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High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants

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  • Sánchez Jiménez, Pedro E.
  • Perejón, Antonio
  • Benítez Guerrero, Mónica
  • Valverde, José M.
  • Ortiz, Carlos
  • Pérez Maqueda, Luis A.

Abstract

High energy density, cycling stability, low cost and scalability are the main features required for thermochemical energy storage systems to achieve a feasible integration in Concentrating Solar Power plants (CSP). While no system has been found to fully satisfy all these requirements, the reversible CaO/CaCO3 carbonation reaction (CaL) is one of the most promising since CaO natural precursors are affordable and earth-abundant. However, CaO particles progressively deactivate due to sintering-induced morphological changes during repeated carbonation and calcinations cycles. In this work, we have prepared acicular calcium and magnesium acetate precursors using a simple, cost-effective and easily scalable technique that requires just the natural minerals and acetic acid, thereby avoiding expensive reactants and environmentally unfriendly solvents. Upon thermal decomposition, these precursors yield a stable porous structure comprised of well dispersed MgO nanoparticles coating the CaO/CaCO3 grains that is resistant to pore-plugging and sintering while at the same time exhibits high long term effective conversion. Process simulations show that the employment of these materials could significantly improve the overall CSP-CaL efficiency at the industrial level.

Suggested Citation

  • Sánchez Jiménez, Pedro E. & Perejón, Antonio & Benítez Guerrero, Mónica & Valverde, José M. & Ortiz, Carlos & Pérez Maqueda, Luis A., 2019. "High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants," Applied Energy, Elsevier, vol. 235(C), pages 543-552.
    • Handle: RePEc:eee:appene:v:235:y:2019:i:c:p:543-552
    DOI: 10.1016/j.apenergy.2018.10.131
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    Cited by:

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    2. Ortiz, C. & Valverde, J.M. & Chacartegui, R. & Perez-Maqueda, L.A. & Giménez, P., 2019. "The Calcium-Looping (CaCO3/CaO) process for thermochemical energy storage in Concentrating Solar Power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    3. Nobuyuki Gokon & Kosuke Hayashi & Hiroki Sawaguri & Fumiya Ohashi, 2022. "Long-Term Thermal Cycling Test and Heat-Charging Kinetics of Fe-Substituted Mn 2 O 3 for Next-Generation Concentrated Solar Power Using Thermochemical Energy Storage at High Temperatures," Energies, MDPI, vol. 15(13), pages 1-23, June.
    4. Ying Yang & Yingjie Li & Xianyao Yan & Jianli Zhao & Chunxiao Zhang, 2021. "Development of Thermochemical Heat Storage Based on CaO/CaCO 3 Cycles: A Review," Energies, MDPI, vol. 14(20), pages 1-26, October.
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    6. Nobuyuki Gokon & Fumiya Ohashi & Hiroki Sawaguri & Kosuke Hayashi, 2023. "Comparative Study of Heat-Discharging Kinetics of Fe-Substituted Mn 2 O 3 /Mn 3 O 4 Being Subjected to Long-Term Cycling for Thermochemical Energy Storage," Energies, MDPI, vol. 16(8), pages 1-23, April.
    7. Li, Caili & Li, Yingjie & Fang, Yi & Zhang, Chunxiao & Ren, Yu, 2024. "TiO2/MnFe2O4 co-modified alkaline papermaking waste for CaO-CaCO3 thermochemical energy storage," Applied Energy, Elsevier, vol. 362(C).
    8. Sun, Hao & Li, Yingjie & Yan, Xianyao & Zhao, Jianli & Wang, Zeyan, 2020. "Thermochemical energy storage performance of Al2O3/CeO2 co-doped CaO-based material under high carbonation pressure," Applied Energy, Elsevier, vol. 263(C).
    9. Bravo, Ruben & Ortiz, Carlos & Chacartegui, Ricardo & Friedrich, Daniel, 2021. "Multi-objective optimisation and guidelines for the design of dispatchable hybrid solar power plants with thermochemical energy storage," Applied Energy, Elsevier, vol. 282(PB).
    10. Michalski, Sebastian & Hanak, Dawid P. & Manovic, Vasilije, 2020. "Advanced power cycles for coal-fired power plants based on calcium looping combustion: A techno-economic feasibility assessment," Applied Energy, Elsevier, vol. 269(C).
    11. Xu, T.X. & Tian, X.K. & Khosa, A.A. & Yan, J. & Ye, Q. & Zhao, C.Y., 2021. "Reaction performance of CaCO3/CaO thermochemical energy storage with TiO2 dopant and experimental study in a fixed-bed reactor," Energy, Elsevier, vol. 236(C).
    12. Kelly Atkinson & Robin Hughes & Arturo Macchi, 2023. "Application of the Calcium Looping Process for Thermochemical Storage of Variable Energy," Energies, MDPI, vol. 16(7), pages 1-19, April.
    13. Alvarez Rivero, M. & Rodrigues, D. & Pinheiro, C.I.C. & Cardoso, J.P. & Mendes, L.F., 2022. "Solid–gas reactors driven by concentrated solar energy with potential application to calcium looping: A comparative review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).
    14. Cabeza, Luisa F. & de Gracia, Alvaro & Zsembinszki, Gabriel & Borri, Emiliano, 2021. "Perspectives on thermal energy storage research," Energy, Elsevier, vol. 231(C).
    15. Fang, Juan & Liu, Qibin & Guo, Shaopeng & Lei, Jing & Jin, Hongguang, 2019. "Spanning solar spectrum: A combined photochemical and thermochemical process for solar energy storage," Applied Energy, Elsevier, vol. 247(C), pages 116-126.
    16. Ma, Zhangke & Li, Yingjie & Zhang, Wan & Wang, Yuzhuo & Zhao, Jianli & Wang, Zeyan, 2020. "Energy storage and attrition performance of limestone under fluidization during CaO/CaCO3 cycles," Energy, Elsevier, vol. 207(C).
    17. Zhao, Yunlei & Jin, Bo & Luo, Xiao & Liang, Zhiwu, 2021. "Thermodynamic evaluation and experimental investigation of CaO-assisted Fe-based chemical looping reforming process for syngas production," Applied Energy, Elsevier, vol. 288(C).
    18. Bian, Ruihao & Deng, Yajun & Li, Qingchen & Zhu, Zhengyue & Zhang, Wei & Sun, Dongliang & Yu, Bo, 2024. "Numerical modeling and experimental validation on the thermal stress inside the three-dimensional porous calcium-based particle for thermochemical energy storage," Renewable Energy, Elsevier, vol. 229(C).

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