IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v190y2020ics0360544219321462.html
   My bibliography  Save this article

Properties and DMFC performance of nafion/mordenite composite membrane fabricated by solution-casting method with different solvent ratio

Author

Listed:
  • Prapainainar, Paweena
  • Du, Zehui
  • Theampetch, Apichaya
  • Prapainainar, Chaiwat
  • Kongkachuichay, Paisan
  • Holmes, Stuart M.

Abstract

The effect of alcohol ratio in solution casting of composite membranes is one of the important factors to their good properties for direct methanol fuel cell (DMFC). The investigation was focused on the effect of alcohol ratio (methanol/ethanol mixture) during the fabrication process on the membrane properties, morphology, chemical resistance, water uptake, proton conductivity and methanol permeability. Alcohol mixture with proportion of 0–5 vol ratio was varied in order to prepare the composite membranes. It was found that the alcohol ratio had insignificant effect on the homogeneity of the composite membranes as the layers of polymer rich and mordenite rich were formed. The ratio had insignificant effect on proton conductivity of the composite membranes. Reducing alcohol ratio from five to three, however, led to 80% chemical resistance reduction and 70% higher methanol permeability. Finally, these composite membranes with five volume ratio of alcohol were used in membrane electrode assembly and tested in a DMFC compared to recast Nafion membrane. The composite membranes gave a maximum power density of 11.5 mW cm−2 at 343.15 K, which was 58% higher than that of recast membrane.

Suggested Citation

  • Prapainainar, Paweena & Du, Zehui & Theampetch, Apichaya & Prapainainar, Chaiwat & Kongkachuichay, Paisan & Holmes, Stuart M., 2020. "Properties and DMFC performance of nafion/mordenite composite membrane fabricated by solution-casting method with different solvent ratio," Energy, Elsevier, vol. 190(C).
  • Handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219321462
    DOI: 10.1016/j.energy.2019.116451
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544219321462
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.energy.2019.116451?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Yeh, Pulin & Chang, Chu Hsiang & Shih, Naichien & Yeh, Naichia, 2016. "Durability and efficiency tests for direct methanol fuel cell's long-term performance assessment," Energy, Elsevier, vol. 107(C), pages 716-724.
    2. Hosseini, Mirollah & Afrouzi, Hamid Hassanzadeh & Arasteh, Hossein & Toghraie, Davood, 2019. "Energy analysis of a proton exchange membrane fuel cell (PEMFC) with an open-ended anode using agglomerate model: A CFD study," Energy, Elsevier, vol. 188(C).
    3. Fang, Shuo & Zhang, Yufeng & Ma, Zezhong & Sang, Shengtian & Liu, Xiaowei, 2016. "Systemic modeling and analysis of DMFC stack for behavior prediction in system-level application," Energy, Elsevier, vol. 112(C), pages 1015-1023.
    4. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Investigation of NaOH concentration effect in injected fuel on the performance of passive direct methanol alkaline fuel cell with modified cation exchange membrane," Energy, Elsevier, vol. 94(C), pages 589-599.
    5. Atyabi, Seyed Ali & Afshari, Ebrahim & Wongwises, Somchai & Yan, Wen-Mon & Hadjadj, Abdellah & Shadloo, Mostafa Safdari, 2019. "Effects of assembly pressure on PEM fuel cell performance by taking into accounts electrical and thermal contact resistances," Energy, Elsevier, vol. 179(C), pages 490-501.
    6. Ko, Johan & Chippar, Purushothama & Ju, Hyunchul, 2010. "A one-dimensional, two-phase model for direct methanol fuel cells – Part I: Model development and parametric study," Energy, Elsevier, vol. 35(5), pages 2149-2159.
    7. Fang, Shuo & Zhang, Yufeng & Ma, Zezhong & Zou, Yuezhang & Liu, Xiaowei, 2016. "Development of a micro direct methanol fuel cell with heat control," Energy, Elsevier, vol. 116(P1), pages 978-985.
    8. Alipour Najmi, Ali & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of physicochemical characterization of potassium-doped Nafion117 membrane and performance evaluation of air-breathing fuel cell in different alkali-methanol solutions," Energy, Elsevier, vol. 113(C), pages 1090-1098.
    9. An, Myung-Gi & Mehmood, Asad & Hwang, Jinyeon & Ha, Heung Yong, 2016. "A novel method of methanol concentration control through feedback of the amplitudes of output voltage fluctuations for direct methanol fuel cells," Energy, Elsevier, vol. 100(C), pages 217-226.
    10. Ogungbemi, Emmanuel & Ijaodola, Oluwatosin & Khatib, F.N. & Wilberforce, Tabbi & El Hassan, Zaki & Thompson, James & Ramadan, Mohamad & Olabi, A.G., 2019. "Fuel cell membranes – Pros and cons," Energy, Elsevier, vol. 172(C), pages 155-172.
    11. Ijaodola, O.S. & El- Hassan, Zaki & Ogungbemi, E. & Khatib, F.N. & Wilberforce, Tabbi & Thompson, James & Olabi, A.G., 2019. "Energy efficiency improvements by investigating the water flooding management on proton exchange membrane fuel cell (PEMFC)," Energy, Elsevier, vol. 179(C), pages 246-267.
    12. Xing, Lei & Shi, Weidong & Su, Huaneng & Xu, Qian & Das, Prodip K. & Mao, Baodong & Scott, Keith, 2019. "Membrane electrode assemblies for PEM fuel cells: A review of functional graded design and optimization," Energy, Elsevier, vol. 177(C), pages 445-464.
    13. Sudaroli, B. Mullai & Kolar, Ajit Kumar, 2016. "An experimental study on the effect of membrane thickness and PTFE (polytetrafluoroethylene) loading on methanol crossover in direct methanol fuel cell," Energy, Elsevier, vol. 98(C), pages 204-214.
    14. Yuan, Zhenyu & Fu, Wenting & Zhao, Yang & Li, Zipeng & Zhang, Yufeng & Liu, Xiaowei, 2013. "Investigation of μDMFC (micro direct methanol fuel cell) with self-adaptive flow rate," Energy, Elsevier, vol. 55(C), pages 1152-1158.
    15. Wang, Luwen & Zhang, Yufeng & An, Zijian & Huang, Siteng & Zhou, Zhiping & Liu, Xiaowei, 2013. "Non-isothermal modeling of a small passive direct methanol fuel cell in vertical operation with anode natural convection effect," Energy, Elsevier, vol. 58(C), pages 283-295.
    16. Yuan, Zhenyu & Zhang, Manna & Zuo, Kaiyuan & Ren, Yongqiang, 2018. "The effect of gravity on inner transport and cell performance in passive micro direct methanol fuel cell," Energy, Elsevier, vol. 150(C), pages 28-37.
    17. Mohammed, Hanin & Al-Othman, Amani & Nancarrow, Paul & Tawalbeh, Muhammad & El Haj Assad, Mamdouh, 2019. "Direct hydrocarbon fuel cells: A promising technology for improving energy efficiency," Energy, Elsevier, vol. 172(C), pages 207-219.
    18. Zhu, Jingyu & Tan, Jinzhu & Pan, Qing & Liu, Zenghui & Hou, Qiong, 2019. "Effects of Mg2+ contamination on the performance of proton exchange membrane fuel cell," Energy, Elsevier, vol. 189(C).
    19. Lee, Chi-Hung & Chen, Szu-Hsien & Wang, Yen-Zen & Lin, Chao-Chien & Huang, Chih-Kai & Chuang, Ching-Nan & Wang, Chih-Kuang & Hsieh, Kuo-Huang, 2013. "Preparation and characterization of proton exchange membranes based on semi-interpenetrating sulfonated poly(imide-siloxane)/epoxy polymer networks," Energy, Elsevier, vol. 55(C), pages 905-915.
    20. Yan, Wei-Mon & Chen, Chen-Yu & Liang, Chia-Hao, 2019. "Comparison of performance degradation of high temperature PEM fuel cells with different bipolar plates," Energy, Elsevier, vol. 186(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pourzare, K. & Mansourpanah, Y. & Farhadi, S. & Sadrabadi, M.M. Hasani & Ulbricht, M., 2022. "Improvement of proton conductivity of magnetically aligned phosphotungstic acid-decorated cobalt oxide embedded Nafion membrane," Energy, Elsevier, vol. 239(PA).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Fang, Shuo & Zhang, Yufeng & Ma, Zezhong & Zou, Yuezhang & Liu, Xiaowei, 2016. "Development of a micro direct methanol fuel cell with heat control," Energy, Elsevier, vol. 116(P1), pages 978-985.
    2. Fang, Shuo & Song, Nan & Liu, Yuntao & Zhou, Chaoyang & Zhao, Chunhui & Wang, Yun, 2023. "Oscillator design for high efficiency DC-DC of micro direct methanol fuel cell," Energy, Elsevier, vol. 284(C).
    3. Abdelkareem, Mohammad Ali & Sayed, Enas Taha & Nakagawa, Nobuyoshi, 2020. "Significance of diffusion layers on the performance of liquid and vapor feed passive direct methanol fuel cells," Energy, Elsevier, vol. 209(C).
    4. Fang, Shuo & Zhang, Yufeng & Zou, Yuezhang & Sang, Shengtian & Liu, Xiaowei, 2017. "Structural design and analysis of a passive DMFC supplied with concentrated methanol solution," Energy, Elsevier, vol. 128(C), pages 50-61.
    5. Fang, Shuo & Zhang, Yufeng & Ma, Zezhong & Sang, Shengtian & Liu, Xiaowei, 2016. "Systemic modeling and analysis of DMFC stack for behavior prediction in system-level application," Energy, Elsevier, vol. 112(C), pages 1015-1023.
    6. Fang, Shuo & Song, Nan & Liu, Yuntao & Zhao, Chunhui & Wang, Ying, 2024. "Comprehensive energy conversion efficiency analysis of micro direct methanol fuel cell stack based on polarization theory," Energy, Elsevier, vol. 287(C).
    7. Yuan, Zhenyu & Zhang, Manna & Zuo, Kaiyuan & Ren, Yongqiang, 2018. "The effect of gravity on inner transport and cell performance in passive micro direct methanol fuel cell," Energy, Elsevier, vol. 150(C), pages 28-37.
    8. Zhang, Xiaoqing & Yang, Jiapei & Ma, Xiao & Zhuge, Weilin & Shuai, Shijin, 2022. "Modelling and analysis on effects of penetration of microporous layer into gas diffusion layer in PEM fuel cells: Focusing on mass transport," Energy, Elsevier, vol. 254(PA).
    9. Najmi, Aezid-Ul-Hassan & Anyanwu, Ikechukwu S. & Xie, Xu & Liu, Zhi & Jiao, Kui, 2021. "Experimental investigation and optimization of proton exchange membrane fuel cell using different flow fields," Energy, Elsevier, vol. 217(C).
    10. Fang, Shuo & Liu, Yuntao & Zhao, Chunhui & Huang, Lilian & Zhong, Zhi & Wang, Yun, 2021. "Polarization analysis of a micro direct methanol fuel cell stack based on Debye-Hückel ionic atmosphere theory," Energy, Elsevier, vol. 222(C).
    11. Hosseini, Mir Ghasem & Mahmoodi, Raana & Daneshvari-Esfahlan, Vahid, 2018. "Ni@Pd core-shell nanostructure supported on multi-walled carbon nanotubes as efficient anode nanocatalysts for direct methanol fuel cells with membrane electrode assembly prepared by catalyst coated m," Energy, Elsevier, vol. 161(C), pages 1074-1084.
    12. Yu, Bor-Chern & Wang, Yi-Chun & Lu, Hsin-Chun & Lin, Hsiu-Li & Shih, Chao-Ming & Kumar, S. Rajesh & Lue, Shingjiang Jessie, 2017. "Hydroxide-ion selective electrolytes based on a polybenzimidazole/graphene oxide composite membrane," Energy, Elsevier, vol. 134(C), pages 802-812.
    13. Maria H. de Sá & Alexandra M. F. R. Pinto & Vânia B. Oliveira, 2022. "Passive Small Direct Alcohol Fuel Cells for Low-Power Portable Applications: Assessment Based on Innovative Increments since 2018," Energies, MDPI, vol. 15(10), pages 1-48, May.
    14. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    15. Cha, Dowon & Yang, Wonseok & Kim, Yongchan, 2019. "Performance improvement of self-humidifying PEM fuel cells using water injection at various start-up conditions," Energy, Elsevier, vol. 183(C), pages 514-524.
    16. Somayeh Toghyani & Seyed Ali Atyabi & Xin Gao, 2021. "Enhancing the Specific Power of a PEM Fuel Cell Powered UAV with a Novel Bean-Shaped Flow Field," Energies, MDPI, vol. 14(9), pages 1-23, April.
    17. Ahmed Mohmed Dafalla & Lin Wei & Bereket Tsegai Habte & Jian Guo & Fangming Jiang, 2022. "Membrane Electrode Assembly Degradation Modeling of Proton Exchange Membrane Fuel Cells: A Review," Energies, MDPI, vol. 15(23), pages 1-26, December.
    18. Tzelepis, Stefanos & Kavadias, Kosmas A. & Marnellos, George E. & Xydis, George, 2021. "A review study on proton exchange membrane fuel cell electrochemical performance focusing on anode and cathode catalyst layer modelling at macroscopic level," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    19. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
    20. Tabbi Wilberforce & Abdul Ghani Olabi, 2020. "Performance Prediction of Proton Exchange Membrane Fuel Cells (PEMFC) Using Adaptive Neuro Inference System (ANFIS)," Sustainability, MDPI, vol. 12(12), pages 1-16, June.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219321462. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.