IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v89y2015icp907-913.html
   My bibliography  Save this article

Effect of salts addition on the hydrogen generation of Al–LiH composite elaborated by ball milling

Author

Listed:
  • Liu, Yongan
  • Wang, Xinhua
  • Liu, Haizhen
  • Dong, Zhaohui
  • Li, Shouquan
  • Ge, Hongwei
  • Yan, Mi

Abstract

Hydrogen generation from ball milled Al–LiH-salts mixture is studied. Different salts are used to test their effects on the hydrolysis properties of Al–LiH composite. KCl is found to be more effective than other salts and shows the best performance. Raising initial reaction temperature can effectively improve hydrogen yield and HG (hydrogen generation) rate of the Al–LiH–KCl mixture. Optimizing the milling conditions is necessary to improve the hydrogen generation performances of the composites. The addition amounts of KCl and LiH are varied and 10 mol% proves to be the optimum value for both of them in this work. Too much addition of LiH or KCl will cause the decrease of the hydrogen yield. A proper milling time of 10 h is discovered in this work which is beneficial for the decrease of grain size and improvement of reactivity. The 10 h milled Al-10 mol%LiH-10 mol% KCl mixture reaches a hydrogen yield of 97.1% in 10 min at 60 °C. Preliminary mechanism for the improvement has been discussed.

Suggested Citation

  • Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Effect of salts addition on the hydrogen generation of Al–LiH composite elaborated by ball milling," Energy, Elsevier, vol. 89(C), pages 907-913.
    • Handle: RePEc:eee:energy:v:89:y:2015:i:c:p:907-913
    DOI: 10.1016/j.energy.2015.06.043
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544215007999
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.06.043?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Fan, Mei Qiang & Sun, Li Xian & Xu, Fen, 2011. "Hydrogen production for micro-fuel-cell from activated Al–Sn–Zn–X (X: hydride or halide) mixture in water," Renewable Energy, Elsevier, vol. 36(2), pages 519-524.
    2. Liu, Yongan & Wang, Xinhua & Dong, Zhaohui & Liu, Haizhen & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2013. "Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3," Energy, Elsevier, vol. 53(C), pages 147-152.
    3. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Cao, Guozhou & Yan, Mi, 2014. "Hydrogen generation from Mg–LiBH4 hydrolysis improved by AlCl3 addition," Energy, Elsevier, vol. 68(C), pages 548-554.
    4. Zhao, Zhongwei & Chen, Xingyu & Hao, Mingming, 2011. "Hydrogen generation by splitting water with Al–Ca alloy," Energy, Elsevier, vol. 36(5), pages 2782-2787.
    5. Fan, Mei-qiang & Sun, Li-xian & Xu, Fen, 2010. "Feasibility study of hydrogen production for micro fuel cell from activated Al–In mixture in water," Energy, Elsevier, vol. 35(3), pages 1333-1337.
    6. Fan, Mei–qiang & Sun, Li–xian & Xu, Fen, 2010. "Experiment assessment of hydrogen production from activated aluminum alloys in portable generator for fuel cell applications," Energy, Elsevier, vol. 35(7), pages 2922-2926.
    7. Huang, Yao-Hui & Su, Chia-Chi & Wang, Shu-Ling & Lu, Ming-Chun, 2012. "Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis," Energy, Elsevier, vol. 46(1), pages 242-247.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gai, Wei-Zhuo & Deng, Zhen-Yan, 2024. "Enhanced hydrogen production from Al-water reaction: Strategies, performances, mechanisms and applications," Renewable Energy, Elsevier, vol. 226(C).
    2. Xiao, Fei & Yang, Rongjie & Li, Jianmin, 2019. "Hydrogen generation from hydrolysis of activated aluminum/organic fluoride/bismuth composites with high hydrogen generation rate and good aging resistance in air," Energy, Elsevier, vol. 170(C), pages 159-169.
    3. Su, Ming & Hu, Haiping & Gan, Jianchang & Ye, Wenhua & Zhang, Wenhua & Wang, Huihu, 2021. "Thermodynamics, kinetics and reaction mechanism of hydrogen production from a novel Al alloy/NaCl/g-C3N4 composite by low temperature hydrolysis," Energy, Elsevier, vol. 218(C).
    4. Xiao, Fei & Guo, Yanpei & Li, Jianmin & Yang, Rongjie, 2018. "Hydrogen generation from hydrolysis of activated aluminum composites in tap water," Energy, Elsevier, vol. 157(C), pages 608-614.
    5. Ma, Miaolian & Yang, Lingli & Ouyang, Liuzhang & Shao, Huaiyu & Zhu, Min, 2019. "Promoting hydrogen generation from the hydrolysis of Mg-Graphite composites by plasma-assisted milling," Energy, Elsevier, vol. 167(C), pages 1205-1211.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sun, Qian & Zou, Meishuai & Guo, Xiaoyan & Yang, Rongjie & Huang, Haitao & Huang, Peng & He, Xiangdong, 2015. "A study of hydrogen generation by reaction of an activated Mg–CoCl2 (magnesium–cobalt chloride) composite with pure water for portable applications," Energy, Elsevier, vol. 79(C), pages 310-314.
    2. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Cao, Guozhou & Yan, Mi, 2014. "Hydrogen generation from Mg–LiBH4 hydrolysis improved by AlCl3 addition," Energy, Elsevier, vol. 68(C), pages 548-554.
    3. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Investigation on the improved hydrolysis of aluminum–calcium hydride-salt mixture elaborated by ball milling," Energy, Elsevier, vol. 84(C), pages 714-721.
    4. Xiao, Fei & Guo, Yanpei & Li, Jianmin & Yang, Rongjie, 2018. "Hydrogen generation from hydrolysis of activated aluminum composites in tap water," Energy, Elsevier, vol. 157(C), pages 608-614.
    5. Liu, Yongan & Wang, Xinhua & Dong, Zhaohui & Liu, Haizhen & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2013. "Hydrogen generation from the hydrolysis of Mg powder ball-milled with AlCl3," Energy, Elsevier, vol. 53(C), pages 147-152.
    6. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2014. "Improved hydrogen generation from the hydrolysis of aluminum ball milled with hydride," Energy, Elsevier, vol. 72(C), pages 421-426.
    7. Öz, Çisem & Coşkuner Filiz, Bilge & Kantürk Figen, Aysel, 2017. "The effect of vinegar–acetic acid solution on the hydrogen generation performance of mechanochemically modified Magnesium (Mg) granules," Energy, Elsevier, vol. 127(C), pages 328-334.
    8. Chai, Y.J. & Dong, Y.M. & Meng, H.X. & Jia, Y.Y. & Shen, J. & Huang, Y.M. & Wang, N., 2014. "Hydrogen generation by aluminum corrosion in cobalt (II) chloride and nickel (II) chloride aqueous solution," Energy, Elsevier, vol. 68(C), pages 204-209.
    9. Yang, Weijuan & Zhang, Tianyou & Liu, Jianzhong & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature," Energy, Elsevier, vol. 93(P1), pages 451-457.
    10. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah, 2014. "Hydrogen production through hydrolysis of sodium borohydride: Oleic acid stabilized Co–La–Zr–B nanoparticle as a novel catalyst," Energy, Elsevier, vol. 68(C), pages 152-159.
    11. Yang, Weijuan & Zhang, Tianyou & Zhou, Junhu & Shi, Wei & Liu, Jianzhong & Cen, Kefa, 2015. "Experimental study on the effect of low melting point metal additives on hydrogen production in the aluminum–water reaction," Energy, Elsevier, vol. 88(C), pages 537-543.
    12. Su, Ming & Hu, Haiping & Gan, Jianchang & Ye, Wenhua & Zhang, Wenhua & Wang, Huihu, 2021. "Thermodynamics, kinetics and reaction mechanism of hydrogen production from a novel Al alloy/NaCl/g-C3N4 composite by low temperature hydrolysis," Energy, Elsevier, vol. 218(C).
    13. Zou, Mei-Shuai & Huang, Hai-Tao & Sun, Qian & Guo, Xiao-Yan & Yang, Rong-Jie, 2014. "Effect of the storage environment on hydrogen production via hydrolysis reaction from activated Mg-based materials," Energy, Elsevier, vol. 76(C), pages 673-678.
    14. Awad, A.S. & El-Asmar, E. & Tayeh, T. & Mauvy, F. & Nakhl, M. & Zakhour, M. & Bobet, J.-L., 2016. "Effect of carbons (G and CFs), TM (Ni, Fe and Al) and oxides (Nb2O5 and V2O5) on hydrogen generation from ball milled Mg-based hydrolysis reaction for fuel cell," Energy, Elsevier, vol. 95(C), pages 175-186.
    15. Xiao, Fei & Yang, Rongjie & Li, Jianmin, 2019. "Hydrogen generation from hydrolysis of activated aluminum/organic fluoride/bismuth composites with high hydrogen generation rate and good aging resistance in air," Energy, Elsevier, vol. 170(C), pages 159-169.
    16. Ma, Miaolian & Yang, Lingli & Ouyang, Liuzhang & Shao, Huaiyu & Zhu, Min, 2019. "Promoting hydrogen generation from the hydrolysis of Mg-Graphite composites by plasma-assisted milling," Energy, Elsevier, vol. 167(C), pages 1205-1211.
    17. Li, Fang & Arthur, Ernest Evans & La, Dahye & Li, Qiming & Kim, Hern, 2014. "Immobilization of CoCl2 (cobalt chloride) on PAN (polyacrylonitrile) composite nanofiber mesh filled with carbon nanotubes for hydrogen production from hydrolysis of NaBH4 (sodium borohydride)," Energy, Elsevier, vol. 71(C), pages 32-39.
    18. Gai, Wei-Zhuo & Deng, Zhen-Yan, 2024. "Enhanced hydrogen production from Al-water reaction: Strategies, performances, mechanisms and applications," Renewable Energy, Elsevier, vol. 226(C).
    19. Zhao, Zhongwei & Chen, Xingyu & Hao, Mingming, 2011. "Hydrogen generation by splitting water with Al–Ca alloy," Energy, Elsevier, vol. 36(5), pages 2782-2787.
    20. Kim, Taegyu, 2014. "NaBH4 (sodium borohydride) hydrogen generator with a volume-exchange fuel tank for small unmanned aerial vehicles powered by a PEM (proton exchange membrane) fuel cell," Energy, Elsevier, vol. 69(C), pages 721-727.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:89:y:2015:i:c:p:907-913. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.