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Reactive ceramics of CeO2–MOx (M=Mn, Fe, Ni, Cu) for H2 generation by two-step water splitting using concentrated solar thermal energy

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  • Kaneko, H.
  • Miura, T.
  • Ishihara, H.
  • Taku, S.
  • Yokoyama, T.
  • Nakajima, H.
  • Tamaura, Y.

Abstract

The addition of MOx (M: di- or tri-valent transition metal ion) into cerium dioxide (CeO2) enhanced the ability of CeO2 for the oxygen (O2)-releasing reaction at lower temperature and swift hydrogen (H2)-generation reaction. CeO2–MOx (M=Mn, Fe, Ni, Cu) reactive ceramics having high melting points were synthesized with the combustion method from their nitrates for solar H2 production. The prepared CeO2–MOx samples were solid solutions between CeO2 and MOx with the fluorite structure through the X-ray diffractometry measurement. Two-step water-splitting reactions with CeO2–MOx reactive ceramics proceeded at 1573–1773K for the O2-releasing step and at 1273K for the H2-generation step by irradiation of infrared image furnace as a solar simulator. The amounts of O2 evolved in the O2-releasing reaction with CeO2–MOx increased with an increase in the reaction temperature. The amounts of H2 evolved in the H2-generation reaction with CeO2–MOx systems except for M=Cu were more than that of CeO2 system after the O2-releasing reaction at the temperatures of 1673 and 1773K. The amounts of H2 evolved in the H2-generation reaction with CeO2–MnO and CeO2–NiO systems were more than those of CeO2–Fe2O3, CeO2–CuO and CeO2 systems after the O2-releasing reaction at the temperature of 1573K. The amounts of evolved H2 after the O2-releasing reaction at the temperature of 1773K in cm3 per gram of CeO2–MOx were 0.975–3.77cm3/g. The O2-releasing reaction at 1673K and H2-generation reaction at 1273K with CeO2–Fe2O3 proceeded with repetition of 4 times stoichiometrically.

Suggested Citation

  • Kaneko, H. & Miura, T. & Ishihara, H. & Taku, S. & Yokoyama, T. & Nakajima, H. & Tamaura, Y., 2007. "Reactive ceramics of CeO2–MOx (M=Mn, Fe, Ni, Cu) for H2 generation by two-step water splitting using concentrated solar thermal energy," Energy, Elsevier, vol. 32(5), pages 656-663.
  • Handle: RePEc:eee:energy:v:32:y:2007:i:5:p:656-663
    DOI: 10.1016/j.energy.2006.05.002
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    References listed on IDEAS

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    1. Tamaura, Y. & Steinfeld, A. & Kuhn, P. & Ehrensberger, K., 1995. "Production of solar hydrogen by a novel, 2-step, water-splitting thermochemical cycle," Energy, Elsevier, vol. 20(4), pages 325-330.
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    2. Hyun-Seok Cho & Tatsuya Kodama & Nobuyuki Gokon & Selvan Bellan & Jong-Kyu Kim, 2021. "Development of Synthesis and Fabrication Process for Mn-CeO 2 Foam via Two-Step Water-Splitting Cycle Hydrogen Production," Energies, MDPI, vol. 14(21), pages 1-14, October.
    3. Lapp, J. & Davidson, J.H. & Lipiński, W., 2012. "Efficiency of two-step solar thermochemical non-stoichiometric redox cycles with heat recovery," Energy, Elsevier, vol. 37(1), pages 591-600.
    4. Lange, M. & Roeb, M. & Sattler, C. & Pitz-Paal, R., 2014. "T–S diagram efficiency analysis of two-step thermochemical cycles for solar water splitting under various process conditions," Energy, Elsevier, vol. 67(C), pages 298-308.
    5. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Cao, Guozhou & Yan, Mi, 2014. "Hydrogen generation from Mg–LiBH4 hydrolysis improved by AlCl3 addition," Energy, Elsevier, vol. 68(C), pages 548-554.
    6. Fan, Mei-qiang & Sun, Li-xian & Xu, Fen, 2010. "Feasibility study of hydrogen production for micro fuel cell from activated Al–In mixture in water," Energy, Elsevier, vol. 35(3), pages 1333-1337.
    7. Abdin, Zainul & Zafaranloo, Ali & Rafiee, Ahmad & Mérida, Walter & Lipiński, Wojciech & Khalilpour, Kaveh R., 2020. "Hydrogen as an energy vector," Renewable and Sustainable Energy Reviews, Elsevier, vol. 120(C).
    8. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2014. "Improved hydrogen generation from the hydrolysis of aluminum ball milled with hydride," Energy, Elsevier, vol. 72(C), pages 421-426.
    9. Gokon, Nobuyuki & Suda, Toshinori & Kodama, Tatsuya, 2015. "Oxygen and hydrogen productivities and repeatable reactivity of 30-mol%-Fe-, Co-, Ni-, Mn-doped CeO2−δ for thermochemical two-step water-splitting cycle," Energy, Elsevier, vol. 90(P2), pages 1280-1289.
    10. Fan, Mei–qiang & Sun, Li–xian & Xu, Fen, 2010. "Experiment assessment of hydrogen production from activated aluminum alloys in portable generator for fuel cell applications," Energy, Elsevier, vol. 35(7), pages 2922-2926.
    11. Zhu, Liya & Lu, Youjun & Shen, Shaohua, 2016. "Solar fuel production at high temperatures using ceria as a dense membrane," Energy, Elsevier, vol. 104(C), pages 53-63.
    12. Christopher L. Muhich & Brian D. Ehrhart & Ibraheam Al-Shankiti & Barbara J. Ward & Charles B. Musgrave & Alan W. Weimer, 2016. "A review and perspective of efficient hydrogen generation via solar thermal water splitting," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(3), pages 261-287, May.

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