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Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature

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  • Yang, Weijuan
  • Zhang, Tianyou
  • Liu, Jianzhong
  • Wang, Zhihua
  • Zhou, Junhu
  • Cen, Kefa

Abstract

In order to recover the released heat of Al–H2O reaction and promote the reaction itself, the hydrogen production processes of aluminum with lithium addition in molten state are investigated. Experiments are conducted by both a thermogravimetric analyzer and a special experimental facility at high temperature. The results on both apparatuses show that the addition of Li can promote the reactivity of aluminum with water. Compared with pure aluminum, only 5% of Li content can achieve a great improvement: the H2 yield increases from 8.7% to 53% and the average H2 generation rate from 15 to 112 mL min−1 g−1. With the increase of Li content, H2 yield is improved distinctly and the period with a high H2 generation rate is prolonged. In the Al–20%Li case, the H2 yield of 88% is obtained, and it appears a stable period in which the H2 generation rate keeps high. When adding lithium, LiAlO2 appears in the products and the products are made of columnar crystals. The pores with an average size of 17–33 nm in the LiAlO2 products are manyfold bigger than the pores of alumina, which takes an important role in improving the reactivity of aluminum and water.

Suggested Citation

  • Yang, Weijuan & Zhang, Tianyou & Liu, Jianzhong & Wang, Zhihua & Zhou, Junhu & Cen, Kefa, 2015. "Experimental researches on hydrogen generation by aluminum with adding lithium at high temperature," Energy, Elsevier, vol. 93(P1), pages 451-457.
    • Handle: RePEc:eee:energy:v:93:y:2015:i:p1:p:451-457
    DOI: 10.1016/j.energy.2015.09.048
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    1. Nong, Guangzai & Li, Ming & Chen, Yiyi & Zhou, Zongwen & Wang, Shuangfei, 2015. "Simulation of energy conversion in a plant of photocatalysts water splitting for hydrogen fuel," Energy, Elsevier, vol. 81(C), pages 471-476.
    2. Shkolnikov, E.I. & Zhuk, A.Z. & Vlaskin, M.S., 2011. "Aluminum as energy carrier: Feasibility analysis and current technologies overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4611-4623.
    3. Ni, Meng & Leung, Michael K.H. & Leung, Dennis Y.C. & Sumathy, K., 2007. "A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(3), pages 401-425, April.
    4. Macanás, Jorge & Soler, Lluís & Candela, Angélica María & Muñoz, Maria & Casado, Juan, 2011. "Hydrogen generation by aluminum corrosion in aqueous alkaline solutions of inorganic promoters: The AlHidrox process," Energy, Elsevier, vol. 36(5), pages 2493-2501.
    5. Chen, Y. & Kim, H., 2010. "Preparation and application of sodium borohydride composites for portable hydrogen production," Energy, Elsevier, vol. 35(2), pages 960-963.
    6. Zhao, Zhongwei & Chen, Xingyu & Hao, Mingming, 2011. "Hydrogen generation by splitting water with Al–Ca alloy," Energy, Elsevier, vol. 36(5), pages 2782-2787.
    7. Fan, Mei-qiang & Sun, Li-xian & Xu, Fen, 2010. "Feasibility study of hydrogen production for micro fuel cell from activated Al–In mixture in water," Energy, Elsevier, vol. 35(3), pages 1333-1337.
    8. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2015. "Investigation on the improved hydrolysis of aluminum–calcium hydride-salt mixture elaborated by ball milling," Energy, Elsevier, vol. 84(C), pages 714-721.
    9. Chai, Y.J. & Dong, Y.M. & Meng, H.X. & Jia, Y.Y. & Shen, J. & Huang, Y.M. & Wang, N., 2014. "Hydrogen generation by aluminum corrosion in cobalt (II) chloride and nickel (II) chloride aqueous solution," Energy, Elsevier, vol. 68(C), pages 204-209.
    10. Johansson, Daniella & Franck, Per-Åke & Berntsson, Thore, 2012. "Hydrogen production from biomass gasification in the oil refining industry – A system analysis," Energy, Elsevier, vol. 38(1), pages 212-227.
    11. Fan, Mei–qiang & Sun, Li–xian & Xu, Fen, 2010. "Experiment assessment of hydrogen production from activated aluminum alloys in portable generator for fuel cell applications," Energy, Elsevier, vol. 35(7), pages 2922-2926.
    12. Principi, G. & Agresti, F. & Maddalena, A. & Lo Russo, S., 2009. "The problem of solid state hydrogen storage," Energy, Elsevier, vol. 34(12), pages 2087-2091.
    13. Wang, H.Z. & Leung, D.Y.C. & Leung, M.K.H. & Ni, M., 2009. "A review on hydrogen production using aluminum and aluminum alloys," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(4), pages 845-853, May.
    14. Gokon, Nobuyuki & Hasegawa, Tomoki & Takahashi, Shingo & Kodama, Tatsuya, 2008. "Thermochemical two-step water-splitting for hydrogen production using Fe-YSZ particles and a ceramic foam device," Energy, Elsevier, vol. 33(9), pages 1407-1416.
    15. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Li, Shouquan & Ge, Hongwei & Yan, Mi, 2014. "Improved hydrogen generation from the hydrolysis of aluminum ball milled with hydride," Energy, Elsevier, vol. 72(C), pages 421-426.
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    2. Xiao, Fei & Yang, Rongjie & Li, Jianmin, 2019. "Hydrogen generation from hydrolysis of activated aluminum/organic fluoride/bismuth composites with high hydrogen generation rate and good aging resistance in air," Energy, Elsevier, vol. 170(C), pages 159-169.
    3. Xiao, Fei & Guo, Yanpei & Li, Jianmin & Yang, Rongjie, 2018. "Hydrogen generation from hydrolysis of activated aluminum composites in tap water," Energy, Elsevier, vol. 157(C), pages 608-614.
    4. Liang, J. & Gao, L.J. & Miao, N.N. & Chai, Y.J. & Wang, N. & Song, X.Q., 2016. "Hydrogen generation by reaction of Al–M (M = Fe,Co,Ni) with water," Energy, Elsevier, vol. 113(C), pages 282-287.

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