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The stability of molten carbonate fuel cell electrodes: A review of recent improvements

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  • Antolini, Ermete

Abstract

The electrode stability is a key issue for the development of conventional hydrogen fuelled and direct internal reforming (DIR) molten carbonate fuel cells (MCFCs). While for conventional MCFC anodes the stability problem has been addressed by the addition of Al or Cr to Ni, the problems of the dissolution of the NiO cathode and of the deactivation of DIR-MCFC anodes have not been fully resolved too. This review reports recent improvements in the chemical and physicochemical stability of cathode and anode materials in MCFCs and DIR-MCFCs, respectively.

Suggested Citation

  • Antolini, Ermete, 2011. "The stability of molten carbonate fuel cell electrodes: A review of recent improvements," Applied Energy, Elsevier, vol. 88(12), pages 4274-4293.
    • Handle: RePEc:eee:appene:v:88:y:2011:i:12:p:4274-4293
    DOI: 10.1016/j.apenergy.2011.07.009
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    1. Mohammed, Hanin & Al-Othman, Amani & Nancarrow, Paul & Tawalbeh, Muhammad & El Haj Assad, Mamdouh, 2019. "Direct hydrocarbon fuel cells: A promising technology for improving energy efficiency," Energy, Elsevier, vol. 172(C), pages 207-219.
    2. Falcucci, G. & Jannelli, E. & Minutillo, M. & Ubertini, S. & Han, J. & Yoon, S.P. & Nam, S.W., 2012. "Integrated numerical and experimental study of a MCFC-plasma gasifier energy system," Applied Energy, Elsevier, vol. 97(C), pages 734-742.
    3. Chen, Shiyi & Zhou, Nan & Wu, Mudi & Chen, Shubo & Xiang, Wenguo, 2022. "Integration of molten carbonate fuel cell and chemical looping air separation for high-efficient power generation and CO2 capture," Energy, Elsevier, vol. 254(PA).
    4. Wu, Sijie & Zhang, Houcheng & Ni, Meng, 2016. "Performance assessment of a hybrid system integrating a molten carbonate fuel cell and a thermoelectric generator," Energy, Elsevier, vol. 112(C), pages 520-527.
    5. Çalışır, Duran & Ekici, Selcuk & Midilli, Adnan & Karakoc, T. Hikmet, 2023. "Benchmarking environmental impacts of power groups used in a designed UAV: Hybrid hydrogen fuel cell system versus lithium-polymer battery drive system," Energy, Elsevier, vol. 262(PB).
    6. Lo Basso, Gianluigi & de Santoli, Livio & Albo, Angelo & Nastasi, Benedetto, 2015. "H2NG (hydrogen-natural gas mixtures) effects on energy performances of a condensing micro-CHP (combined heat and power) for residential applications: An expeditious assessment of water condensation an," Energy, Elsevier, vol. 84(C), pages 397-418.
    7. Zhang, Xiuqin & Liu, Huiying & Ni, Meng & Chen, Jincan, 2015. "Performance evaluation and parametric optimum design of a syngas molten carbonate fuel cell and gas turbine hybrid system," Renewable Energy, Elsevier, vol. 80(C), pages 407-414.
    8. Abdollahipour, Armin & Sayyaadi, Hoseyn, 2021. "Thermal energy recovery of molten carbonate fuel cells by thermally regenerative electrochemical cycles," Energy, Elsevier, vol. 227(C).
    9. Yang, Bo & Liang, Boxiao & Qian, Yucun & Zheng, Ruyi & Su, Shi & Guo, Zhengxun & Jiang, Lin, 2024. "Parameter identification of PEMFC via feedforward neural network-pelican optimization algorithm," Applied Energy, Elsevier, vol. 361(C).
    10. Das, Satyen Kumar & Mohanty, Pravakar & Majhi, Sachchit & Pant, Kamal Kishore, 2013. "CO-hydrogenation over silica supported iron based catalysts: Influence of potassium loading," Applied Energy, Elsevier, vol. 111(C), pages 267-276.
    11. Skabelund, B.B. & Milcarek, R.J., 2022. "Review of thermal partial oxidation reforming with integrated solid oxide fuel cell power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    12. Zakaria, Zulfirdaus & Kamarudin, Siti Kartom & Abd Wahid, Khairul Anuar & Abu Hassan, Saiful Hasmady, 2021. "The progress of fuel cell for malaysian residential consumption: Energy status and prospects to introduction as a renewable power generation system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    13. Rizkiana, Jenny & Guan, Guoqing & Widayatno, Wahyu Bambang & Hao, Xiaogang & Wang, Zhongde & Zhang, Zhonglin & Abudula, Abuliti, 2015. "Oil production from mild pyrolysis of low-rank coal in molten salts media," Applied Energy, Elsevier, vol. 154(C), pages 944-950.

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