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Direct hydrocarbon fuel cells: A promising technology for improving energy efficiency

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  • Mohammed, Hanin
  • Al-Othman, Amani
  • Nancarrow, Paul
  • Tawalbeh, Muhammad
  • El Haj Assad, Mamdouh

Abstract

The world's first fuel cell described in the early 1800's was fueled with hydrogen. While hydrogen is still the most common fuel, hydrocarbon fuels offer several advantages including availability at a lower cost, higher storage density and existing infrastructure. This paper provides an overview for the significant potential benefits of using hydrocarbon fuels directly in a fuel cell system. Their use leads to a reduction in the capital cost due to the elimination of the fuel processor unit. The fundamentals, advantages, types of direct hydrocarbon fuel cells (DHFC), challenges and applications are discussed in this paper. The past and current status of research and development activities are addressed with emphasis on efficiency and exergy analyses. In spite of their high theoretical energy efficiency, technical challenges remain unsolved in DHFC systems. In high temperature hydrocarbon fueled operation, the deposition of carbon-based material leads to fuel cell degradation. In lower temperature fuel cells, electrode (mainly the anode) over-potentials and fuel crossover are still challenging. Therefore, the improvement and commercialization of these types of fuel cells will probably require the development of less or non-noble catalysts and reasonably functioning membranes.

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  • Mohammed, Hanin & Al-Othman, Amani & Nancarrow, Paul & Tawalbeh, Muhammad & El Haj Assad, Mamdouh, 2019. "Direct hydrocarbon fuel cells: A promising technology for improving energy efficiency," Energy, Elsevier, vol. 172(C), pages 207-219.
    • Handle: RePEc:eee:energy:v:172:y:2019:i:c:p:207-219
    DOI: 10.1016/j.energy.2019.01.105
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    References listed on IDEAS

    as
    1. Wang, Junye, 2015. "Barriers of scaling-up fuel cells: Cost, durability and reliability," Energy, Elsevier, vol. 80(C), pages 509-521.
    2. Jiao, Yong & Zhang, Liqin & An, Wenting & Zhou, Wei & Sha, Yujing & Shao, Zongping & Bai, Jianping & Li, Si-Dian, 2016. "Controlled deposition and utilization of carbon on Ni-YSZ anodes of SOFCs operating on dry methane," Energy, Elsevier, vol. 113(C), pages 432-443.
    3. Patil, V. & Shastry, V. & Himabindu, M. & Ravikrishna, R.V., 2016. "Life-cycle analysis of energy and greenhouse gas emissions of automotive fuels in India: Part 2 – Well-to-wheels analysis," Energy, Elsevier, vol. 96(C), pages 699-712.
    4. Wang, Yun & Chen, Ken S. & Mishler, Jeffrey & Cho, Sung Chan & Adroher, Xavier Cordobes, 2011. "A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research," Applied Energy, Elsevier, vol. 88(4), pages 981-1007, April.
    5. Tippawan, Phanicha & Arpornwichanop, Amornchai & Dincer, Ibrahim, 2015. "Energy and exergy analyses of an ethanol-fueled solid oxide fuel cell for a trigeneration system," Energy, Elsevier, vol. 87(C), pages 228-239.
    6. Seungdoo Park & John M. Vohs & Raymond J. Gorte, 2000. "Direct oxidation of hydrocarbons in a solid-oxide fuel cell," Nature, Nature, vol. 404(6775), pages 265-267, March.
    7. Federico Rossi & Andrea Nicolini, 2012. "Ethanol reforming for supplying molten carbonate fuel cells," International Journal of Low-Carbon Technologies, Oxford University Press, vol. 8(2), pages 140-145, May.
    8. Daud, W.R.W. & Rosli, R.E. & Majlan, E.H. & Hamid, S.A.A. & Mohamed, R. & Husaini, T., 2017. "PEM fuel cell system control: A review," Renewable Energy, Elsevier, vol. 113(C), pages 620-638.
    9. Taner, Tolga, 2018. "Energy and exergy analyze of PEM fuel cell: A case study of modeling and simulations," Energy, Elsevier, vol. 143(C), pages 284-294.
    10. Antolini, Ermete, 2011. "The stability of molten carbonate fuel cell electrodes: A review of recent improvements," Applied Energy, Elsevier, vol. 88(12), pages 4274-4293.
    11. Zhu, Li & Chen, Junghui, 2018. "Prognostics of PEM fuel cells based on Gaussian process state space models," Energy, Elsevier, vol. 149(C), pages 63-73.
    12. Badwal, S.P.S. & Giddey, S. & Kulkarni, A. & Goel, J. & Basu, S., 2015. "Direct ethanol fuel cells for transport and stationary applications – A comprehensive review," Applied Energy, Elsevier, vol. 145(C), pages 80-103.
    13. Chen, Xiaohang & Wang, Yuan & Zhao, Yingru & Zhou, Yinghui, 2016. "A study of double functions and load matching of a phosphoric acid fuel cell/heat-driven refrigerator hybrid system," Energy, Elsevier, vol. 101(C), pages 359-365.
    14. Rahgoshay, S.M. & Ranjbar, A.A. & Ramiar, A. & Alizadeh, E., 2017. "Thermal investigation of a PEM fuel cell with cooling flow field," Energy, Elsevier, vol. 134(C), pages 61-73.
    15. Sharaf, Omar Z. & Orhan, Mehmet F., 2014. "An overview of fuel cell technology: Fundamentals and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 810-853.
    16. Damo, U.M. & Ferrari, M.L. & Turan, A. & Massardo, A.F., 2019. "Solid oxide fuel cell hybrid system: A detailed review of an environmentally clean and efficient source of energy," Energy, Elsevier, vol. 168(C), pages 235-246.
    17. Gupta, S. & Patil, V. & Himabindu, M. & Ravikrishna, R.V., 2016. "Life-cycle analysis of energy and greenhouse gas emissions of automotive fuels in India: Part 1 – Tank-to-Wheel analysis," Energy, Elsevier, vol. 96(C), pages 684-698.
    18. Andújar, J.M. & Segura, F., 2009. "Fuel cells: History and updating. A walk along two centuries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2309-2322, December.
    19. Fathabadi, Hassan, 2018. "Novel fuel cell/battery/supercapacitor hybrid power source for fuel cell hybrid electric vehicles," Energy, Elsevier, vol. 143(C), pages 467-477.
    20. Abdelkareem, Mohammad Ali & Allagui, Anis & Sayed, Enas Taha & El Haj Assad, M. & Said, Zafar & Elsaid, Khaled, 2019. "Comparative analysis of liquid versus vapor-feed passive direct methanol fuel cells," Renewable Energy, Elsevier, vol. 131(C), pages 563-584.
    21. Oliveira, V.B. & Pereira, J.P. & Pinto, A.M.F.R., 2017. "Modeling of passive direct ethanol fuel cells," Energy, Elsevier, vol. 133(C), pages 652-665.
    22. Chavan, Sudarshan L. & Talange, Dhananjay B., 2017. "Modeling and performance evaluation of PEM fuel cell by controlling its input parameters," Energy, Elsevier, vol. 138(C), pages 437-445.
    23. Lucia, Umberto, 2014. "Overview on fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 164-169.
    24. Kirubakaran, A. & Jain, Shailendra & Nema, R.K., 2009. "A review on fuel cell technologies and power electronic interface," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(9), pages 2430-2440, December.
    25. Stropnik, R. & Sekavčnik, M. & Ferriz, A.M. & Mori, M., 2018. "Reducing environmental impacts of the ups system based on PEM fuel cell with circular economy," Energy, Elsevier, vol. 165(PB), pages 824-835.
    26. Hou, Qinlong & Zhao, Hongbin & Yang, Xiaoyu, 2018. "Thermodynamic performance study of the integrated MR-SOFC-CCHP system," Energy, Elsevier, vol. 150(C), pages 434-450.
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