, Alon & Aschwanden, Yves & Häseli, Jamina & Reckinger, Pit & Haueter, Philipp & Steinfeld, Aldo, 2023. "High-temperature heat recovery from a solar reactor for the thermochemical redox splitting of H2O and CO2," Applied Energy, Elsevier, vol. 329(C).
    20. Christopher L. Muhich & Brian D. Ehrhart & Ibraheam Al-Shankiti & Barbara J. Ward & Charles B. Musgrave & Alan W. Weimer, 2016. "A review and perspective of efficient hydrogen generation via solar thermal water splitting," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(3), pages 261-287, May.
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