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Improved hydrogen generation from the hydrolysis of aluminum ball milled with hydride

Author

Listed:
  • Liu, Yongan
  • Wang, Xinhua
  • Liu, Haizhen
  • Dong, Zhaohui
  • Li, Shouquan
  • Ge, Hongwei
  • Yan, Mi

Abstract

The hydrolysis of aluminum powder can be efficiently improved by milling with hydrides, among which LiH performs the best. Both sample composition and milling time affect the hydrolysis of Al–LiH mixture. Reaction temperature has a great impact on improving the hydrolysis properties. The reactions taken place in the solution are studied and the formation of the LiAl2(OH)7 hydrate is found to be important in enhancing the corrosion of Al. The Al-30 mol% LiH milled for 3 h sample reaches a yield of 96.3%, i.e. 1442.4 ml H2 g−1 (composite) within 1 h at 75 °C.

Suggested Citation

  • Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2014. "Improved hydrogen generation from the hydrolysis of aluminum ball milled with hydride," Energy, Elsevier, vol. 72(C), pages 421-426.
    • Handle: RePEc:eee:energy:v:72:y:2014:i:c:p:421-426
    DOI: 10.1016/j.energy.2014.05.060
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    Cited by:

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    2. Xiao, Fei & Yang, Rongjie & Li, Jianmin, 2019. "Hydrogen generation from hydrolysis of activated aluminum/organic fluoride/bismuth composites with high hydrogen generation rate and good aging resistance in air," Energy, Elsevier, vol. 170(C), pages 159-169.
    3. Yang, Weijuan & Zhang, Tianyou & Liu, Jianzhong & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature," Energy, Elsevier, vol. 93(P1), pages 451-457.
    4. Zou, Mei-Shuai & Huang, Hai-Tao & Sun, Qian & Guo, Xiao-Yan & Yang, Rong-Jie, 2014. "Effect of the storage environment on hydrogen production via hydrolysis reaction from activated Mg-based materials," Energy, Elsevier, vol. 76(C), pages 673-678.
    5. Su, Ming & Hu, Haiping & Gan, Jianchang & Ye, Wenhua & Zhang, Wenhua & Wang, Huihu, 2021. "Thermodynamics, kinetics and reaction mechanism of hydrogen production from a novel Al alloy/NaCl/g-C3N4 composite by low temperature hydrolysis," Energy, Elsevier, vol. 218(C).
    6. Liang, J. & Gao, L.J. & Miao, N.N. & Chai, Y.J. & Wang, N. & Song, X.Q., 2016. "Hydrogen generation by reaction of Al–M (M = Fe,Co,Ni) with water," Energy, Elsevier, vol. 113(C), pages 282-287.
    7. Li, Kang-Ning & Yang, Chuan-Lu & Han, Yan-Xiao & Wang, Mei-Shan & Ma, Xiao-Guang & Wang, Li-Zhi, 2016. "Generating H2 from a H2O molecule by catalysis using a small Al6Cu cluster," Energy, Elsevier, vol. 106(C), pages 131-136.
    8. Yang, Weijuan & Zhang, Tianyou & Zhou, Junhu & Shi, Wei & Liu, Jianzhong & Cen, Kefa, 2015. "Experimental study on the effect of low melting point metal additives on hydrogen production in the aluminum–water reaction," Energy, Elsevier, vol. 88(C), pages 537-543.
    9. Wang, Hongqi & Wang, Zhi & Shi, Zhihao & Gong, Xuzhong & Cao, Jianwei & Wang, Mingyong, 2017. "Facile hydrogen production from Al-water reaction promoted by choline hydroxide," Energy, Elsevier, vol. 131(C), pages 98-105.

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