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Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy

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  • Abanades, Stéphane
  • Charvin, Patrice
  • Flamant, Gilles
  • Neveu, Pierre

Abstract

Hydrogen, a promising and clean energy carrier, could potentially replace the use of fossil fuels in the transportation sector. Currently, no environmentally attractive, large-scale, low-cost and high-efficiency hydrogen production process is available for commercialization. Solar-driven water-splitting thermochemical cycles may constitute one of the ultimate options for CO2-free production of hydrogen. The method is environmentally friendly since it uses only water and solar energy. First, the potentially attractive thermochemical cycles must be identified based on a set of criteria. To reach this goal, a database that contains 280 referenced cycles was established. Then, the selection and evaluation of the promising cycles was performed in the temperature range of 900–2000°C, suitable to the use of concentrated solar energy. About 30 cycles selected for further investigations are presented in this paper. The principles and basis for a thermodynamic evaluation of the cycles are also given.

Suggested Citation

  • Abanades, Stéphane & Charvin, Patrice & Flamant, Gilles & Neveu, Pierre, 2006. "Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy," Energy, Elsevier, vol. 31(14), pages 2805-2822.
    • Handle: RePEc:eee:energy:v:31:y:2006:i:14:p:2805-2822
    DOI: 10.1016/j.energy.2005.11.002
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    References listed on IDEAS

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    1. Sturzenegger, M & Nüesch, P, 1999. "Efficiency analysis for a manganese-oxide-based thermochemical cycle," Energy, Elsevier, vol. 24(11), pages 959-970.
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