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Thermochemical two-step water-splitting for hydrogen production using Fe-YSZ particles and a ceramic foam device

Author

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  • Gokon, Nobuyuki
  • Hasegawa, Tomoki
  • Takahashi, Shingo
  • Kodama, Tatsuya

Abstract

Fe3O4 supported on cubic yttria-stabilized zirconia (Fe3O4/c-YSZ) is proposed as a promising redox material for the production of hydrogen from water via a thermochemical two-step water-splitting cycle. In this study, the evolution of oxygen and hydrogen during the cyclic reaction was examined using Fe3O4/c-YSZ particles in order to demonstrate reproducible and stoichometric oxygen/hydrogen production through a repeatable two-step reaction. Subsequently, a ceramic foam device coated with Fe3O4 and c-YSZ particles was prepared and examined as a thermochemical water-splitting device in a directly irradiated receiver/reactor hydrogen production system. The Fe3O4/c-YSZ system formed a Fe-containing YSZ (Fe-YSZ) by high-temperature reaction between Fe3O4 and the c-YSZ support at 1400°C in an inert atmosphere. The reaction mechanism of the two-step water-splitting cycle is associated with the redox transition of Fe2+–Fe3+ ions in the c-YSZ lattice. The Fe-YSZ particles exhibit good reproducibility for reaction with a hydrogen/oxygen ratio of approximately 2.0 throughout repeated cycles. The foam device coated with Fe-YSZ particles was also successful for continual hydrogen production through 32 repeated cycles. A 20–27% ferrite conversion was obtained using 10.5wt% Fe3O4 loading over an irradiation period of 60min.

Suggested Citation

  • Gokon, Nobuyuki & Hasegawa, Tomoki & Takahashi, Shingo & Kodama, Tatsuya, 2008. "Thermochemical two-step water-splitting for hydrogen production using Fe-YSZ particles and a ceramic foam device," Energy, Elsevier, vol. 33(9), pages 1407-1416.
    • Handle: RePEc:eee:energy:v:33:y:2008:i:9:p:1407-1416
    DOI: 10.1016/j.energy.2008.04.011
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    References listed on IDEAS

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    1. Tamaura, Y. & Steinfeld, A. & Kuhn, P. & Ehrensberger, K., 1995. "Production of solar hydrogen by a novel, 2-step, water-splitting thermochemical cycle," Energy, Elsevier, vol. 20(4), pages 325-330.
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    3. Xiao, Lan & Wu, Shuang-Ying & Li, You-Rong, 2012. "Advances in solar hydrogen production via two-step water-splitting thermochemical cycles based on metal redox reactions," Renewable Energy, Elsevier, vol. 41(C), pages 1-12.
    4. Fan, Mei-qiang & Sun, Li-xian & Xu, Fen, 2010. "Feasibility study of hydrogen production for micro fuel cell from activated Al–In mixture in water," Energy, Elsevier, vol. 35(3), pages 1333-1337.
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    6. Yang, Weijuan & Zhang, Tianyou & Liu, Jianzhong & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature," Energy, Elsevier, vol. 93(P1), pages 451-457.
    7. Daphne Oudejans & Michele Offidani & Achilleas Constantinou & Stefania Albonetti & Nikolaos Dimitratos & Atul Bansode, 2022. "A Comprehensive Review on Two-Step Thermochemical Water Splitting for Hydrogen Production in a Redox Cycle," Energies, MDPI, vol. 15(9), pages 1-24, April.
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    10. Song, Lee-hwa & Kang, Hyun Woo & Park, Seung Bin, 2012. "Thermally stable iron based redox catalysts for the thermo-chemical hydrogen generation from water," Energy, Elsevier, vol. 42(1), pages 313-320.

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