IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v188y2017icp672-681.html
   My bibliography  Save this article

Thermochemical energy storage with CaO/Ca(OH)2 – Experimental investigation of the thermal capability at low vapor pressures in a lab scale reactor

Author

Listed:
  • Schmidt, Matthias
  • Gutierrez, Andrea
  • Linder, Marc

Abstract

The reversible reaction of calcium hydroxide (Ca(OH)2) to calcium oxide (CaO) and water vapor is well known in the context of thermochemical energy storage. Cheap material costs, a theoretically very high energy density and the potentially wide temperature range of the reaction imply that the storage system could be beneficial for many high temperature processes. For example the system could be applied to store and reutilize industrial waste heat or as an alternative storage solution in future concentrated solar power plants.

Suggested Citation

  • Schmidt, Matthias & Gutierrez, Andrea & Linder, Marc, 2017. "Thermochemical energy storage with CaO/Ca(OH)2 – Experimental investigation of the thermal capability at low vapor pressures in a lab scale reactor," Applied Energy, Elsevier, vol. 188(C), pages 672-681.
    • Handle: RePEc:eee:appene:v:188:y:2017:i:c:p:672-681
    DOI: 10.1016/j.apenergy.2016.11.023
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916316087
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.11.023?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Pardo, P. & Deydier, A. & Anxionnaz-Minvielle, Z. & Rougé, S. & Cabassud, M. & Cognet, P., 2014. "A review on high temperature thermochemical heat energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 591-610.
    2. Yan, J. & Zhao, C.Y., 2016. "Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage," Applied Energy, Elsevier, vol. 175(C), pages 277-284.
    3. Shkatulov, Alexandr & Aristov, Yuri, 2015. "Modification of magnesium and calcium hydroxides with salts: An efficient way to advanced materials for storage of middle-temperature heat," Energy, Elsevier, vol. 85(C), pages 667-676.
    4. Zhang, Hui & Wang, Hong & Zhu, Xun & Qiu, Yong-Jun & Li, Kai & Chen, Rong & Liao, Qiang, 2013. "A review of waste heat recovery technologies towards molten slag in steel industry," Applied Energy, Elsevier, vol. 112(C), pages 956-966.
    5. Prieto, Cristina & Cooper, Patrick & Fernández, A. Inés & Cabeza, Luisa F., 2016. "Review of technology: Thermochemical energy storage for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 909-929.
    6. Nagel, T. & Shao, H. & Roßkopf, C. & Linder, M. & Wörner, A. & Kolditz, O., 2014. "The influence of gas–solid reaction kinetics in models of thermochemical heat storage under monotonic and cyclic loading," Applied Energy, Elsevier, vol. 136(C), pages 289-302.
    7. Wang, Wenqing & Kolditz, Olaf & Nagel, Thomas, 2017. "Parallel finite element modelling of multi-physical processes in thermochemical energy storage devices," Applied Energy, Elsevier, vol. 185(P2), pages 1954-1964.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Aman Gupta & Piyush Sabharwall & Paul D. Armatis & Brian M. Fronk & Vivek Utgikar, 2022. "Coupling Chemical Heat Pump with Nuclear Reactor for Temperature Amplification by Delivering Process Heat and Electricity: A Techno-Economic Analysis," Energies, MDPI, vol. 15(16), pages 1-25, August.
    2. Lutz, Michael & Bhouri, Maha & Linder, Marc & Bürger, Inga, 2019. "Adiabatic magnesium hydride system for hydrogen storage based on thermochemical heat storage: Numerical analysis of the dehydrogenation," Applied Energy, Elsevier, vol. 236(C), pages 1034-1048.
    3. Laurie André & Stéphane Abanades, 2020. "Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature," Energies, MDPI, vol. 13(22), pages 1-23, November.
    4. Risthaus, Kai & Linder, Marc & Schmidt, Matthias, 2022. "Experimental investigation of a novel mechanically fluidized bed reactor for thermochemical energy storage with calcium hydroxide/calcium oxide," Applied Energy, Elsevier, vol. 315(C).
    5. Wang, Mengyi & Chen, Li & Zhou, Yuhao & Tao, Wen-Quan, 2022. "Numerical simulation of the calcium hydroxide/calcium oxide system dehydration reaction in a shell-tube reactor," Applied Energy, Elsevier, vol. 312(C).
    6. Seitz, Gabriele & Helmig, Rainer & Class, Holger, 2020. "A numerical modeling study on the influence of porosity changes during thermochemical heat storage," Applied Energy, Elsevier, vol. 259(C).
    7. Luo, Ji-Wang & Chen, Li & Wang, MengYi & Xia, Yang & Tao, WenQuan, 2022. "Particle-scale study of coupled physicochemical processes in Ca(OH)2 dehydration using the lattice Boltzmann method," Energy, Elsevier, vol. 250(C).
    8. Schmidt, Matthias & Linder, Marc, 2017. "Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design," Applied Energy, Elsevier, vol. 203(C), pages 594-607.
    9. Peng, Xinyue & Yao, Min & Root, Thatcher W. & Maravelias, Christos T., 2020. "Design and analysis of concentrating solar power plants with fixed-bed reactors for thermochemical energy storage," Applied Energy, Elsevier, vol. 262(C).
    10. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Castelain, Cathy, 2019. "Integration of a thermochemical energy storage system in a Rankine cycle driven by concentrating solar power: Energy and exergy analyses," Energy, Elsevier, vol. 167(C), pages 498-510.
    11. Selvan Bellan & Tatsuya Kodama & Nobuyuki Gokon & Koji Matsubara, 2022. "A review on high‐temperature thermochemical heat storage: Particle reactors and materials based on solid–gas reactions," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 11(5), September.
    12. Gabriel Zsembinszki & Aran Solé & Camila Barreneche & Cristina Prieto & A. Inés Fernández & Luisa F. Cabeza, 2018. "Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants," Energies, MDPI, vol. 11(9), pages 1-23, September.
    13. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    14. Jun Yan & Lei Jiang & Changying Zhao, 2023. "Numerical Simulation of the Ca(OH) 2 /CaO Thermochemical Heat Storage Process in an Internal Heating Fixed-Bed Reactor," Sustainability, MDPI, vol. 15(9), pages 1-14, April.
    15. Risthaus, Kai & Bürger, Inga & Linder, Marc & Schmidt, Matthias, 2020. "Numerical analysis of the hydration of calcium oxide in a fixed bed reactor based on lab-scale experiments," Applied Energy, Elsevier, vol. 261(C).
    16. Timothy Praditia & Thilo Walser & Sergey Oladyshkin & Wolfgang Nowak, 2020. "Improving Thermochemical Energy Storage Dynamics Forecast with Physics-Inspired Neural Network Architecture," Energies, MDPI, vol. 13(15), pages 1-26, July.
    17. Xiao, Sinan & Praditia, Timothy & Oladyshkin, Sergey & Nowak, Wolfgang, 2021. "Global sensitivity analysis of a CaO/Ca(OH)2 thermochemical energy storage model for parametric effect analysis," Applied Energy, Elsevier, vol. 285(C).
    18. Wang, Mengyi & Chen, Li & He, Pu & Tao, Wen-Quan, 2019. "Numerical study and enhancement of Ca(OH)2/CaO dehydration process with porous channels embedded in reactors," Energy, Elsevier, vol. 181(C), pages 417-428.
    19. Funayama, Shigehiko & Takasu, Hiroki & Kim, Seon Tae & Kato, Yukitaka, 2020. "Thermochemical storage performance of a packed bed of calcium hydroxide composite with a silicon-based ceramic honeycomb support," Energy, Elsevier, vol. 201(C).
    20. Anti Kur & Jo Darkwa & John Calautit & Rabah Boukhanouf & Mark Worall, 2023. "Solid–Gas Thermochemical Energy Storage Materials and Reactors for Low to High-Temperature Applications: A Concise Review," Energies, MDPI, vol. 16(2), pages 1-35, January.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Schmidt, Matthias & Linder, Marc, 2017. "Power generation based on the Ca(OH)2/ CaO thermochemical storage system – Experimental investigation of discharge operation modes in lab scale and corresponding conceptual process design," Applied Energy, Elsevier, vol. 203(C), pages 594-607.
    2. Yi Yuan & Yingjie Li & Jianli Zhao, 2018. "Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review," Sustainability, MDPI, vol. 10(8), pages 1-24, July.
    3. Müller, Danny & Knoll, Christian & Gravogl, Georg & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Schreiner, Manfred & Harasek, Michael & Hradil, Klaudia & Werner, An, 2019. "Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    4. Mastronardo, E. & Bonaccorsi, L. & Kato, Y. & Piperopoulos, E. & Lanza, M. & Milone, C., 2016. "Thermochemical performance of carbon nanotubes based hybrid materials for MgO/H2O/Mg(OH)2 chemical heat pumps," Applied Energy, Elsevier, vol. 181(C), pages 232-243.
    5. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    6. Gabriel Zsembinszki & Aran Solé & Camila Barreneche & Cristina Prieto & A. Inés Fernández & Luisa F. Cabeza, 2018. "Review of Reactors with Potential Use in Thermochemical Energy Storage in Concentrated Solar Power Plants," Energies, MDPI, vol. 11(9), pages 1-23, September.
    7. Tescari, S. & Singh, A. & Agrafiotis, C. & de Oliveira, L. & Breuer, S. & Schlögl-Knothe, B. & Roeb, M. & Sattler, C., 2017. "Experimental evaluation of a pilot-scale thermochemical storage system for a concentrated solar power plant," Applied Energy, Elsevier, vol. 189(C), pages 66-75.
    8. Yan, J. & Zhao, C.Y. & Pan, Z.H., 2017. "The effect of CO2 on Ca(OH)2 and Mg(OH)2 thermochemical heat storage systems," Energy, Elsevier, vol. 124(C), pages 114-123.
    9. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Castelain, Cathy, 2019. "Integration of a thermochemical energy storage system in a Rankine cycle driven by concentrating solar power: Energy and exergy analyses," Energy, Elsevier, vol. 167(C), pages 498-510.
    10. Yan, J. & Zhao, C.Y., 2016. "Experimental study of CaO/Ca(OH)2 in a fixed-bed reactor for thermochemical heat storage," Applied Energy, Elsevier, vol. 175(C), pages 277-284.
    11. Böhm, Hans & Lindorfer, Johannes, 2019. "Techno-economic assessment of seasonal heat storage in district heating with thermochemical materials," Energy, Elsevier, vol. 179(C), pages 1246-1264.
    12. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
    13. Arias, I. & Cardemil, J. & Zarza, E. & Valenzuela, L. & Escobar, R., 2022. "Latest developments, assessments and research trends for next generation of concentrated solar power plants using liquid heat transfer fluids," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    14. Gravogl, Georg & Knoll, Christian & Artner, Werner & Welch, Jan M. & Eitenberger, Elisabeth & Friedbacher, Gernot & Harasek, Michael & Hradil, Klaudia & Werner, Andreas & Weinberger, Peter & Müller, D, 2019. "Pressure effects on the carbonation of MeO (Me = Co, Mn, Pb, Zn) for thermochemical energy storage," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    15. Flegkas, S. & Birkelbach, F. & Winter, F. & Freiberger, N. & Werner, A., 2018. "Fluidized bed reactors for solid-gas thermochemical energy storage concepts - Modelling and process limitations," Energy, Elsevier, vol. 143(C), pages 615-623.
    16. Seon Tae Kim & Haruka Miura & Hiroki Takasu & Yukitaka Kato & Alexandr Shkatulov & Yuri Aristov, 2019. "Adapting the MgO-CO 2 Working Pair for Thermochemical Energy Storage by Doping with Salts: Effect of the (LiK)NO 3 Content," Energies, MDPI, vol. 12(12), pages 1-13, June.
    17. André, Laurie & Abanades, Stéphane & Flamant, Gilles, 2016. "Screening of thermochemical systems based on solid-gas reversible reactions for high temperature solar thermal energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 703-715.
    18. Cabeza, Luisa F. & Solé, Aran & Fontanet, Xavier & Barreneche, Camila & Jové, Aleix & Gallas, Manuel & Prieto, Cristina & Fernández, A. Inés, 2017. "Thermochemical energy storage by consecutive reactions for higher efficient concentrated solar power plants (CSP): Proof of concept," Applied Energy, Elsevier, vol. 185(P1), pages 836-845.
    19. Müller, Danny & Knoll, Christian & Gravogl, Georg & Jordan, Christian & Eitenberger, Elisabeth & Friedbacher, Gernot & Artner, Werner & Welch, Jan M. & Werner, Andreas & Harasek, Michael & Miletich, R, 2021. "Medium-temperature thermochemical energy storage with transition metal ammoniates – A systematic material comparison," Applied Energy, Elsevier, vol. 285(C).
    20. Risthaus, Kai & Bürger, Inga & Linder, Marc & Schmidt, Matthias, 2020. "Numerical analysis of the hydration of calcium oxide in a fixed bed reactor based on lab-scale experiments," Applied Energy, Elsevier, vol. 261(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:188:y:2017:i:c:p:672-681. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.